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4. Predict the products of the following Diels Alle reactions delu, COOCH 01 - COOCH b....
4. Predict the products of the following Diels-Alder reactions: a. C(CH3)3 COOCH Cooch + CH=CHCH COOCH b.
4. Predict the products of the following Diels-Alder reactions: a. C(CH)s COOCH + CH, CHCH, — COOCH b.
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4. Predict the products of the following Diels-Alder reactions: 9.4 CH) a. Соосн. +CH,=CHCH, COOCH b.
4. Predict the products of the following Diels-Alder reactions: ECH соосон, р +снаснен, — сонин осн, -
Predict the product in each of the following Diels-Alder reactions.
Predict the product in each of the following Diels-Alder reactions. Cyclopentadience reacts as a diene in the Diels-Alder reaction a great deal faster than does 1,3-butadience. Explain. Predict the diene and dienophile that would lead to each of the following products.
predict the major products of the following Diels-Alder
reactions showing relative stereochemistry where appropriate.
Diels-Alder СН3 H Diels-Alder + CO2CH3 Diels-Alder CN OCH3
Predict the products of the following Diels-Alder reactions. Include Stereochemistry where appropriate 1. b) heat heat COOH COOH d) OCHa c) heat heat 0. CHO e) heat heat 9) h) 0 CHO heat heat 0
1) Predict the products of the following reactions: COOH CN + COOH NC a) b) 2) Predict the starting materials for the following Diels-Alder product: at 3) Some highly fused ring systems can be made through an intramolecular Diels-Alder reaction. Suggest a mechanism for the following reaction:
If you could show mechanism that would be helpful
4. Predict products for the following reactions. Indicate stereochemistry where available. NC high temperature retro Diels-Alder 5. Draw the MAJOR potential bicyclic Diels-Alder product for the reaction below.
4. What dienes and dienophiles would react to give the following Diels-Alder products 18 pts) 5. Predict the products of the following Diels-Alder reactions. (10 pts) 6. Explain why each compound or ion should be aromatic, antiaromatic, or nonaromatic. (10 pts)