Homework Answers
1. Entropy is the measure of randomness. More gas products means
more randomness and thus more entropy.
In both rxn 1 and rxn 2, the entropy increases as the number of gas
molecules in the product side is more than the reactant side.
so the answer is 2nd option. (Rxn01 and Rxn02).
2.
For endothermic reaction, ΔH=+be and given that ΔS is
negative.
we know ΔG=ΔH - TΔS
clalrly as ΔH is positive and ΔS is negative, because of the -ve
sign of TΔS term, ΔG is always positive in this case.
we also know ΔG is positive means the reaction is always
non-spontaneous.
thus the first option is the answer.
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In which reactions is the AS rxn positive CIO(g) + O2(g) - CI(g) + 2O2(8) RXN...
help please asap please Question 12 (1 point) Which diagram best describes an aqueous son of...
help please asap please
Question 12 (1 point) Which diagram best describes an aqueous son of copper chord Water molecules are omitted for clarity O- FA 09 o Figure Figure D 8098 0.000 Figure E Question 11 (1 point) Which atom is the largest? O carbon O phosphorus silicon nitrogen Question 10 (1 point) For the process O2(g) → 20(g), AH° = 498 kJ.mol-1. What would be the predicted sign of AS rxn and the conditions under which this reaction...
8) HY 8) Consider a reaction that has a negative AH and a positive AS. Which...
8) HY 8) Consider a reaction that has a negative AH and a positive AS. Which of the following statements is true? A) This reaction will be spontaneous only at high temperatures. B) This reaction will be spontaneous at all temperatures C) This reaction will be nonspontaneous at all temperatures. D) This reaction will be nonspontaneous only at high temperatures. E) It is not possible to determine without more information 9) What is the volume of 5.60 g of O2...
Consider the reaction 2N205(a) <-> 4NO2(g) + O2(a) at 25°C for which the following data are...
Consider the reaction 2N205(a) <-> 4NO2(g) + O2(a) at 25°C for which the following data are relevant: AHF N205 11.289 kJ/mol 355.28 J/K mol NO2 33.150 kJ/mol 239.90 J/K mol 02 0kJ/mol 204.80 J/K mol a. Predict the sign of AS for the reaction and explain your reasoning. b. Calculate AS" for the reaction. c. Calculate AH for the reaction. d. Calculate AG for the reaction at 25°C. e. Will the reaction be spontaneous at no temperature, low temperatures only,...
4. Which of the following is consistent with a spontaneous endothermic reaction? (A) AH> 0, AS...
4. Which of the following is consistent with a spontaneous endothermic reaction? (A) AH> 0, AS <0, AG <0 (D) AH<0, AS > 0, AG>O (B) AH > 0, AS > 0, AG <0 (E) AH>0, AS <0, AG>0 (C) AH<0, AS <0, AG<0 5. For the reaction H, (g) +S (8) HS (g), AF- -20.2 kJ/mol and AS = +43.1 J/K mol. Which of these statements is true? (A) The reaction is only spontaneous at low temperatures. (B) The...
3. Predict the sign (positive or negative) on the entropy change for each of these reactions....
3. Predict the sign (positive or negative) on the entropy change for each of these reactions. (a) 2 SO2 (g) + O2 (g) → 2 SO3 (g) Negative (b) 2 NH3 (g) → N2 (g) + 3 H2 (g) (c) CO (g) + 2 H2 (g) → CH3OH (1) 4. For the reaction: 2NO2 (g) + N204 (g) at 298 K, The value of AH° and AS™ are -58.03 kJ and -176.6J/K, respectively. (a) What is the value of AG°...
help with these please N2(g) + O2(g) 2NO(g) Using the standard thermodynamic data in the tables...
help with these please
N2(g) + O2(g) 2NO(g) Using the standard thermodynamic data in the tables linked above, calculate the equilibrium constant for this reaction at 298.15K ANSWER: CH (9) +202(g) →CO2(g) + 2H2O(g) de manera en cas de este mai mare de mise en contact tenda Using standard thermodynamic data at 298K, calculate the free energy change when 1.62 moles of CH4(g) react at standard conditions. AGºrx Nz9) +202(g) +2NO2(g) Using standard thermodynamic data at 298K, calculate the free...
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a...
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a 2 Mg(s) +,(@) 2 Mgo (s) AS b. CH206(s) → 2C,H,OH(I) + 2003(g) AS c. 2 NH3(g) + CO2(g) → H2O(l) + NH CONH3(aq) AS d. Cu(s) (at 100°C) → Cu(s) (at 25°C) AS 2. Which two variables can indicate if a reaction is spontaneous or not? 3. The second law of thermodynamics tells us that: a Energy is conserved. b. The entropy of...
8. For the following reaction, CC2(s) + 2H2O(l) + Ca(OH)2(s) + C2H2(g) which is spontaneous at all temperatures, on...
8. For the following reaction, CC2(s) + 2H2O(l) + Ca(OH)2(s) + C2H2(g) which is spontaneous at all temperatures, one would predict that a. AG is positive for all temperatures. d. AH is - and AS is for the reaction. b. AH is + and AS is for the reaction. e. AH is + and AS' is- for the reaction. c. AH is - and AS is for the reaction. 9. Calculate the standard absolute entropy, in J/mol K. of Mg:...
9. Carbon monoxide (CO) is toxic because it can displace oxygen (O2) from the iron in...
9. Carbon monoxide (CO) is toxic because it can displace oxygen (O2) from the iron in hemoglobin (Hgb) following the reaction: HgbO2 (s) + CO(g) + Hgbco (s) + O2 (g) AG®rx = -30. kl/mol A. Consider the following reactions involving hemoglobin, O2 and Co: Hgboz (s) + Hgb (s) + O2 (g) AG®rxn = 40. kJ/mol HgbCO (s) -- Hgb (s) + CO (6) AGºrx = ??? Using Hess's law, determine the free energy AG*rn (in kJ/mol) for the...
Example Problem Calculate the enthalpy (AH°, ) of combustion of Benzene, CH6. rxn C6H615/2 O2 (8)6CO2 (g) + 3H2O AH...
Example Problem Calculate the enthalpy (AH°, ) of combustion of Benzene, CH6. rxn C6H615/2 O2 (8)6CO2 (g) + 3H2O AH°, [C6H6= 49.0 kl/mol AH°% [CO2(@)= -393 .5 kJ/mol AHO, [H20 = -285.8 kl/mol AH', [O2@= 0 kl/mol
help please asap please
Question 12 (1 point) Which diagram best describes an aqueous son of copper chord Water molecules are omitted for clarity O- FA 09 o Figure Figure D 8098 0.000 Figure E Question 11 (1 point) Which atom is the largest? O carbon O phosphorus silicon nitrogen Question 10 (1 point) For the process O2(g) → 20(g), AH° = 498 kJ.mol-1. What would be the predicted sign of AS rxn and the conditions under which this reaction...
8) HY 8) Consider a reaction that has a negative AH and a positive AS. Which of the following statements is true? A) This reaction will be spontaneous only at high temperatures. B) This reaction will be spontaneous at all temperatures C) This reaction will be nonspontaneous at all temperatures. D) This reaction will be nonspontaneous only at high temperatures. E) It is not possible to determine without more information 9) What is the volume of 5.60 g of O2...
Consider the reaction 2N205(a) <-> 4NO2(g) + O2(a) at 25°C for which the following data are relevant: AHF N205 11.289 kJ/mol 355.28 J/K mol NO2 33.150 kJ/mol 239.90 J/K mol 02 0kJ/mol 204.80 J/K mol a. Predict the sign of AS for the reaction and explain your reasoning. b. Calculate AS" for the reaction. c. Calculate AH for the reaction. d. Calculate AG for the reaction at 25°C. e. Will the reaction be spontaneous at no temperature, low temperatures only,...
4. Which of the following is consistent with a spontaneous endothermic reaction? (A) AH> 0, AS <0, AG <0 (D) AH<0, AS > 0, AG>O (B) AH > 0, AS > 0, AG <0 (E) AH>0, AS <0, AG>0 (C) AH<0, AS <0, AG<0 5. For the reaction H, (g) +S (8) HS (g), AF- -20.2 kJ/mol and AS = +43.1 J/K mol. Which of these statements is true? (A) The reaction is only spontaneous at low temperatures. (B) The...
3. Predict the sign (positive or negative) on the entropy change for each of these reactions. (a) 2 SO2 (g) + O2 (g) → 2 SO3 (g) Negative (b) 2 NH3 (g) → N2 (g) + 3 H2 (g) (c) CO (g) + 2 H2 (g) → CH3OH (1) 4. For the reaction: 2NO2 (g) + N204 (g) at 298 K, The value of AH° and AS™ are -58.03 kJ and -176.6J/K, respectively. (a) What is the value of AG°...
help with these please
N2(g) + O2(g) 2NO(g) Using the standard thermodynamic data in the tables linked above, calculate the equilibrium constant for this reaction at 298.15K ANSWER: CH (9) +202(g) →CO2(g) + 2H2O(g) de manera en cas de este mai mare de mise en contact tenda Using standard thermodynamic data at 298K, calculate the free energy change when 1.62 moles of CH4(g) react at standard conditions. AGºrx Nz9) +202(g) +2NO2(g) Using standard thermodynamic data at 298K, calculate the free...
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a 2 Mg(s) +,(@) 2 Mgo (s) AS b. CH206(s) → 2C,H,OH(I) + 2003(g) AS c. 2 NH3(g) + CO2(g) → H2O(l) + NH CONH3(aq) AS d. Cu(s) (at 100°C) → Cu(s) (at 25°C) AS 2. Which two variables can indicate if a reaction is spontaneous or not? 3. The second law of thermodynamics tells us that: a Energy is conserved. b. The entropy of...
8. For the following reaction, CC2(s) + 2H2O(l) + Ca(OH)2(s) + C2H2(g) which is spontaneous at all temperatures, one would predict that a. AG is positive for all temperatures. d. AH is - and AS is for the reaction. b. AH is + and AS is for the reaction. e. AH is + and AS' is- for the reaction. c. AH is - and AS is for the reaction. 9. Calculate the standard absolute entropy, in J/mol K. of Mg:...
9. Carbon monoxide (CO) is toxic because it can displace oxygen (O2) from the iron in hemoglobin (Hgb) following the reaction: HgbO2 (s) + CO(g) + Hgbco (s) + O2 (g) AG®rx = -30. kl/mol A. Consider the following reactions involving hemoglobin, O2 and Co: Hgboz (s) + Hgb (s) + O2 (g) AG®rxn = 40. kJ/mol HgbCO (s) -- Hgb (s) + CO (6) AGºrx = ??? Using Hess's law, determine the free energy AG*rn (in kJ/mol) for the...
Example Problem Calculate the enthalpy (AH°, ) of combustion of Benzene, CH6. rxn C6H615/2 O2 (8)6CO2 (g) + 3H2O AH°, [C6H6= 49.0 kl/mol AH°% [CO2(@)= -393 .5 kJ/mol AHO, [H20 = -285.8 kl/mol AH', [O2@= 0 kl/mol
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