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19 1) mCPBA 2) MeOH,H 20 1) LIATH (excess) 2) H20+, H30+ 21 1) NaNH, 2)...
19 1) mCPBA 2) MeOH,H 20 1) LiAlH4 (excess) og 2) H20+, H30+ 21 1) NaNH2 2) CH3CH2Br 3) HBr (2 equiv.)
19 1) mCPBA 2) MeOH,H 20 1) LiAlH4 (excess) og 2) H20+, H30+ 21 1) NaNH2 2) CH3CH2Br 3) HBr (2 equiv.)
HELP PLEASE ANSWER ALL III. Predict the major product(s) or fill in the reagent(s) for the following reactices. If there is to reaction write NR. (6 points each, 16 points total) Show the correct stresshemistry when needed!! 16 H.CO (excess) CHO HO 17 10 (equiv.) 2) Mes (2 equis.) 18 OH o" 19 1) mCPBA 2) EXON, EICH 20 1) LIAIR (excess) io 2) H 0,1,0 21 1) SNI, 2) CH, Br 3) HBr (2 equiv.) 22.Draw DETAILED arrow.pushing mechanisms...
15. H.Pd 16. 17. 17. H3C 1) NaNH, 2) CH CH,Br 3) Lindlar's H2 18. 1) KMnO4(aq) warm, OH 2) H30+ 19. -CH3 excess Br? 20. 1) 1 equiv. HBr. peoxides 2) HCI
organic III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 HO H,Cro (excess) -CHO 17 1)0, (2 equiv.) 2) Mezs (2 equiv.) 18 Ph Ph он om Ph Ph 19 1) mCPBA 2) EtONa, EtOH 20 1) LIAIH (excess) 2) H20*, ,0+ 21 1) NaNH, 2) CH,Br 3) HBr (2 equiv.)
Br Br excess NaNH, HBr, 2-equiv. Bry, 2-equiv. CH3Br NaBH4 PBr3 Hz. Lindlar cat. BH/THF NaOH. HBr, 1-equiv. Brz, 1-equiv. H30*
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20 refux 9- NH2 CH -C-Cl 10. 2.HaO кон. rMso 12- CH3 CH Ch 13- NH2 14- -78C 15- OH LiAIH 4 16- socl2 2 pyridine P2Os NH2 18- 1. NaHCO.. H2O 2. OH Br 19. 2, H30 20- 1. BH4 2. H3O 21- 22- 2. PBr 3.2 equiv. CH,CH CH&NH 23- 1. Mg Br 3. NaHCO Cl 24- 2 LAH 25-
2. Predict the product. CH,CH NH2 NH 1. LiAlH 2. H20 Br H30 KOH 1. excess CH1 2. Ag20, H20 heat
In each reaction box, place the best reagent and conditions from the list below. M 1) Bra 2) 2 equiv. NaNH, HBO 3) 4) H.O., NaOH, H20 BHYTHF CHOBI Hz. Lindlar catalyst bromocyclohexane H30. H SOL. HgSO4 NaBHA CH CH Br excess NaNH3, then H20 SOCI
Organic Chem Ch 11 worksheet Name Homework #7 20 Points Due 11/20/19 1) Name the following (6 points) NH2 он 2) Draw the following (4 points) (1R)-1-bromo-N-methylpentan-1-amine (2R)-2-cyanopropanoic acid 3) What are the products and mechanisms for both products? (4 points) HBr Thermodynamic Kinetic 4) Fill-in the Boxes (6 points) НCL Br Only Products Br 1) LDA (2X) 2) H2SO4, HgSO, H20 НВr, -80°C One Product