Homework Answers
1.
Benzoic acid on reaction with two equivalent methyl lithium we will
acetophenone as product.
2. Second reaction is trans esterification reaction in which methanol will get replaced by ethanol.
3. In third reaction first step is conversion of acid to acid chloride which will further react with dimethylhydroxylamine to get amide product.
4. In fourth reaction first acid will convert to acid chloride and reaction of this acid chloride with alcohol will give us ester as a product.
5. Salicylic acid on reaction with acetic anhydride we will get Aspirin as product and acetic acid as a byproduct.
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find products
Pro 2 Eq MeLi снасн,он, н* 1. SOCI2 2. NH(CH3)2 OH 1. SOCI, 2....
Predict the product: н н NaBHa (0.50 eq.), CH;ОН 1. 2. HСI, Н,о
Predict the product:
н н NaBHa (0.50 eq.), CH;ОН 1. 2. HСI, Н,о
Predict the product for the following reaction. он 1. SOCI2/pyridine 2. LiA[[OC(CH3)3]Н ОН Осн. || ОН...
Predict the product for the following reaction. он 1. SOCI2/pyridine 2. LiA[[OC(CH3)3]Н ОН Осн. || ОН SOCIII Оооооо
Он н H-C-C-CH3 + H20+ reactant H OH 1. + H30+ - reaction of: CH, (1)...
Он н H-C-C-CH3 + H20+ reactant H OH 1. + H30+ - reaction of: CH, (1) BH, - THE (2) H2O, NaOH H product is: OH H,SO calor reactant: 4 OH NaBH, CH CHON H
14. (1 pt each) Name the following molecules. CH3 CH3 нно н н-с-с-с-NA ті Hн н,с...
14. (1 pt each) Name the following molecules. CH3 CH3 нно н н-с-с-с-NA ті Hн н,с Сн, Н CH,CH нс H 15. (3 pts each) Give the product(s) for the following reactions, and name all reactants and products. CH, он ОН н,с + нэс- сн - сн 3 нус. NH2 ОН Hн ІІ ОН + н-с-с-о-н НО P н Н ОН
Predict the (stable organic) products NaBH, CH,оH 1 2. HC, H,о NaBH, (1 eq.), сн,он 1....
Predict the (stable organic) products
NaBH, CH,оH 1 2. HC, H,о NaBH, (1 eq.), сн,он 1. 2. HC, H,о NaBн(осн)» (1 еч.), сн,он 1. 2 HCI, H,о LIAIH (1 eq THF 1. Br 2. HC, H,о
Predict the product by providing the stable organic products for each reaction. NaBH4, CH3OH 1. н...
Predict the product by providing the stable organic products for
each reaction.
NaBH4, CH3OH 1. н 2. HСI, Н20 н Н NaBHa (0.50 eq.), сH,он 1 2. HСI, Н20 LIAIH4 (1 eq.), THF 1 2. HC, H,о NaBH(ОCH;)з. (1 еq.), CH,он 1. CI 2. HCI, Н20 о
+ C) NH H2N CO2H 2 moles NaOH NH3 н. D) CH,CH(CH3)2 ОН H2N Show transcribed...
+ C) NH H2N CO2H 2 moles NaOH NH3 н. D) CH,CH(CH3)2 ОН H2N
+ C) NH H2N CO2H 2 moles NaOH NH3 н. D) CH,CH(CH3)2 ОН H2N Show transcribed...
+ C) NH H2N CO2H 2 moles NaOH NH3 н. D) CH,CH(CH3)2 ОН H2N
These monosaccharides are CH,OH CH,OH H ОН НО НО H ОНОН Н. ОН 1 Н НО...
These monosaccharides are
CH,OH CH,OH H ОН НО НО H ОНОН Н. ОН 1 Н НО Н. H Н H H H ОН.
о, DMS RCO H Он но н'но) Он SOCI РСС ОН н'-но) SH Raney Ni HS...
о, DMS RCO H Он но н'но) Он SOCI РСС ОН н'-но) SH Raney Ni HS н'*но) н' Но CH, Oн NH2 1) LAH ОН 2) H,O Shem 415 Question 1 (6 points). Provide IUPAC names for the following structures. Question 2 (14 points), Convert the following IUPAC names into structures. 2,4-dimethylcyclopent-2-enone 5-hydroxy-2-phenyl-3-hexanone (S)-2-bromo-2-methylcyclobutanone 3-methyl-5-(4-chlorophenyl) hexanal 3-isobutylbenzoic acid Acetic butanoic anhydride N-phenyl-N-propyl-2,3-dimethylbutanamide Page 2 o
Predict the product:
н н NaBHa (0.50 eq.), CH;ОН 1. 2. HСI, Н,о
Predict the product for the following reaction. он 1. SOCI2/pyridine 2. LiA[[OC(CH3)3]Н ОН Осн. || ОН SOCIII Оооооо
Он н H-C-C-CH3 + H20+ reactant H OH 1. + H30+ - reaction of: CH, (1) BH, - THE (2) H2O, NaOH H product is: OH H,SO calor reactant: 4 OH NaBH, CH CHON H
14. (1 pt each) Name the following molecules. CH3 CH3 нно н н-с-с-с-NA ті Hн н,с Сн, Н CH,CH нс H 15. (3 pts each) Give the product(s) for the following reactions, and name all reactants and products. CH, он ОН н,с + нэс- сн - сн 3 нус. NH2 ОН Hн ІІ ОН + н-с-с-о-н НО P н Н ОН
Predict the (stable organic) products
NaBH, CH,оH 1 2. HC, H,о NaBH, (1 eq.), сн,он 1. 2. HC, H,о NaBн(осн)» (1 еч.), сн,он 1. 2 HCI, H,о LIAIH (1 eq THF 1. Br 2. HC, H,о
Predict the product by providing the stable organic products for
each reaction.
NaBH4, CH3OH 1. н 2. HСI, Н20 н Н NaBHa (0.50 eq.), сH,он 1 2. HСI, Н20 LIAIH4 (1 eq.), THF 1 2. HC, H,о NaBH(ОCH;)з. (1 еq.), CH,он 1. CI 2. HCI, Н20 о
+ C) NH H2N CO2H 2 moles NaOH NH3 н. D) CH,CH(CH3)2 ОН H2N
+ C) NH H2N CO2H 2 moles NaOH NH3 н. D) CH,CH(CH3)2 ОН H2N
These monosaccharides are
CH,OH CH,OH H ОН НО НО H ОНОН Н. ОН 1 Н НО Н. H Н H H H ОН.
о, DMS RCO H Он но н'но) Он SOCI РСС ОН н'-но) SH Raney Ni HS н'*но) н' Но CH, Oн NH2 1) LAH ОН 2) H,O Shem 415 Question 1 (6 points). Provide IUPAC names for the following structures. Question 2 (14 points), Convert the following IUPAC names into structures. 2,4-dimethylcyclopent-2-enone 5-hydroxy-2-phenyl-3-hexanone (S)-2-bromo-2-methylcyclobutanone 3-methyl-5-(4-chlorophenyl) hexanal 3-isobutylbenzoic acid Acetic butanoic anhydride N-phenyl-N-propyl-2,3-dimethylbutanamide Page 2 o
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