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4. (a) Draw the structure of the two chair forms of methylcyclohexane....
(a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even...
(a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why?
(a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even...
(a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why?
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all...
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why? 5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and...
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as...
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as axial or equatorial 10. Draw the most stable chair conformation of the following molecules, and estimate the amount of strain in each: (a) trans-1-Chloro-3-methylcyclohexane (b) cis-1-Ethyl-2-methylcyclohexane (c) cis-1-Bromo-4-ethylcyclohexane (d) cis-1-tert-Butylcyclohexane 11. Which isomer is more stable, cis-decalin or trans-decalin? Explain. 12. Glucose exists in two forms having a 36:64 ratio at equilibrium. Draw a skeletal structure of each, describe the difference between them and...
Which of the statements below correctly describes the chair conformations of cis–1,3–dimethylcyclohexane? a. The two cha...
Which of the statements below correctly describes the chair conformations of cis–1,3–dimethylcyclohexane? a. The two chair conformations are of equal energy. b. The higher energy chair conformation (least stable) contains one axial methyl group and one equatorial methyl group c. The lower energy chair conformation (most stable) contains one axial methyl group and one equatorial methyl group d. The higher energy chair conformation (least stable) contains two axial methyl groups Please show work for the correct answer.
Chair Forms of Substituted Cyclohexanes For each structure or name below, draw both chair forms of...
Chair Forms of Substituted Cyclohexanes For each structure or name below, draw both chair forms of the compound and indicate which of the two is more stable. Consult the table of A values here. 16. 1-tert-butyl-1-methylcyclohexane Ph 19. 17. trans-1,3-dibromocyclohexane 18. Cl 20. OH
PART B: Cyclohexane Procedures: 1. Make a model of cis-1,2-dimethylcyclohexane and trans-1,2-dimethylcyclohexane. Do a ring flip...
PART B: Cyclohexane Procedures: 1. Make a model of cis-1,2-dimethylcyclohexane and trans-1,2-dimethylcyclohexane. Do a ring flip of both *Draw the two conformation of the cis and trans cyclohexane structures above *List the number of axial and equatorial substituents for both the cis and trans *Which isomer is more stable overall, cis or trans? Why? 2. Make a model cis-1,3-dimethylcyclohexane and trans-1,3-dimethylcyclohexane. Do a ring flip *Draw the two conformation of the cis and trans cyclohexane structures above *List the number...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain thes...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial inte...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
How would you draw the most stable conformation of cis-1-ethyl-2-methylcyclohexane? Axial ethyl group on C-1, Axial...
How would you draw the most stable conformation of cis-1-ethyl-2-methylcyclohexane? Axial ethyl group on C-1, Axial methyl group on C-2 Axial ethyl group on C-1, Equatorial methyl group on C-2 Equatorial ethyl group on C-1, Axial methyl group on C-2 Equatorial ethyl group on C-1, Equatorial methyl group on C-2 Choices b and care both correct O Choices a and d are both correct Submit Answer Tries 0/1 How would you draw the most stable conformation of trans-1,4-dimethylcyclohexane? Axial methyl...
(a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why?
(a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why?
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why? 5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and...
9. Draw two different chair conformations of cyclohexanol, showing all hydropen atoms. Identify each position as axial or equatorial 10. Draw the most stable chair conformation of the following molecules, and estimate the amount of strain in each: (a) trans-1-Chloro-3-methylcyclohexane (b) cis-1-Ethyl-2-methylcyclohexane (c) cis-1-Bromo-4-ethylcyclohexane (d) cis-1-tert-Butylcyclohexane 11. Which isomer is more stable, cis-decalin or trans-decalin? Explain. 12. Glucose exists in two forms having a 36:64 ratio at equilibrium. Draw a skeletal structure of each, describe the difference between them and...
Chair Forms of Substituted Cyclohexanes For each structure or name below, draw both chair forms of the compound and indicate which of the two is more stable. Consult the table of A values here. 16. 1-tert-butyl-1-methylcyclohexane Ph 19. 17. trans-1,3-dibromocyclohexane 18. Cl 20. OH
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
11. Build the chair and boat conformations and identify the most stable conformation. Identify the 1,3-diaxial interactions. 12. Draw the most stable conformation of (a) ethylcyclohexane (b) 3-isopropyl-1,1-dimethylcyclohexane (c) cis-1-tert-butyl-4-isopropylcyclohexane 13. Draw all possible conformations of 1,4-dimethylcyclohexane and identify the most stable conformation 14. (a) Draw both chair conformations of cis-1,2-dimethylcyclohexane, and determine which conformer is more stable. (b) Repeat for the trans isomer. (c) Predict which isomer (cis or trans) is more stable. 15. (a) Draw both chair conformations...
How would you draw the most stable conformation of cis-1-ethyl-2-methylcyclohexane? Axial ethyl group on C-1, Axial methyl group on C-2 Axial ethyl group on C-1, Equatorial methyl group on C-2 Equatorial ethyl group on C-1, Axial methyl group on C-2 Equatorial ethyl group on C-1, Equatorial methyl group on C-2 Choices b and care both correct O Choices a and d are both correct Submit Answer Tries 0/1 How would you draw the most stable conformation of trans-1,4-dimethylcyclohexane? Axial methyl...
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