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3.1 Apply the aromaticity rules to determine whether the following compounds are aromatic or not. А...
26 a) Describe whether or not the following molecule is aromatic. Explain based on the rules...
26 a) Describe whether or not the following molecule is aromatic. Explain based on the rules of aromaticity: b) When pyrrole undergoes an SeAr reaction with bromine, substitution takes place at the 2. position. Explain mechanistically why this occurs Relry ) Draw the products of the following reactions: LDA THE 2) CH CH CH Br NOCH.CH.CH 2) CH.CH,Br 3) NaOH, HCO 4)H,0', het b) Write a structural formula for the principal organic product() of each of the following reactions CH,...
3. Please indicate how many pi electrons each of the following compounds have and whether they...
3. Please indicate how many pi electrons each of the following compounds have and whether they are aromatic, non-aromatic, or anti-aromatic. (8 points) 4. Draw the mechanism of the reaction between toluene and isopropyl chloride in the presence of AlCl3 to give 4-isopropyl toluene. (7 points) AICI: Please draw the major product or products of each of the following reactions. (4 points each) HBr/ UV light 5. Brą/UV light
1. For the following compounds, label each substituent as electron donating or electron withdrawing, and indicate...
1. For the following compounds, label each substituent as electron donating or electron withdrawing, and indicate whether this effect is achieved via induction or resonance. ŅO2 H2N SO3H 2. Predict the TH NMR of the above benzene derivatives. For chemical shift, indicate whether the peak would likely be downfield or upfield of benzene (7.2 ppm). (Hint: think about the resonance structures that can be drawn based on your responses from above) A B # of peaks chemical shift indicate: >7.2,...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.)...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.) (9 points) Name the following compounds: 3.) (8 points) Label the following molecules as aromatic, anti-aromatic, or non-aromatic. For the ones th aren't aromatic, explain why they are either non-aromatic or anti-aromatic. 0.8 4.) (11 points) For the following electrophilic aromatic substitution reaction: Вт, FeBr; a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product...
26 a) Describe whether or not the following molecule is aromatic. Explain based on the rules of aromaticity: b) When pyrrole undergoes an SeAr reaction with bromine, substitution takes place at the 2. position. Explain mechanistically why this occurs Relry ) Draw the products of the following reactions: LDA THE 2) CH CH CH Br NOCH.CH.CH 2) CH.CH,Br 3) NaOH, HCO 4)H,0', het b) Write a structural formula for the principal organic product() of each of the following reactions CH,...
3. Please indicate how many pi electrons each of the following compounds have and whether they are aromatic, non-aromatic, or anti-aromatic. (8 points) 4. Draw the mechanism of the reaction between toluene and isopropyl chloride in the presence of AlCl3 to give 4-isopropyl toluene. (7 points) AICI: Please draw the major product or products of each of the following reactions. (4 points each) HBr/ UV light 5. Brą/UV light
1. For the following compounds, label each substituent as electron donating or electron withdrawing, and indicate whether this effect is achieved via induction or resonance. ŅO2 H2N SO3H 2. Predict the TH NMR of the above benzene derivatives. For chemical shift, indicate whether the peak would likely be downfield or upfield of benzene (7.2 ppm). (Hint: think about the resonance structures that can be drawn based on your responses from above) A B # of peaks chemical shift indicate: >7.2,...
1.) (9 points) Give structures for the following compounds: a) meta-phenylphenol b) 6-benzyl-3-heptanol e) ortho-sec-butyltoluene 2.) (9 points) Name the following compounds: 3.) (8 points) Label the following molecules as aromatic, anti-aromatic, or non-aromatic. For the ones th aren't aromatic, explain why they are either non-aromatic or anti-aromatic. 0.8 4.) (11 points) For the following electrophilic aromatic substitution reaction: Вт, FeBr; a) Which product is the major one? b) Draw a complete mechanism for the formation of the major product...
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