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3. Provide a mechanism for the following reactions a) осн. CH, H, A NHCH b) 1)...
1. What will be the products (A-D) in the following aldehyde and ketone reactions ? Hoon 1) SOCI 2) (CH3)2NH A FO сндон, H30* OH B CH H₃C. OH H3C Pyridine H3C CH, с مل CH3NH2, A D 2. Provide IUPAC names for the following compounds (E-G). Name: нас. сн, сн. E Name: H3C CH3 CH3 F Name: HO OH CH3 G 3. Provide a mechanism for the following reactions a) OCH3 CH3NH2, 4 NHCH3 b) FO 1) SOCI 2)...
- 1. Provide a mechanism for the following reactions OCH CH3NH2, A *HH CHI b) 1) SOCI 2) NOSCH,CH, HC ОН - Hic CH CH, MOBI 1 00, 2) H30 OH нор Н.com
What major Organic product is formed after the following sequence of reactions? 1) NaH, THF 2) Br Br B1 (C) (b) Br Bi a. a Considering both regiochemistry and stereochemistry, what is the major Organic product of the following reaction? о ні. CH-CH, НСІ Снон HC "CH; но CH, НО CH, HCO CH-CH; CH «CH-CH, OCH; CH CH3 ОН нс СІ H; Н;С (6) (c) H.CO CH, Kotic CH.CH НО CH; Но CH.CH Сн, НП). CH,CH; ОН нс Н.С осн;...
2. Arrange the following in order of: (i) increasing reactivity with HCI. CH, CH CH H.C=C nec nec 20 cm H.C=C CH HC=C CH, (b) H.C=C NHCH, CHOCH, ОСН, (a) (c) (d) Teast reactive most reactive (ii) increasing stability. CH CH3 CH (a) (C) least stable most stable (iii) increasing heat of hydrogenation. CH,CH, CH=CH2 C H.CH O CH.CH CH3 CH,CH; CH,CH, (0) lowest heat of hydrogenation
Show the mechanism for parts A, B, & C. 1) SOCI 2) NaSCH CH3 о A Н.С. ОН Н.С. SCH3 CH3 сн. OCH, CH3NH2, A NHCH3 MgBr C 1) CO2 2) H30* OH нсо H.CO
3.8. Provide a mechanistic interpretation of the following reactions and observations. a. Show the mechanism for inversion of a hydroxyl site under the Mitsunobu conditions, as illustrated by the reaction of cholesterol. H₃ C C₂H17 Hzc | нс сH17 1) PhaP, HCOH 2) C,H,O,CN=NCO,CH HCO Hgc
(2) Provide the product for the following reactions. + HC=CNa (1)NH,(1), - 330 (2)H,0* CH, COCH, + HC=CMgBr (1) ELO (2)H,0* (3) Place the following carboxylic acids in the order from strongest acid to weakest acid. CF, CH, CH2COOH CF, CH,COOH CF,CH, CH,CH, COOH a. F=-соон -COOH -COOH F b. 0-соон -COOH c.
CH, 7. Give the mechanism of following reactions (10") CH; CH CH,0 H- CH=CH-BT HỌC -CH-CH, + HgC-C=CHCH CHOH ī CHS OCH (1) 1) BrMg(CH2)MgBr.THF OH (2) 2)H30 8. Give the possible synthesis method of following compounds (29) CHE сн.
1. Give IUPAC names for the following compounds: O H.C =CH-C-NH2 H,00 H.CO 2. Draw structures corresponding to each of the given names. Ethyl 4-aminobenzoate acetic formic anhydride 3. What is the order of decreasing reactivity towards nucleophilic acyl substitution for the carboxylic acid derivatives? (most reactive first) H,C-4-0--CHHC-2-N(CH) Hc--OCH, (CH),CH----OCH,
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH