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provide the major organic product for each of the following 12 pp.) ox 2 Na, NH,,...
NO, 00) 1.80.H.SO 2 онкона 3.HO pp.) 2 Na NDIO 1.2.2,0 2 DO XS PCC HO CH ON OH XSHCIO NH إياها NINH w.) OH OH XS Bobbitt's SiO, CH2Cl2 ww.) OH 1. XS KMnONaOH(aq). A 2. H,O* HO 1. NaNO.HCI 2. H,PO (a) CHO NH yy.) NH 1. NaNO, HCl(conc) 2. D.PO 1. LITHF 2. D20 14 aaa) wo NaBHJEICH bbb.) су Cl2 FeBry HO НО. Feb COL) H 1 KM. NOW 2. Ho didd) cleum com) NO 1....
provide the major organic product for each of the following 13 uu.) NaNHẠNH, w.) OH OH XS Bobbitt's SiO2, CH2CH2 ww.) OH 1. XS KMnO4, NaOH(aq), 4 2. H30* HO 1. NaNO2, HCI 2. H3PO3(aq) CH30 NH2 yy.) NH2 1. NaNO2, HCl(conc) 2. D.POZ zz.) 1. Li/THF 2. D20
Provide the major product for the following reactions: T Тѕон EtOH 1. HBO 2. Li, hexane 3. H.CO 4. H,00 Br 1. Mg, THE 2. 요 3. H,0 H2PO4 cat. H OH TOH acetone HO Br 1. PP 2. NaH 3. benzaldehyde 4. H,0 1. KM004. A 2. (COCI)
2. (40 pts, 4 pts each) Prediet-the-products. Draw the major organic product after each series of reactions. You must draw the correct regioisomer and/or stereoisomer for full credit. Some schemes contain more than one step; you do not need to draw the product after each step. Only the final products drawn in the boxes provided will be graded. 1. Brz, CHCI 1. Na, NHI -CHE 2. NaOMe (xs) DMSO 2. mCPBA CHCI 3. H. HSO4 НО. CI Но, Me 1....
provide major organic product(s). watch for stereochemistry. m.) 1. Pr-CI, AICI 2. NBS, CCU A n.) -OH XS HỌCrO4 acetone OH OH XS Bobbitt's SiO2, CH2Cl2 OH P.) 1. Ch. AICI 2. NaOH, 350°C 4,000 psi 3. HCI SCH, -9CH3 2Na, EtOH, NH,
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
predict the major organic product(s) of the following reactions. Indicate stereochemistry ps.) Predict the major organic product or products of the following reactions Indicate stereochemistry of product(s) where appropriate. CHCI 1. BH,THE 2. HÔ , HO, HẠO H-Br H₂O₂ Brz НО
Section 2 Predict the Product/Intermediate for each Organic Reaction Provide only the major organic product(s) formed for each reaction below. (0.5 pt. each) For Stereoisomers: If the reaction is diastereoselective then you must provide the correct relative configuration for the diastereomer(s) formed as a result of the reaction. Br2, CCL 2 eq. (CH3),COK, DMSO DBN Na, Liquid NH Nal, Acetone 2) OH, H202 Draw intermediate 1.0 eq. HB Draw Intermediate HgSo., H2SO., H,0
CONCEPT QUESTION: PREDICT THE PRODUCT Provide the stable organic product(s) that would result for each reaction below. Label the product formed in highest yield as "major" OH OH K2Cr207 H2SO4 acetone 0 OH NaNO3 (2 eq.) AcOH reflux HO 0 PCC (3 eq.) H20 он HO PCC (3 eq.) DCM но K2Cr207 H2SO4 H20 он
VI. Reactions (21 pts) Provide the major product in the following reaction. If no reaction occurs, write "NR as the product. Show your work for each step!! Pay attention to Regiochemistry and Stereochemistry! TSCI EtyN 1. CHg-Br (xs) 2. Ag20, H20, A H-CI Et20 Sold lo no? NaBH CN a. NaNg, EtOH b. H20,4 OH 1. SOCI, pyridine 2. NaN, DMF 3. LIAIH, Et20