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Predict the major product for each of the following reactions. Assume that each reagent is available...
1. Name each of the following b. а. .H CI 2. Provide the major product(s) of the following reactions. a. 1. NABH4, EtOH 2. Hао* н b. 1. CH3CH2MgCI, Etyo H2 2. H3O* Pt с. 1. HNO3, H2SO 2. H2, Ni 3. NANO2, HCI, H2O 4. KI 3. Provide the missing reagent(s) for the following reactions. осн, O a. CH3O но b. NCH
What is the major product is this reaction sequence? Cl2, hv 5 Hg(OAc)2, H20 NaBH4 Br2 NaOET EtOH FeBr3 OH OH OH ot Br Br Br A B с D ΟΑ B D Which is the major product of this reaction? CN 1. EtMgBr 2. acid workup one OH or one A B с D B оооо What is the major product of this reaction? 1. aq. NaOH 2. acid workup NH он for HN. NH но. он NH2 -он...
What ie the major organic product of the following sequence of reactions? What is the major Organic product of the following sequence of reactions? он о ОН Н Br (а) (b) 1) 2 equiv Kон меон, а 2) Haso, H,So4. Но Br ОСН с ОН (0 (4) (е) b.b с. с d. d е, с f, f
predict the major product of the following reactions: H2, Pt E CH=CH2 CH3 d2 az но CH3 Hz Pd CH3 нс н с с н Сн, CHCl3 КОН 1. О, сна, 270, HOẶC
19.54 predict the major product(s) from the treatment of acetone with the following: 19.54 Predict the major product(s) from the treatment of acetone with the following: (a) [H*1, NH3, (-H2O) (b) [H*], CH3NH2, (-H2O) (d) [H*], (CH3)2NH, (-H2O) (c) [H*], excess ETOH, (-H2O) (e) [H*], NH2NH2, (-H2O) (f) [H*1, NH2OH, (-H2O) (g) NaBH4, MeOH (h) RCO3H (i) HCN, KCN () EtMgBr followed by H2O (k) (C&Hs)3P=CHCH2CH3 (I) LIAIH4 followed by H2O
organic III. Predict the major product(s) or fill in the reagent(s) for the following reactions. If there is no reaction write NR. (6 points each, 36 points total) Show the correct stereochemistry when needed!! 16 HO H,Cro (excess) -CHO 17 1)0, (2 equiv.) 2) Mezs (2 equiv.) 18 Ph Ph он om Ph Ph 19 1) mCPBA 2) EtONa, EtOH 20 1) LIAIH (excess) 2) H20*, ,0+ 21 1) NaNH, 2) CH,Br 3) HBr (2 equiv.)
predict the major products a. РСС HO b. 1. LIAIH4 2. HзО* ОН С. OsO4, (CH3)3COOH (СH3)3СОН, НО- d. NABH4, EtOH e. 16 1.Et2O 2. H30* + CH3CH2MgBr f. H2SO4 OH 2 heat h. ОН HIO4 -OH i. OTs KSH
Which of the following reactions would not normally yield an alcohol? A. Oxymercuration/ de mercuraction of alkenes B. Hydroboration of alkene C. Reaction of a carboxylic acid with NaBH4 D. Reaction of ketone with a Grignard reagent Which set of reagents is the best to perform the following transformation? OH step(s) A. PCC; CH2MgBr, POCIz/pyridine B. tosyl chloride; CH3MgBr C. PBrz; Mg(0); CH31 D. CrOz/H3O+; NaBH4, CH MgBr 1) excess LiAIHA 2) Н,0* І, Но но- Но он но- он...
Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. Mechanism SN2 SN1 НО. HBr 0°С, НаО E2 Е1 Mechanism ОН SN2 SN1 H2SO4 Е2 Е1 Mechanism SN2 SN1 HBr D rt, H2O E2 Е1 ОН
6. Predict the major product for the following reactions. PhCOH ово. Но. Но, не Но, не H₂ Pi 어 Only а. но 04 Hz Pd Ons Н нс с с н оо. КОН он, to, сно. ZZA, HOẶC