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Section: 7-11 8. Give the reagents for the following reaction. Write the product for each step....
17. Give the reagents for the following reaction. Write the product for each step. HCECH CH, CH2CH2CH CH, CH.CHOH 18. Give the reagents for the following reaction. Write the mechanism for each step. Br Br HCECH CH.CH -CH2CH3 1 Br Br
16. Give the reagents for the following reaction. Write the product for each step. CH, CH2CH2CECH CH3CH2CH2CHCH2Br :CH, HCH. BY Br
Give the expected major product of reaction of 2,2-dimethyloxacyclopropane with each of the following reagents. Give the expected major product of reaction of 2, 2-dimethyloxacyclopropane with each of the following reagents. dilute H_2SO_4 in CH_3OH NaOCH_3 in CH_3OH Dilute aqueous HBr concentrated HBr CH_3Mgl, then H^+/H_2O C_6H_5Li, then H^+/H_2O
Give the expected major product of reaction of 2,2-dimethyloxacyclopropane with each of the following reagents. Give the expected major product of reaction of 2, 2-dimethyloxacydopropane with each of the following reagents. dilute H_2SO_4 in CH_3OH NaOCH_3 in CH_3OH Dilute aqueous HBr concentrated HBr CH_3Mgl, then H^+/H_2O C_6H_5Li, then H^+/H_2O
12.) Propose a reaction scheme/conditions (all reagents for each step) to synthesize the following product from benzene. (8 points) SO3H
Give the expected major product of reaction of 2,2-dimethyloxacyclopropane with each of the following reagents. Map Give the expected major product of reaction of 2,2-dimethyloxacyclopropane with each of the following reagents (a) dilute H2SO4 in CH3OH (d) concentrated HBr Br ?? ?? (b) NaOCH3 in CH3OH (e) CH3Mgl, then H/H20 ?? ?? (c) Dilute aqueous HBr (f) CeHsLi, then H/H20
11. (8 points) Determine the product at each step in the following reaction and show the mechanism for the first three steps (but not Hz/Lindlar) | 1) xs NaNH, 1) NaNH, CHCI 2) H, 0 2 ) Lindlar Brz Br 12. (4 points) Devise a synthesis and show the mechanism (unless it is hydrogenation or hydroboration) for each product from the given starting material. More than one step is required for each. both products will form
Give the expected major product of reaction of 2,2-dimethyloxacyclopropane with each of the following reagents. (a) dilute H_2 SO_4 in CH_3 OH (b) NaOCH_3 in CH_3 OH (d) concentrated HBr (e) CH_3Mgl, then H_3O^+/H_2O
7. Draw the product of the reaction of n-propanol with each of the following reagents. (3pts) a. SOCI2 b. PBr3
7. Draw the product of the reaction of n-propanol with each of the following reagents. (3pts) a. SOCI b. PBr3