Question

The gas phase reaction OH(g) + CH4(g) → H2O(g) + CH(g) is second order overall and first order in both reactants. The initial rate of appearance (measured at constant volume and temperature) of HO as a function of temperature is given in the table below. The initial concentration of OH and CH, is 0.500 mol m23. (a) Calculate the Arrhenius parameters for the rate constant. (b) Calculate the initial rate and concentration of OH and H,O after 1 ms at 250 K for the same initial pressure. T/K R/mol m3s 284 509 838 1290 240 260 280 300

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