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QUESTION 1 Using the curved arrow formalism, outline an acceptable mechanism for the acid catalyzed electrophilic...
Using the curved arrow formalism, outline an acceptable mechanism for the acid catalyzed electrophilic addition of water to 1-Methylcyclohexene as shown below. Your mechanism should show the movement of all electrons involved in bond forming and bond breaking steps as well as all formal charges for atoms that are not neutral. CH HOH H
Using the curved arrow formalism, outline an acceptable mechanism for the acid catalyzed electrophilic addition of water to 1-Methylcyclohexene as shown below. Your mechanism should show the movement of all electrons involved in bond forming and bond breaking steps as well as all formal charges for atoms that are not neutral CH, H-O-H H
Using the curved arrow formalism, outline an acceptable mechanism for the acid catalyzed electrophilic addition of water to 1-Methylcyclohexene as shown below. Your mechanism should show the movement of all electrons involved in bond forming and bond breaking steps as well as all formal charges for atoms that are not neutral. CH *** H-O-H H
Write a curved arrow mechanism for the acid catalyzed Fischer esterification of benzoic acid in CH3O*H (that is 0-18 labeled methanol). Show all steps, lone pair of electrons, charges and labeled O atoms through the mechanism.
4. (22 points) "Fun in acid" question: Draw a reasonable mechanism using the curved-arrow formalism (include lone pair electrons) for the following rearrangement reaction of an arene oxide in the presence of dilute aqueous sulfuric acid to give the corresponding phenol. What is the thermodynamic driving force for the conversion of the arene oxide into the phenol? Hint: 4-steps H2SO4 HO in excess: used as solvent) "Fun in acid" question: Draw a reasonable mechanism using the curved-arrow formalism (include lone...
The electrophilic aromatic substitution of isopropylbenzene with FeBr3, Br2 gives 1-bromo-4-isopropylbenzene. Complete the curved-arrow mechanism below, beginning with formation of the active brominating reagent. Remember to include lone pairs and formal charges where appropriate. The electrophilic aromatic substitution of isopropylbenzene with FeBr3, Br2 gives 1-bromo-4-isopropylbenzern Complete the curved-arrow mechanism below, beginning with formation of the active brominating reagent. Remember to include lone pairs and formal charges where appropriate. Draw the pro Overall transformation (ungraded) bromine and FeBr3 Include curved arrow(s)....
2. (5 pts) Draw out the mechanism for the acid-catalyzed dehydration shown below. Include all steps, clearly show all charges, and all unshared electron pairs. Use curved arrows to show electron movement in all making and breaking of bonds. NOTE: To show the breaking of a bond you must draw the bond explicitly so that you can clearly draw an arrow from the electrons in the bond. : OH Q" - W H;0* -H;0
“Fun in acid” question: Draw a reaction mechanism using the curved-arrow formalism (include lone pair electrons) for the conversion of an ester into an alcohol and a methyl ester in the presence of acid in excess methanol. Hint: 6-steps.
“Fun in acid” question: Draw a reaction mechanism using the curved-arrow formalism (include lone pair electrons) for the following transesterification of an ester into an alcohol and a methyl ester in the presence of acid in excess methanol. Hint: 6-steps. H+
6. "Fun in base" question: Draw a reaction mechanism using the curved-arrow formalism (include lone pair electrons) for the conversion of methyl salicylate into the corresponding conjugate base of salicylic acid and methanol in the presence of excess aqueous hydroxide. Hint: The first step is an acid- base reaction. H20 осни + он o + CH OH (in excess; used as solvent) ОН Be sure you explain acid-base chemistry and use appropriate PK, values in steps 1 and 4. Compound...