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11. Predict the major organic product(s) for the following reactions. If there is no reaction write...
11. Predict the major organic product(s) for the following reactions. If there is no reaction write N.R. (6 points each, 72 points total) Show the correct stereochemistry when needed!! -OH HSO heat 1) 0, (2 equiv.) 2) Meys (2 equiv.) HC104 excess CHO NaBH4 (excess) HO CHOH Br ON HỌ, PHÚC
61Sum2020FinalMU.pdf Download Print Save to OneDrive HBr peroxide Br2 (1 equiv.) CH_C2 Br NaOH THE heat Br, H20 1) KMnO4 NаОН НЬО NBS heat hv 2) H0 H30 11. Predict the major organic product(s) for the following reactions. If there is no reaction write N.R. (6 points each, 72 points total) Show the correct stereochemistry when needed!!
2. Predict the structure of the major organic product(s) of following sequence of reactions. Be sure to indicate any relevant stereochemistry. If no reaction is expected, please write N.R. Please place your answers in the box provided. (4 points) mCPBA 1) EtMgBr ether 2) H30*
organic III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 HO H,Cro (excess) -CHO 17 1)0, (2 equiv.) 2) Mezs (2 equiv.) 18 Ph Ph он om Ph Ph 19 1) mCPBA 2) EtONa, EtOH 20 1) LIAIH (excess) 2) H20*, ,0+ 21 1) NaNH, 2) CH,Br 3) HBr (2 equiv.)
III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 H,Cro (excess) -CHO HO 17 1)0, (2 equiv.) 2) Mes (2 equiv.) 18 Ph Ph Ph Ph OH
Predict the Major product(s) for the following reactions and draw their corresponding arrow-pushing mechanisms. If there is no reaction write NR. (21 points total) detailed Show the correct stereochemistry when needed KOH THF substitution Cl Mechanism: MeOH substitution Mechanism: CI t-BuOK, DMF heat elimination Mechanism:
In each reaction Predict the major organic product(s). Where necessary show appropriate stereochemistry and regiochemistry. DO NOT DRAW THE MECHANISM! 1) Br/FeBr 2) Separate p-isomer 3) CH3CH2B(OR)2/PdL2/NaOH 4) KMnO4/NaOH/A 5) H 0 1) Br2/FeBr3 2) Separate p-isomer 5) H30 3) CH3CH2B(OR)2 4) KMnO4/NaOH/A PdL2/NaOH C. C.
predict the major organic product(s) of the following reactions. Indicate stereochemistry ps.) Predict the major organic product or products of the following reactions Indicate stereochemistry of product(s) where appropriate. CHCI 1. BH,THE 2. HÔ , HO, HẠO H-Br H₂O₂ Brz НО
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: 1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: CHCl3 KOC(CH3)3, (CH3)3COH 1. conc. HBr, heat 2. KOBU, HOBU ✓ 1. NaoMe, MeOH 2. BrCN 1. 1 eq. BH3, THE 2. H2O2, NaOH, H20 3. Hg(OAc)2, MeOH 4. NaBH4, NaOH, H20
8. Predict the major product or products for the following reactions. Assume reagents are present in excess amounts unless otherwise indicated. Clearly depict any stereochemistry. "No Reaction" is a possible answer. (4 points) each heat two products HBr ether KMnO4 H30