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practice questions
③ show the product on products Expected for the reactions below a) + CH₃OH...
practice complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid +...
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
practice question por ③ continued show product (s) Ķç ----C-C-C-R -15 HC oč -c-c-c-R H₂O H.C...
practice question
por ③ continued show product (s) Ķç ----C-C-C-R -15 HC oč -c-c-c-R H₂O H.C - - - C-C-CAR (Basic Conditions) (soap) NOH p) Hre -15- A (Acidio conditions) Get Fatty Ands ) c-c-co-CH3 98-CHA+ Dering a -10- ester amine A c-c-c is mg Ether it makes Griquand Reagent -15- Bri 2) c-cc * Bonus! 3) ها همه s) -10- mg Br DCOR Grignand Reagent 2) to
3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH CH NH2 amino acid...
3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH CH NH2 amino acid → pH=7 Neotial pH = 3 HCO H C-C-C -Ć-C HA Hao e -100 Chydrolysis) Pac-c- -15- -c-c. ö-c-c H Hal heat (hydrolysic) 0 i) c-c-c-ć H N-CH3 Hag heat 40- H Chucdeolysis)
practice + CH₃-C-C-GH B Continued - show products b) P-6 H H₂ C-Croh NH₂ NH₂ (amino...
practice
+ CH₃-C-C-GH B Continued - show products b) P-6 H H₂ C-Croh NH₂ NH₂ (amino acids) dipeptide ta 11 HC - CGH NH₂ HN ♡ Nite 20 OH diamine diacid dimen os Š IN -a-c-c. io 10: CH3 -c _N-2-8-chu-G - C - 8-CH3 н [ the 1, H heat Total Hydrolysis (show all products)
15. Complete the following alkene preparation reactions. Show only the major product unless otherwise noted. Show...
15. Complete the following alkene preparation reactions. Show only the major product unless otherwise noted. Show stereochemistry where appropriate. b. 2-heptyne- cis-2-heptene c. Ph-C C-C2-CH3 2) NH CI alc KOH d. 2-chloro-1-isopropylcyclohexane CH3 e. CH CH,CH,CHCHCHOCH/CHOH (show all products, label major) alc KOH Br (show all products, label major) alc KOH h. Cl (show all products, label major) Cl KOtBu /tBuOH (show all products, label major)
Please show all work! Will rate high Calculate the concentration of the glutamine anion when 0.50...
Please show all work! Will rate high
Calculate the concentration of the glutamine anion when 0.50 M of glutamine is at a physiological pH of 7.4. The pka of the a-amine group is 9.13. (Answer in mm) Sort the names of each amino acid in this peptide from the N-terminus (top) to the C-terminus. NH HN-C HN-CH, HC-CH H. 0 -NH HC-CH, HN NH 0 o HC-CH, HN но-с NH, H.C HO-CH 0 0 H CH, CH, 0 NH O...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
4. Write out the 10 structure for the following polypeptide: он он HyN-CH-C-N-CH-C-N-CH-COO CH2 CH-OH CH...
4. Write out the 10 structure for the following polypeptide: он он HyN-CH-C-N-CH-C-N-CH-COO CH2 CH-OH CH C-NH2 CH3 COO 5. Illustrate the possible 2° structure interactions in the following polypeptide: R. 6. Identify the type of 3° structure interaction that will occur between the following pairs of amino acids: a) Aspartic acid and lysine b) Serine and tyrosine c) Leucine and valine d) Cysteine and cysteine 7. Draw out the products of the hydrolysis of the following polypeptide: HsN CH-C-N-C-C-N-C-C-N-CH-C-N-CH-COo...
HO CH сн. CH2 нс HC CH3 HAC-HC CH CH CH CH d) OH OH 13....
HO CH сн. CH2 нс HC CH3 HAC-HC CH CH CH CH d) OH OH 13. The labels have fallen off three bottles. Bottle A contains a gas, bottle B contains a liquid, and bottle C contains a solid. The labels indicate that the compounds have the same number of carbon atoms, one being an alkane, one an alcohol, and the other a carboxylic acid. Suggest the identity of the contents of each bottle, and give reasons for your explanation...
Hi I need help predicting the products for these reactions OEt NaOCH.CH CH,CH OH b. H,...
Hi I need help predicting the products for these
reactions
OEt NaOCH.CH CH,CH OH b. H, O/H,0 a. NaOCH.CH CH,CH,OH b. Br c. NaOHH O, beat d. H2O*/H2O 1. NaCN, DMSO 2. CH,MgBr, Eto 3. H.O/H,O EN 2. NaH, CH,Br chemoselective 1. a. NaOet, EtOH Br b. 2. a. NaOH/H,O, heat b. H30+/H20 CY.NECEN cy OH b. then add HC-NH2 a. NaCN, DMSO b. HO*/H,0
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
practice question
por ③ continued show product (s) Ķç ----C-C-C-R -15 HC oč -c-c-c-R H₂O H.C - - - C-C-CAR (Basic Conditions) (soap) NOH p) Hre -15- A (Acidio conditions) Get Fatty Ands ) c-c-co-CH3 98-CHA+ Dering a -10- ester amine A c-c-c is mg Ether it makes Griquand Reagent -15- Bri 2) c-cc * Bonus! 3) ها همه s) -10- mg Br DCOR Grignand Reagent 2) to
3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH CH NH2 amino acid → pH=7 Neotial pH = 3 HCO H C-C-C -Ć-C HA Hao e -100 Chydrolysis) Pac-c- -15- -c-c. ö-c-c H Hal heat (hydrolysic) 0 i) c-c-c-ć H N-CH3 Hag heat 40- H Chucdeolysis)
practice
+ CH₃-C-C-GH B Continued - show products b) P-6 H H₂ C-Croh NH₂ NH₂ (amino acids) dipeptide ta 11 HC - CGH NH₂ HN ♡ Nite 20 OH diamine diacid dimen os Š IN -a-c-c. io 10: CH3 -c _N-2-8-chu-G - C - 8-CH3 н [ the 1, H heat Total Hydrolysis (show all products)
15. Complete the following alkene preparation reactions. Show only the major product unless otherwise noted. Show stereochemistry where appropriate. b. 2-heptyne- cis-2-heptene c. Ph-C C-C2-CH3 2) NH CI alc KOH d. 2-chloro-1-isopropylcyclohexane CH3 e. CH CH,CH,CHCHCHOCH/CHOH (show all products, label major) alc KOH Br (show all products, label major) alc KOH h. Cl (show all products, label major) Cl KOtBu /tBuOH (show all products, label major)
Please show all work! Will rate high
Calculate the concentration of the glutamine anion when 0.50 M of glutamine is at a physiological pH of 7.4. The pka of the a-amine group is 9.13. (Answer in mm) Sort the names of each amino acid in this peptide from the N-terminus (top) to the C-terminus. NH HN-C HN-CH, HC-CH H. 0 -NH HC-CH, HN NH 0 o HC-CH, HN но-с NH, H.C HO-CH 0 0 H CH, CH, 0 NH O...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
4. Write out the 10 structure for the following polypeptide: он он HyN-CH-C-N-CH-C-N-CH-COO CH2 CH-OH CH C-NH2 CH3 COO 5. Illustrate the possible 2° structure interactions in the following polypeptide: R. 6. Identify the type of 3° structure interaction that will occur between the following pairs of amino acids: a) Aspartic acid and lysine b) Serine and tyrosine c) Leucine and valine d) Cysteine and cysteine 7. Draw out the products of the hydrolysis of the following polypeptide: HsN CH-C-N-C-C-N-C-C-N-CH-C-N-CH-COo...
HO CH сн. CH2 нс HC CH3 HAC-HC CH CH CH CH d) OH OH 13. The labels have fallen off three bottles. Bottle A contains a gas, bottle B contains a liquid, and bottle C contains a solid. The labels indicate that the compounds have the same number of carbon atoms, one being an alkane, one an alcohol, and the other a carboxylic acid. Suggest the identity of the contents of each bottle, and give reasons for your explanation...
Hi I need help predicting the products for these
reactions
OEt NaOCH.CH CH,CH OH b. H, O/H,0 a. NaOCH.CH CH,CH,OH b. Br c. NaOHH O, beat d. H2O*/H2O 1. NaCN, DMSO 2. CH,MgBr, Eto 3. H.O/H,O EN 2. NaH, CH,Br chemoselective 1. a. NaOet, EtOH Br b. 2. a. NaOH/H,O, heat b. H30+/H20 CY.NECEN cy OH b. then add HC-NH2 a. NaCN, DMSO b. HO*/H,0
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