draw final products, mechanisms and intermediates
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draw final products, mechanisms and intermediates c) 1. CH3CH2CI, AICI: 2. KMnO4 3. SOCl2, pyridine 4....
draw final products, mechanisms and intermediates b) # NEN 1. CuCN 2. PhMgBr, Et20 3. H30* workup Cl 4. PPh3
Fll in the structures for the letters 1. NaCN C 2. LiAlH4 3. Hot NBS B hv 1. NaN3 D CH4Cl 2. LiAlH4 3. H30* A AICI: O KMnO4 SOCl2 1. LiAlH(O+Bu); E C1 F pyridine 2. Hz0+ HCl cat. C + F G pH 4-5 NaBH(OAc); C + F H AcOH HCl cat. D + F pH 4-5
1) Reactions. Provide the major products for each reaction sequence, account for stereochemistry 1) KMnO4, A 2) SOCI, CH2Cl2 3) 2 equiv. 1) ethylene oxide, THF 2) H3O+ workup Culi 3) DIBAL-H, THF 4) H3O+ workup 5) cat. TsOH, THF H3CCHE (c) HN COH 1) excess LAH, THE 2) H30+ workup 3) 1 equiv. EtN, DMF 4) pyridine i ( " culi , THF (d) PC Ph 2) H3O+/H2O workup 3) KMnO4, A 4) CH,OH, cat. H2SO4 5) cat. TsOH,...
Predict the product of the following reaction. 1. CH3CH2CI, AICI: 2. KMnO4, -OH 3. H3O+
(a) 2 1. -OH, H2O H 2.H307, heat (b) CI AICI: (c) SH HS H2SO4 (d) OH 1. Na Cr 07, H2SO4 2. SOCl2, pyridine 3. excess (CH2CH2)2NH excess (e) (f) Br2, H30*
4. Draw the mechanisms for the followino reartions to nredict the products Clus AICI
VI. Draw the major products for the synthetic sequence below. Do not show any intermediates or mechanisms sequence (4 pts): AICl, 2 Ho VII. Draw the major products for the e synthetic sequence below. Do not show any intermediates or mechanisms below (4 pts): AICI, Br FeBry ci Predict the major product and show the mechanism for reaction below; draw your structures legibly (4 pts): VIIl. FeCl +C Page 5 of 14
please help 3. Draw the major product of the final step of the following scheme in the box provided. 1. NBS, ROOR or NBS, cat AIBN, CCls, heat 2. DBN 3. Hydroboration-oxidation 4. PBr3 5. Mg, Et2o 6. PhCHO, then workup 7. Jones reagent 8. PhLi, Et O, then H30 9. TsOH, heat 10. NBS, HOH 11. NaOH (intramolecular SN2) 12. MeMgBr (excess), then workup 13. E2 14. HBr 15. Mg, ether 16. dry ice, then workup 17. LiAlH4, ether,...
3. Provide the intermediates/products for the following reactions. 3. Provide the intermediates/products for the following reactions 1. BH3. THF 2. H20s NaOH, H2O CH3 1·LDA,-78°C, THF 4. H2O 1. Na CroO HSO, HO 2. SOCl2 Bn
give organic products + SOCl2 KMnO4 1) CO2 2) H30* СОН + NaOH он ㄚ CH3CH2OH H30