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Extra Credit II 1) Provide structures for A-J in the following roadmap. H NaN, CHANH, LiAIH...
1) Provide structures for A-J in the following roadmap. H NaN LiAIH SOCI, CHINH + B...
1) Provide structures for A-J in the following roadmap. H NaN LiAIH SOCI, CHINH + B с D- CH,OH (xs) CH,OH E+ A CHOS 1) KOH, H20 2) H,07 NH SOCI 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. CN Oro NaOH H2O are OH
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH...
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
Two pages 30 1) Provide the structure of the major product for ten of the following...
Two pages
30 1) Provide the structure of the major product for ten of the following fifteen reactions. Assume enough reagent to react with all functional groups capable of reaction. NH NaBH,CN 1) MEB 2)H,0 HO NH NaN, 1) NaNO,, H.SO. NH, 2) HBF. KOH 1) odo H30 opas 1) LiAIH, 2) H.O OH h) NH H,SO H.0, A CN 1 cui Oculi O .-780 Br SOCI, NH 1) CHI (xs) 2) Ag,0,H,O, tion N'HSO, H20 Cu_0 Br corond me...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr 1. LIAIH, ether...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr 1. LIAIH, ether 2. H2O Мt. NaOH 2. CH,OH 2. CHỊCH, B pBig H HR 1. LIAJH, other 2. H2O 1. PICHg) 2. Bu-i OH PBrys NaCN1.CHMgBr, ether 2. CHCH 1. LIAIH, other W 2. H20 CH,(excess) NaOH, A HOOCH HOC CHEV → W NaOCH CH3, y CH,CH,OH 2. NHCI Suggest how you would synthesize each of the following from Acetophenone (acetophenone), using any reagents necessary. (Hint:...
tion 5 continued) c. Anthracene is known to act as the diene in Diels-Alder read as...
tion 5 continued) c. Anthracene is known to act as the diene in Diels-Alder read as maleic anhydride as shown below. Draw the str reaction and draw a reasonable mechanism illustrating its comma explanation for the observed regioselectivity. he diene in Diels-Alder reactions with dienophiles such s shown below. Draw the structure of the major product of this nechanism illustrating its formation. Give a brief [4 marks) Propose a detailed mechanism for the following two transformations. Use curved arrows to...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1....
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
2. Provide missing conditions, reactants in the following synthesis. Propose the structures for Products A, B...
2. Provide missing conditions, reactants in the following synthesis. Propose the structures for Products A, B and C. Note: each step consists of more than one transformation. Step 1 in slope fin Step 2 Hint: you can use Br 1. H', ethylene glycol, heat 2. NaOH/H, O, heat 3. H30* Product A Step 3 HCl dilute Product C Product B 1. PhMgBr, ether 2. H20 acetone Step 1: Step 2: Step 3: 3. Show the full mechanism of Step 3...
1. (10 marks the wol 1. (10 marks) The Wolff-Kishner reduction is a method to transform...
1. (10 marks the wol 1. (10 marks) The Wolff-Kishner reduction is a method to transform ketones into alkanes. An example is provided below. step 1 step 2 NH oh oh oh oon HẠN-NH, KOH/H20 A mechanism for the Wolff-Kishner reduction is proposed online at the following website: However, all steps and all electron-pushing arrows are not clearly illustrated in this mechanism. Propose a detailed mechanism with all electron-pushing arrows for both steps of the Wolff-Kishner reduction. Notice the first...
1) Provide structures for A-J in the following roadmap. H NaN LiAIH SOCI, CHINH + B с D- CH,OH (xs) CH,OH E+ A CHOS 1) KOH, H20 2) H,07 NH SOCI 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. CN Oro NaOH H2O are OH
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
Two pages
30 1) Provide the structure of the major product for ten of the following fifteen reactions. Assume enough reagent to react with all functional groups capable of reaction. NH NaBH,CN 1) MEB 2)H,0 HO NH NaN, 1) NaNO,, H.SO. NH, 2) HBF. KOH 1) odo H30 opas 1) LiAIH, 2) H.O OH h) NH H,SO H.0, A CN 1 cui Oculi O .-780 Br SOCI, NH 1) CHI (xs) 2) Ag,0,H,O, tion N'HSO, H20 Cu_0 Br corond me...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr 1. LIAIH, ether 2. H2O Мt. NaOH 2. CH,OH 2. CHỊCH, B pBig H HR 1. LIAJH, other 2. H2O 1. PICHg) 2. Bu-i OH PBrys NaCN1.CHMgBr, ether 2. CHCH 1. LIAIH, other W 2. H20 CH,(excess) NaOH, A HOOCH HOC CHEV → W NaOCH CH3, y CH,CH,OH 2. NHCI Suggest how you would synthesize each of the following from Acetophenone (acetophenone), using any reagents necessary. (Hint:...
tion 5 continued) c. Anthracene is known to act as the diene in Diels-Alder read as maleic anhydride as shown below. Draw the str reaction and draw a reasonable mechanism illustrating its comma explanation for the observed regioselectivity. he diene in Diels-Alder reactions with dienophiles such s shown below. Draw the structure of the major product of this nechanism illustrating its formation. Give a brief [4 marks) Propose a detailed mechanism for the following two transformations. Use curved arrows to...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
Determine the structures of compounds K-Y in the following reaction sequences. NH MgBr Ho 1. LIAIH4, ether 2. HO 1. NaOH → M- Mchu >N 2. CH CH Br 2. CH,OH ola.ompelen 1. LIAIH., ether PBrs > p 1. PICH) » Q" 2. Bu- H R 2. H2O NaCN OH PBrya 1 V 1. LIAIH, ether 2. 0 .CHMgBrother 2. CH,OH Challe CHET (excess) NaOH, a HGG OCH CHO X- NaOCH,CHY CH.CH OH 2. NHCI
2. Provide missing conditions, reactants in the following synthesis. Propose the structures for Products A, B and C. Note: each step consists of more than one transformation. Step 1 in slope fin Step 2 Hint: you can use Br 1. H', ethylene glycol, heat 2. NaOH/H, O, heat 3. H30* Product A Step 3 HCl dilute Product C Product B 1. PhMgBr, ether 2. H20 acetone Step 1: Step 2: Step 3: 3. Show the full mechanism of Step 3...
1. (10 marks the wol 1. (10 marks) The Wolff-Kishner reduction is a method to transform ketones into alkanes. An example is provided below. step 1 step 2 NH oh oh oh oon HẠN-NH, KOH/H20 A mechanism for the Wolff-Kishner reduction is proposed online at the following website: However, all steps and all electron-pushing arrows are not clearly illustrated in this mechanism. Propose a detailed mechanism with all electron-pushing arrows for both steps of the Wolff-Kishner reduction. Notice the first...
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