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8. Show the transition states and energy diagram that helps rationalize the experimental results below. Br...
8. Show the transition states and energy diagram that helps rationalize the experimental results below. Br...
8. Show the transition states and energy diagram that helps rationalize the experimental results below. Br 5% N н. N + BrLi Li 95% reactants products Which product is lower in energy, the mono or the tri substituted alkene?
7. Draw the energy profile diagram of SN and El reactions. Show all transition states and...
7. Draw the energy profile diagram of SN and El reactions. Show all transition states and products of the reactions.
8. Below is a figure depicting the energy diagram of a reaction. Both uncatalyzed and catalyzed...
8. Below is a figure depicting the energy diagram of a reaction. Both uncatalyzed and catalyzed version of the reaction are shown. Use the figure to answer the following questions. 5 1 AAG (the reduction in AG by the catalyst) G 2 3 A+B=P+Q Reaction coordinate a. Number 4 corresponds to which of the following? a. Products (P+) b. Reactants (A+B) C. Transition state d AG of the reaction b. Which number refers to the energy diagram of the uncatalyzed...
Draw an energy diagram for each of the reactions described below. Properly label each diagram, including...
Draw an energy diagram for each of the reactions described below. Properly label each diagram, including reactants, products, transition state, axis labels, scale (set the reactants at 0 kJ/mol), Delta H, and E_a. Exothermic by 43 kJ/mol; E_a = 95 kJ/mol Endothermic by 15 kJ/mol; E_a = 55 kJ/mol Which of the reactions will occur the fastest? Slowest? Assume equal temperatures, concentrations, and the same rate law for both reactions.) For which of the reactions would the reverse reaction be...
Answer questions 7 and 8) based on this energy diagram 14. Choose the correct structure for:...
Answer questions 7 and 8) based on this energy diagram 14. Choose the correct structure for: trans-1,3-diethylcyclopentane CH.CH CHOM CHCH Energy CHOH B. оцон CH.CH 7. How many transition states are there in this reaction? a. 1 b. c. 4 d. 2 15. Which of these Newman projections show bromine antiperiplanar to one another? H-9 8. What type of reaction is this? a. endergonic b. exergonic c. isogonic d. hypertonic BC 9. Which alkane will have the highest boiling point?...
Please Explain the Answer Question 2 (Parts A-C, 20 points): Use the energy diagrams shown below...
Please Explain the Answer
Question 2 (Parts A-C, 20 points): Use the energy diagrams shown below to answer parts A and B. on Products Rectants Energy Products Reactants Reaction coordinate (a) Highly exothermic reaction Reaction coordinate (b) Highly endothermic reaction A) Does the structure of the transition state in the endothermic reaction resemble that of the reactants or the products? B) Which energy diagram best represents the rate determining step of free radical bromination (Br,, light) of butane: the one...
5) The diagram below represents the energy diagram for the reaction of 1-butyl chloride with water....
5) The diagram below represents the energy diagram for the reaction of 1-butyl chloride with water. On the diagram, draw and indicate the position of each of the following: (0.9 points) a) structures of reactants, products, and intermediates (indicate the position of each on the diagram) b) indicate the positions of all transition states (label as "TS") c) indicate the activation energy of the rate-determining step (label as Ea) Energy Reaction Coordinate 6) Below is an energy diagram that represents...
8. A). Draw a Free energy diagram for each of the following reactions below. In your...
8. A). Draw a Free energy diagram for each of the following reactions below. In your diagram indicate the Free energy of activation (AGⓇ) and the overall free energy change (AGºra) (10 points) B). Determine which side of the equilibrium is favored (products or reactants). (5 points) C). Calculate the relative equilibrium constant for each the reaction. (Hint: use pKas) (5 points) NH2 @NH NaOH HC pk = 27 NH NH2 NaOH H.0 pka 4.6 SI
4. An energy diagram for electrophilic aromatic substitution of benzene with Br2 with FeBr3 as catalyst...
4. An energy diagram for electrophilic aromatic substitution of benzene with Br2 with FeBr3 as catalyst below. The rate-limiting step is formation of the sigma complex (Step 1). Generally, any factor that stabilizes the sigma complex also stabilizes the transition-state leading to that complex. This effect leads to a lower transition-state energy and a faster reaction. rate-limiting transition state reactants + Br + FeBrz Η Br FeBr + O energy intermediate products Br + HBr + FeBr 3 -45 kJ/mol...
9) Circle the correct answer for each of the questions below. e. Which reacts faster in...
9) Circle the correct answer for each of the questions below. e. Which reacts faster in an Syl reaction? a. Which reacts faster in an Sy2 reaction? CHs CH, CH,CHCHCH, or CH,CH,CCHy Br Br Br b. Which reacts faster in an El reaction? d. Which reacts faster in an E2 reaction? Br Br 10)2-bromobutane will react with OCH, in the present of dimethylsulfoxide, DMSO, as a solvent to create 1-butene and 2-butene by an elimination reaction A) Write the chemical...
8. Show the transition states and energy diagram that helps rationalize the experimental results below. Br 5% N н. N + BrLi Li 95% reactants products Which product is lower in energy, the mono or the tri substituted alkene?
7. Draw the energy profile diagram of SN and El reactions. Show all transition states and products of the reactions.
8. Below is a figure depicting the energy diagram of a reaction. Both uncatalyzed and catalyzed version of the reaction are shown. Use the figure to answer the following questions. 5 1 AAG (the reduction in AG by the catalyst) G 2 3 A+B=P+Q Reaction coordinate a. Number 4 corresponds to which of the following? a. Products (P+) b. Reactants (A+B) C. Transition state d AG of the reaction b. Which number refers to the energy diagram of the uncatalyzed...
Draw an energy diagram for each of the reactions described below. Properly label each diagram, including reactants, products, transition state, axis labels, scale (set the reactants at 0 kJ/mol), Delta H, and E_a. Exothermic by 43 kJ/mol; E_a = 95 kJ/mol Endothermic by 15 kJ/mol; E_a = 55 kJ/mol Which of the reactions will occur the fastest? Slowest? Assume equal temperatures, concentrations, and the same rate law for both reactions.) For which of the reactions would the reverse reaction be...
Answer questions 7 and 8) based on this energy diagram 14. Choose the correct structure for: trans-1,3-diethylcyclopentane CH.CH CHOM CHCH Energy CHOH B. оцон CH.CH 7. How many transition states are there in this reaction? a. 1 b. c. 4 d. 2 15. Which of these Newman projections show bromine antiperiplanar to one another? H-9 8. What type of reaction is this? a. endergonic b. exergonic c. isogonic d. hypertonic BC 9. Which alkane will have the highest boiling point?...
Please Explain the Answer
Question 2 (Parts A-C, 20 points): Use the energy diagrams shown below to answer parts A and B. on Products Rectants Energy Products Reactants Reaction coordinate (a) Highly exothermic reaction Reaction coordinate (b) Highly endothermic reaction A) Does the structure of the transition state in the endothermic reaction resemble that of the reactants or the products? B) Which energy diagram best represents the rate determining step of free radical bromination (Br,, light) of butane: the one...
5) The diagram below represents the energy diagram for the reaction of 1-butyl chloride with water. On the diagram, draw and indicate the position of each of the following: (0.9 points) a) structures of reactants, products, and intermediates (indicate the position of each on the diagram) b) indicate the positions of all transition states (label as "TS") c) indicate the activation energy of the rate-determining step (label as Ea) Energy Reaction Coordinate 6) Below is an energy diagram that represents...
8. A). Draw a Free energy diagram for each of the following reactions below. In your diagram indicate the Free energy of activation (AGⓇ) and the overall free energy change (AGºra) (10 points) B). Determine which side of the equilibrium is favored (products or reactants). (5 points) C). Calculate the relative equilibrium constant for each the reaction. (Hint: use pKas) (5 points) NH2 @NH NaOH HC pk = 27 NH NH2 NaOH H.0 pka 4.6 SI
4. An energy diagram for electrophilic aromatic substitution of benzene with Br2 with FeBr3 as catalyst below. The rate-limiting step is formation of the sigma complex (Step 1). Generally, any factor that stabilizes the sigma complex also stabilizes the transition-state leading to that complex. This effect leads to a lower transition-state energy and a faster reaction. rate-limiting transition state reactants + Br + FeBrz Η Br FeBr + O energy intermediate products Br + HBr + FeBr 3 -45 kJ/mol...
9) Circle the correct answer for each of the questions below. e. Which reacts faster in an Syl reaction? a. Which reacts faster in an Sy2 reaction? CHs CH, CH,CHCHCH, or CH,CH,CCHy Br Br Br b. Which reacts faster in an El reaction? d. Which reacts faster in an E2 reaction? Br Br 10)2-bromobutane will react with OCH, in the present of dimethylsulfoxide, DMSO, as a solvent to create 1-butene and 2-butene by an elimination reaction A) Write the chemical...
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