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2. Complete the following reaction: сH,ОН CH₂OH Нt + еңс-он он, ОН 애 Show transcribed image...
15. What is the product of the following reaction? CH,CH,сH-Mgвг Etgo Но Он OH A. В. C. D.
7. What redox coenzyme is most likely to be involved in the reaction below? он O LLL он он CH,-с—сн,-сH-сH,-с-он сH-сн—сн,-снсн,-с-он a. NADPH b. NADP+ c. NAD+ d. FAD e. This reaction does not require a coenzyme.
8. Identify the major substitution product in the following reaction: Br 7 сH, CH;он. HC H 9. Which halide ion would react the fastest with cyclopentyl p-toluenesulfonate (below) in ethanol/water? What would the final product of that reaction be? OTS 10. Draw a detailed mechanism for the following reaction. Hint: The first step is deprotonation of the hydroxyl group. NaOCH; ~ OH NOCH CH;ОН
Examine the following compounds. CH3-CH2-CH2-CH)-CH2-CH3 НО-СН-СН-CH--CH--CH-ОН С A ОН Но-СН--СH-CH-CH--CH-ОН CH--CH-CH-СH--CH-ОН D would be the most soluble in water Structure O A В O C O D
Provide the multistep synthesis for the following reaction. Include reagents: он сн, сH, .CH CH Н.С Н, с
но (CH,),CHBr (CH),CH-OH (е) но (CHJ,СB (CH),C-Он acetone - сн,сH,осH,сн, + Br CH,CH,O' + CH,сH, Br аcctone Br CH,CH,SCH,CH, + CH,CH,S + CH,сң, Br (CH),СBr + кон + KBr (CH],COн ab (CH),CBr + H,о + HBr (CH,),COH CH,OH (CH,),CH-OCH, (CH,),CHBr (h) сHOн (CH),C-ОCH, (CH,),CBr HS Br Br SH +HS +Br SH Br
1. NaH 14. СH3(СH);CH,ОН 2. СH,CH,CH>1I Ао00с HBr 16. CH2 CHCH=CH2 25°C 17. CH3MgBr + CH2CCH L. Et,O 2. H30* OH H2CRO4 18. CH3(CH2)5CCH2CH3 Acetone, 35°C H
Propose an efficient synthesis for the following reaction. - ОН OH
1. Draw the product of each reaction CH сн, CHT CH он OH CHy c ctly Hcl + CH3 сH, -Of + NH2 Ph PhRou H2O Ph -아H Ph d. он +HaO NH2 CH + HC NO2 f HaN Кон CH3 NH2 Но 1-04 9
Consider the following reaction: OH HC H.SO CH, + ОН Δ Show the complete mechanism for the following transformations. Make sure to show all arrows depicting the movement of electrons. The above reaction (using acid and heat) causes a number of unwanted side products to form (a big mess). Propose a better synthesis for the product using the same starting materials. Show the reagents and intermediate steps to complete the synthesis: OH H3C- ??? + CH3 OH X steps Propose...