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ch 22 In both series below the three aromatic compounds illustrated undergo the electrophilic substitution reaction...
TRUVIOw Topics (References] In both series below the three aromatic compounds illustrated undergo the electrophilic substitution reaction shown O=0 C- H CH2CH2CH2CH3 Reaction: Chlorination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? _ OCH3 OCH3 NO2 NO2 Reaction: Nitration Which compound (A, B, or C) reacts the fastest? – Which compound (A, B, or C) reacts the slowest? –
(Review Topics] (References) In both series below the three aromatic compounds illustrated undergo the electrophilic substitution reaction shown CH3 CH3 NO2 NO2 NO2 , Reaction: Nitration Which compound (A, B, or C) reacts the fastest? - Which compound (A, B, or C) reacts the slowest? - D D OCHZ COH Reaction: Chlorination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? _D
h both series below the three aromatic compounds ilhestrated undergo the electrophilic substitution reaction show NHCCHE A B Reaction: Bromination Which compound (A, B, C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? O OCH COH A B C Reaction: Chlorination Which compound (A, B, or C) reacts the fastest? Which compound (A, B, or C) reacts the slowest? h both series below the three stomatic compounds ilhestrated undergo the electrophilic substitution reaction shown -C-CH2CH3 OH...
Indicate, by letter(s), the position(s) on the ring at which substitution occurs when the aromatic compounds shown undergo bromination with Brz, FeBrz (when necessary). CN a b С NO2 a NO2 Indicate, by letter(s), the position(s) on the ring at which substitution occurs when the aromatic compounds shown undergo bromination with Br2, FeBrz (when necessary). SO3H 5 a b С 6 Br c a Br
r each compound below, identify which position(s) is/are most likely to undergo an electrophilic aromatic substitution reaction? Circle the carbon that undergoes electrophilic substitution. (3) b. CH NO2 O2N What Wittig reagent and carbonyl compounds are used to synthesize the following compound? (2) c. (CH3CH2)2C-cHCHCH2CH3 Write the equations to convert benzene to the following compounds? Some conversions need more than one step. (10) 3. a. Toluene b. m-bromo nitrobenzene c. Benzene sulfonic acid d. Aniline e. Benzoic acid r each...
Electrophilic Aromatic Substitution The most common reactions of aromatic compounds involve the substitution of other atoms or groups for a ring hydrogen: Fech + CI chlormation + Br FeBry bromination HNO3 H,SO nitration (HONO) H,SO sulfona (HOSO,H) AICH + RC- alkylation H,80 + CH=CH alkylation + RCCI - acvlation CH2CH2CH2CH3 Oxidation KMnO4 Ho CH3 Reduction Hy. Pt: ethanol 130 atm, 25 "C CH3
What isare) the product(s) of the following reaction? CH + CHECH,CH,CI Alch CH,CH(CH, a mixture of C.H.CH.CH,CH, and CH.CH(CH)2 CH.CH.CH.CH C.H.CH,CH.CH,C1 Where would the compound shown below undergo bromination with NBS and benzoyl peroxide? meta position on ring 1 C(2) position on ring 2 ortho/para position on ring 1 methyl group on ring 2 Which of the following aromatic compounds reacts faster than benzene in electrophilic aromatic bromination? Which of the following is the best method to make n-butylbenzene? A)...
6. (9 pts) In regards to an electrophilic aromatic substitution reaction, define the 3 compounds shown below as either: a) Activating, ortho, para director b) Deactivating, ortho para director, c) Activating, meta director, d) Deactivating, meta director. CH -ОН -N-CH3 CH3 7. Answer a-c for compounds A-F below dos a. (5 pts) Which compound(s) have an aromatic carbocation intermediate if it underwent an Snl or E1 reaction? b. (5 pts) Which compound(s) would have an anti-aromatic carbocation intermediate if it...
Which compound is the least reactive in the aromatic electrophilic substitution reaction? What product would you expect from the following reaction? Answer both, please. 1. Which compound is the least reactive in the aromatic electrophilic substitution reaction? NH . B NH С. SOH Logo D. NO2 E 2. What product would you expect from the following reaction? CO.CH ÇO.CH А ÇOCH B OCH, D CO.CH E
In an electrophilic aromatic substitution reaction, which group is both ortho, para directing and ring deactivating? of Select one: O -NH2 O-SO3H O-1 0 -CN O-OCH3