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5.5. Place the methyl groups by drawing the axial and equatorial positions on the cyclohexane structure...
Please make hand writing neat. Thank you:) 12. Construct cis-1,3-dimethylcyclohexane by placing both -CH, groups in...
Please make hand writing neat. Thank you:)
12. Construct cis-1,3-dimethylcyclohexane by placing both -CH, groups in the axial Which is the more positions. Do ring flips and examine the two chair conformations. stable conformation? Explain your answer (12) 13. Construet trans-1,3-dimethylcyclohexane by placin g one- CH3 group axial and the other equatorial. Do ring flips and examine the two chair conformations. the more stable conformation? Explain your answer (13a). Given the two1 trans-1,3-dimethylcyclohexane and cis-1,3-dimethyleyc stable isomer? Explain your answer...
of 9 Select the statement about equatorial and axial positions in cyclohexane that is correct Each...
of 9 Select the statement about equatorial and axial positions in cyclohexane that is correct Each face of the chair conformation of cyclohexane ring has three axial and three equatorial hydrogens in an alternating pattern. OTwo substituents on the same face of the ring that are not adjacent to each other will be trans. Two substituents on the same face of the ring, one of which is axial and one that is equatorial with be trans to each other. OEach...
20. Name these compoands CHy 21. Draw chair structures for each of these compounds. Label cach...
20. Name these compoands CHy 21. Draw chair structures for each of these compounds. Label cach substituent as axial or equatorial. trans-1,2-intethylcyclohexane cis-1.2-dimetlylcyclohexane 22. Draw a chair conformation of cyclohexane with one CH,CH: gruup and ene Clls group that fits cach description. 1,1-disubstituted cyclohexane with an axial CHCH: group cis-1,2-disubstituted cyeloliexane with an axial CHs group trans-1,3-disulstituted cyclohexane wilh an equatorial Cli, group trans-1,4-disubistituted cyclohexane with an equatorial CHCiH: group
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all...
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why? 5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and...
Using the table below, calculate the difference in energy between a) the lowest energy conformations of...
Using the table below, calculate the difference in energy between a) the lowest energy conformations of cis- and trans-1,2-dimethylcyclohexane. b) the highest and lowest energy conformations of methyl cyclohexane, trans-1,2-dimethylcyclohexane and cis-1,3-dimethylcyclohexane Type of Strain Interaction Associated Energy Eclipsing of a pair of H's 4kj/mol Eclipsing of a H and a CH3 group 6kj/mol Eclipsing of a pair of CH3 groups 11kj/mol Gauche (60) Interactin between CH3 Groups 3.8 kj/mol 1,3 CH3 to H Interaction on Cyclohexane Chair 3.8kj/mol 1,3...
Q11. The correct structure of trans-1-bromo-3-methyl cyclopentane is ...Br (A) (B) -Br Br (C) (D) *Br...
Q11. The correct structure of trans-1-bromo-3-methyl cyclopentane is ...Br (A) (B) -Br Br (C) (D) *Br Q12. The correct order of increasing stability for the following conformations is CH, H Н. Н H H H CH2CH3 H Н CH,CH CH CH3CH2 CH H2C CH, H CH, I II III (A) III < III (C) II <I<III (B) I<III <II (D) I< II < III Q13. Identify the relationship between the following two Newman projections. CH, H НАС. H Н;С. Н...
The cyclohexane derivative shown exists primarily in the more stable of the two available chair conformations. Give the position, axial or equatorial, of each of the three groups shown in the more st...
The cyclohexane derivative shown exists primarily in the more stable of the two available chair conformations. Give the position, axial or equatorial, of each of the three groups shown in the more stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CH-CH2 CI Group...
Laboratory Work 1. Draw the skeletal formulas and make models of the three constitutional isomers of...
Laboratory Work 1. Draw the skeletal formulas and make models of the three constitutional isomers of C5H12. 2. Draw Kekule structures and make models of all the constitutional isomers of C2H4Cl2. 3. Draw Kekule formulas and make models of ethane, ethene, and ethyne. How does the geometry of their structures differ? Which compound contains sp hybridized carbons? 4. Draw and label the Newman projection and make the model of the anti-conformation of 1,2-dibromoethane. Rotate around the carbon-carbon bond...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain thes...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
Is it axial, equatorial, or ax/eq? The cyclohexane derivative shown exists primarily in the more stable...
Is it axial, equatorial, or ax/eq?
The cyclohexane derivative shown exists primarily in the more stable of the two available chair conformations. Give the position, axial or equatorial, of each of the three groups shown in the more stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq. The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for...
Please make hand writing neat. Thank you:)
12. Construct cis-1,3-dimethylcyclohexane by placing both -CH, groups in the axial Which is the more positions. Do ring flips and examine the two chair conformations. stable conformation? Explain your answer (12) 13. Construet trans-1,3-dimethylcyclohexane by placin g one- CH3 group axial and the other equatorial. Do ring flips and examine the two chair conformations. the more stable conformation? Explain your answer (13a). Given the two1 trans-1,3-dimethylcyclohexane and cis-1,3-dimethyleyc stable isomer? Explain your answer...
of 9 Select the statement about equatorial and axial positions in cyclohexane that is correct Each face of the chair conformation of cyclohexane ring has three axial and three equatorial hydrogens in an alternating pattern. OTwo substituents on the same face of the ring that are not adjacent to each other will be trans. Two substituents on the same face of the ring, one of which is axial and one that is equatorial with be trans to each other. OEach...
20. Name these compoands CHy 21. Draw chair structures for each of these compounds. Label cach substituent as axial or equatorial. trans-1,2-intethylcyclohexane cis-1.2-dimetlylcyclohexane 22. Draw a chair conformation of cyclohexane with one CH,CH: gruup and ene Clls group that fits cach description. 1,1-disubstituted cyclohexane with an axial CHCH: group cis-1,2-disubstituted cyeloliexane with an axial CHs group trans-1,3-disulstituted cyclohexane wilh an equatorial Cli, group trans-1,4-disubistituted cyclohexane with an equatorial CHCiH: group
4 4. (a) Draw the structure of the two chair forms of methylcyclohexane. Draw in all bonds (even the C-H bonds). Be sure the axial and equatorial bonds are shown correctly. On the appropriate structure, indicate the 1,3-diaxial interactions involving the methyl group. (b) Which is more stable, trans-1,3-dimethylcyclohexane or cis-1,3-dimethylcyclohexane? Why? 5. Draw the Newman projections for the anti conformation and two types of eclipsed conformations of 1,2-diiodoethane. Of the two eclipsed conformations, which is of higher energy, and...
Q11. The correct structure of trans-1-bromo-3-methyl cyclopentane is ...Br (A) (B) -Br Br (C) (D) *Br Q12. The correct order of increasing stability for the following conformations is CH, H Н. Н H H H CH2CH3 H Н CH,CH CH CH3CH2 CH H2C CH, H CH, I II III (A) III < III (C) II <I<III (B) I<III <II (D) I< II < III Q13. Identify the relationship between the following two Newman projections. CH, H НАС. H Н;С. Н...
The cyclohexane derivative shown exists primarily in the more stable of the two available chair conformations. Give the position, axial or equatorial, of each of the three groups shown in the more stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for answering this question. CH-CH2 CI Group...
6. Build the cyclobutane ring and study the angle strain and torsional strain. Draw the structures to explain these factors. 7. The conformation of cyclobutane is slightly folded. Folding gives partial relief from the eclipsing of bonds, as shown in the Newman projection. Compare this actual structure with the hypothetical planar structure. Draw the relevant structures. 8. trans-1,2-Dimethylcyclobutane is more stable than cis-1,2-dimethylcyclobutane, but cis-1,3- dimethylcyclobutane is more stable than trans-1,3-dimethylcyclobutane. Use the molecular models to find the reasons for...
Is it axial, equatorial, or ax/eq?
The cyclohexane derivative shown exists primarily in the more stable of the two available chair conformations. Give the position, axial or equatorial, of each of the three groups shown in the more stable chair conformation. If a group divides its time equally between axial and equatorial positions, indicate this with ax/eq. The table of "Axial Strain Energies for Monosubstituted Cyclohexanes" found in the "Strain Energy Increments" section of the Reference tool is useful for...
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