Determine the structure based on the molecular formula and its 1H NMR spectrum (and IR spectrum, if provided). Show the work by providing a table summarizing the data from each spectrum and explain in detail the reasoning. You must analyze each absorption in the NMR and four absorptions in the IR (if applicable).
The table for NMR should include: chemical shift (δ value), the splitting, the number of neighbors, the integration, and the assignment of the specific protons responsible for the absorption.
The table for IR should include: frequency/wavenumbers, bond responsible, and mode of vibration.
Homework Answers
Add Answer to:
Determine the structure based on the molecular formula and its
1H NMR spectrum (and IR spectrum,...
2. Use the 'H NMR and IR data to determine the structure of the following compounds...
2. Use the 'H NMR and IR data to determine the structure of the following compounds and name them. Compound A Molecular formula: CroH IR absorptions at N/A H NMR data: 1.3 (singlet, 9H), 7.0 to 7.5 (multiplet, 5H) ppm Compound B Molecular formula: CHO IR absorptions at 1H NMR data: 1735-1745, 1050 cm 0.93 (doublet, 6H), 1.52 (multiplet, 2H), 1.69 (multiplet, 1H), 2.04 (singlet, 3H), and 4.10 (triplet,2H) ppm Compound C Molecular ion: IR absorptions at 1710 cm 1H...
1. Given the 'H NMR spectrum below and a molecular formula of CH20, provide a structure....
1. Given the 'H NMR spectrum below and a molecular formula of CH20, provide a structure. Note you must assign all of the signals in the spectrum below to receive full credit. IR: 1600-1650 cm' (multiple peaks) (5 pts.) 3H, S 3H. t 2H, d 2H, d 2H, PPM 2. Given the 'H NMR spectrum below and a molecular formula of CH.0, provide a structure. Note you must assign all of the signals in the spectrum below to receive full...
3. Given the 'H NMR spectrum below and a molecular formula of C.HO. provide a structure....
3. Given the 'H NMR spectrum below and a molecular formula of C.HO. provide a structure. Note you must assign all of the signals in the spectrum below to receive full credit. IR: 3300 cm' (broad) (5 pts.) 3H, d 3H, 2H, t 2H, 2H, m 1H, bs 1H, m PPM
A compound with a molecular formula C5H11NO has the following 1H NMR spectrum. The IR spectrum...
A compound with a molecular formula C5H11NO has the following 1H NMR spectrum. The IR spectrum shows an absorption at around 3400 cm 1. Which of the following structures is consistent with this spectrum? exchanges with D20 PPM ZI IZ IZ IZ
3. Deduce the structure of each compound using IR data and 'H NMR spectrum provided. (a)...
3. Deduce the structure of each compound using IR data and 'H NMR spectrum provided. (a) C.H:02 IR data: one strong absorption at 1730 cm, 2 strong absorptions at 1050 cm and 1200 cm 'H NMR Spectrum PPM (b) CH120 IR data: medium to weak absorptions at 3030 cm, 1600 cm. and 1500 cm, one strong absorption at 1100 cm 2H 2H
Determine the structure based on the following molecular formula, IR, and NMR spectrum: 39. Formula: CH N ఇ 4000 35...
Determine the structure based on the following molecular formula, IR, and NMR spectrum: 39. Formula: CH N ఇ 4000 3500 3000 25e 1s02 2800 1800 3H 4H 2H 2 PPM 229 B162
for the following 2 compounds, please calculate, and show the calculations for, the degree of unsaturation, assign the IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR peaks, and draw th...
for the following 2 compounds, please calculate, and
show the calculations for, the degree of unsaturation, assign the
IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR
peaks, and draw the structure for the unknown compound.
CHIM 245 Spectroscopy Problem Set #2 In this problem set there are two unknown compounds. You are provided with the formula, IR spectrum, "C NMR spectrum, and 'H NMR spectrum for each compound. Each unknown is worth 10 points, with an...
2. Given the 'H NMR spectrum below and a molecular formula of CsH60, provide a structure....
2. Given the 'H NMR spectrum below and a molecular formula of CsH60, provide a structure. Note you must assign all of the signals in the spectrum below to receive full credit. IR: 1710 cm (5 pts.) 6H, 1H, S 2H, d 1H, m NH PPM CHE 310 Homework 9 Due WED NOV 20 3. Given the 'H NMR spectrum below and a molecular formula of CH..0. provide a structure. Note you must assign all of the signals in the...
Give the structure that corresponds to the following molecular formula and 1H NMR spectrum
Give the structure that corresponds to the following molecular formula and 1H NMR spectrum: C7H12Cl2 : δ 1.07 (9H, singlet): δ 1.83 (2H, doublet); δ 5.77 (1H, triplet).Draw the structure of the compound that is consistent with the 1H NMR data below. Do not draw any hydrogens in your solution. It must be drawn as a true skeletal structure.
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a st...
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 148, an IR peak at 1680 cm'and gives the following H and 13C NMR spectra 3H зн 2H 2H 2H 3 5 2 7 6 4 PPM 160 140 180 60 220 200 20 0 120 100 80 40 PPM -
2. Use the 'H NMR and IR data to determine the structure of the following compounds and name them. Compound A Molecular formula: CroH IR absorptions at N/A H NMR data: 1.3 (singlet, 9H), 7.0 to 7.5 (multiplet, 5H) ppm Compound B Molecular formula: CHO IR absorptions at 1H NMR data: 1735-1745, 1050 cm 0.93 (doublet, 6H), 1.52 (multiplet, 2H), 1.69 (multiplet, 1H), 2.04 (singlet, 3H), and 4.10 (triplet,2H) ppm Compound C Molecular ion: IR absorptions at 1710 cm 1H...
1. Given the 'H NMR spectrum below and a molecular formula of CH20, provide a structure. Note you must assign all of the signals in the spectrum below to receive full credit. IR: 1600-1650 cm' (multiple peaks) (5 pts.) 3H, S 3H. t 2H, d 2H, d 2H, PPM 2. Given the 'H NMR spectrum below and a molecular formula of CH.0, provide a structure. Note you must assign all of the signals in the spectrum below to receive full...
3. Given the 'H NMR spectrum below and a molecular formula of C.HO. provide a structure. Note you must assign all of the signals in the spectrum below to receive full credit. IR: 3300 cm' (broad) (5 pts.) 3H, d 3H, 2H, t 2H, 2H, m 1H, bs 1H, m PPM
A compound with a molecular formula C5H11NO has the following 1H NMR spectrum. The IR spectrum shows an absorption at around 3400 cm 1. Which of the following structures is consistent with this spectrum? exchanges with D20 PPM ZI IZ IZ IZ
3. Deduce the structure of each compound using IR data and 'H NMR spectrum provided. (a) C.H:02 IR data: one strong absorption at 1730 cm, 2 strong absorptions at 1050 cm and 1200 cm 'H NMR Spectrum PPM (b) CH120 IR data: medium to weak absorptions at 3030 cm, 1600 cm. and 1500 cm, one strong absorption at 1100 cm 2H 2H
Determine the structure based on the following molecular formula, IR, and NMR spectrum: 39. Formula: CH N ఇ 4000 3500 3000 25e 1s02 2800 1800 3H 4H 2H 2 PPM 229 B162
for the following 2 compounds, please calculate, and
show the calculations for, the degree of unsaturation, assign the
IR spectrum peaks, assign the 13C NMR peaks, assign the 1H NMR
peaks, and draw the structure for the unknown compound.
CHIM 245 Spectroscopy Problem Set #2 In this problem set there are two unknown compounds. You are provided with the formula, IR spectrum, "C NMR spectrum, and 'H NMR spectrum for each compound. Each unknown is worth 10 points, with an...
2. Given the 'H NMR spectrum below and a molecular formula of CsH60, provide a structure. Note you must assign all of the signals in the spectrum below to receive full credit. IR: 1710 cm (5 pts.) 6H, 1H, S 2H, d 1H, m NH PPM CHE 310 Homework 9 Due WED NOV 20 3. Given the 'H NMR spectrum below and a molecular formula of CH..0. provide a structure. Note you must assign all of the signals in the...
16. Propose a structure for a molecule of formula CaHsCl which gave the following 1H NMR spectrum. PPM 17. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 148, an IR peak at 1680 cm'and gives the following H and 13C NMR spectra 3H зн 2H 2H 2H 3 5 2 7 6 4 PPM 160 140 180 60 220 200 20 0 120 100 80 40 PPM -
Most questions answered within 3 hours.
-
Which of the following statements explains why the cost of
advertising might be relevant to a...
asked 3 minutes ago -
NO3- nitrate ion, what is the symmetry operationof rotation of
it?
asked 8 minutes ago -
Block A, with mass mA, is initially at rest on a frictionless
horizontal floor. Block B,...
asked 9 minutes ago -
Space shuttle astronauts each consume an average of 3000
calories per day. One meal normally consists...
asked 10 minutes ago -
A distribution center for a sporting goods retailer places
orders with manufacturers for a variety of...
asked 26 minutes ago -
Suppose you have a bag of Skittles with 27 blue Skittles, 18
green
Skittles, 32 red...
asked 29 minutes ago -
Sketch the circuit diagram for an inverting amplifier, and give
component values that will produce a...
asked 32 minutes ago -
Develop in C language the function whose prototype is described
below. Please, send the entire code,...
asked 49 minutes ago -
What single payment today would replace a payment stream of
$50,000 that will be paid today,...
asked 43 minutes ago -
please c++ with functions *Modify the Guessing Game Write the
secret number to a file. Then...
asked 43 minutes ago -
Question about ACID/BASE. Equal volumes of 0.230 M weak base (Kb
= 4.0× 10–9) and 0.230...
asked 49 minutes ago -
The charges and coordinates of two charged particles held fixed
in an xy plane are q1...
asked 51 minutes ago