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Below is the structure of fructose, which numbered carbon is the anomeric carbon? CH2OH H О,...
Question 10 0.5 pts Below is the structure of fructose, which numbered carbon is the anomeric carbon? CH2OH HO HO ОН. 2 Н. 31 CH2OH OH H 5 1 o O 6 O 3 O o
Question 8 0.5 pts Below is the structure of fructose, is it D-or L-fructose AND which numbered carbon determines this? CH2OH 0 HO -H H- OH НЕОН CH2OH L-fructose; #5 carbon O L-fructose; #2 carbon D-fructose; #5 carbon D-fructose; #4 carbon O L-fructose; #4 carbon
5 a) identify the anomeric carbon in the below molecule b) identify the thpe of ring pyranose or furanose c) identify if it is a or b 6 a) identify the anomeric carbon in the below molecule b) identify the thpe of ring pyranose or furanose c) identify if it is a or b 7 The structure of 6-carbon ketose sugar is shown. Draw the common cyclic structure of this structure (both a and b form) 8 Identify the relationship...
is the following sugar an aldose or ketose? why? what carbon is its anomeric carbon? is this sugar d or l? which structure (a-d) describes its beta- anomer? Н CH OH CH2OH CH OH -оон CH2OH ОН о ОН ₂ ООН ОН ОН ОН HO-31 ОН ОН ОН ОН ОН Нота-Н -Н НА-ОН Н -ОН 6CHOH ОН ОН ОН ОН A в D
1) a. Please draw the structure of the intermediate in the process shown below. CH2OH CH2OH Кон о он КОН OH OH OH OH OH The process shown above is called: c. Please mark an anomeric carbon and designate the orientation of the hydroxyl group. d. Indicate the carbon that determines the D or L configuration in the glucopyranose above by number or with an X. e. Is this a reducing sugar? f. Can it react with another carbohydrate to...
12. Circle each anomeric carbon in the sugars below. (2 points) Which of the sugars below is a reducing sugar? (1 point) Which sugar contains a glycosidic linkage? (1 point) CH-OH носно он н и носн,он они нон glucose fructose он Ин Н CH,он нон носно А он нон но/н,он и онон н sucrose 13. Extra credit: What type of enzyme catalyzes phosphate transfer? What type of enzyme usually catalyzes the rearrangement of a molecule? (2 points each)
Also Which is the anomeric carbon? The structure of the dissaccharide lactose is shown, which is the main sugar found in milk. OH m CH,он OH K O -I KOH XXH VH A Ve OHfCH OH - OH o Identify an acetal carbon in lactose. Identify a hemiacetal carbon in lactose.
Which of the following reaction conditions would specifically target the anomeric carbon of the pyranose below: OH CH OH 20 НО. он HO cal. HCI H20 PaC, H2 II BnBr, NaH DMF, heat III TBDPSCI AgNO, IV HIO CH,COCH, cat. H,SO V cat. HCI CH,OH VII Pd/Baso H VIII VI O VI O O O VII O IV OV VII
3. a) Cellobiose is a disaccharide with two glucopyranose rings connected with a B1-4 linkage. Based on this information, draw cellobiose at right: b) This linkage is similar to which polysaccharide? c) Give a balanced reaction for the hydrolysis of cellobiose. Draw all structures: 4. What type of linkage is in each disaccharide below? Give the number of the each carbon linked in the glycosidic bond, and the a or ß chirality for each anomeric carbon (e.g., a1-4) НО. А...
4. What type of linkage is in each disaccharide below? Give the number of the each carbon linked in the glycosidic bond, and the cor ßchirality for each anomeric carbon (e.g., a1-4) но А —о, он D он CH OH он -о, CH,OH —о, он CH OH Он -о, Р. он он он он он Е CH2OH Он -о, CH OH он -оон он о н он снОн -оон но он он Г но Но, он 9 , CH OH...