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draw the structure for the major organic product of each of the following reactions. оо 15....
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) 11. Ç(CH3)3 o 1) CH3CCI, AICI 2) (CH3)2NH H2, Raney-Ni, heat
II. Draw the structure for the major organic product of each of the following reactions. 11. Ç(CH3) 30 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. ÇO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+ 13. o CNH2 1) Br2, NaOH, H20 O 2) (CH3)2CHČCI, pyridine 14. Br2, H20 CHO HOEH H -OH H-OH HOEH CH2OH
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) o 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. CO2Me 1) PhMgBr (2 equiv.) 2) H20, H30+ O 13. CNH2 1) Brą, NaOH, H20 o 2) CH3CCI, pyridine 14. HNO3 CHO HOEH НЕОН H OH HO+H CH2OH 4
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 11. 1) PhČCI, AICI 2) EtNH, H2, Raney-Ni, heat 12. ço Me 1) EtMgBr (2 equiv.) 2) H20, H30*
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 0 11. 1) PhCCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. co Me 1) EtMgBr (2 equiv.) 2) H2O, H30* 13. o CNH, 1) Bra, NaOH, HẠO o 2) (CH3)CHČCI, pyridine 14. CHO Но+н HTOH Br2, H20 н+ОН НО-НН CH OH 4
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 0 11. 1) PhCCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. co Me 1) EtMgBr (2 equiv.) 2) H2O, H30* 13. o CNH, 1) Bra, NaOH, HẠO o 2) (CH3)CHČCI, pyridine 14. CHO Но+н HTOH Br2, H20 н+ОН НО-НН CH OH 4
For each of the following reactions, draw the structure of the major organic product in the box provided. Each numbered set of reagents above or below the arrow represents a complete separate reaction. For multi-step reactions, give only the structure of the final product. КОН (alc) Br b) KOtBu HOtBu Br THE H2SO4 OTS КОН (ale) CH,CH Show Specific Stereochemistry CH(CH3)2 HCI H- CH CH_CH KOH (ale) Show Specific Stereochemistry NaOCH HOCH KO:Bu HOBu
17. Draw the structure of the major organic product(s) for each of the following reactions. Indicate stereochemistry when appropriate. C(CH3)3 NASH Br (S)-2-bromononane - acetonitrile KOH CH,OH NaCN HE Br Acetonitrile C2H5 H, Br NaOH Acetone excess HBr ROOR HC1 + Br Na o DMSO