Using Ideal Gas equation: PV = nRT
Where P = Pressure, V= Volume, n= no. of moles, R = Universal Gas Constant, T = temperature
Given:
P = 1 atm = 101325 Pa
V = 50 cm3 = 50 * 10-6 m3
T = 200C = 293 K
PV = nRT
101325 * 50 * 10-6 = n * 8.314 * 293
n = 2.08 * 10-3 moles
In step 2, the pin is reinserted so it’s a isochoric process
In isochoric process V = constant
Which implies P/T = constant. It can be written as P1/T1 = constant
1*101325/293 = 3*101325/T2
T2 = 879 K
Since its an isochoric process, V2 = 50 cm3
Work done in isochoric process is always zero i.e. = Wisochoric = 0 J
Calculation of amount of heat energy absorbed by the gas
Q = mCp∆T = (n * MW)(5/2 R)(879-293)
Q = (2.08 * 10-3 X 28)(5/2 * 8.314)(586)
Q = 709.36 J
Therefore the amount of heat energy absorbed by the gas is 709.36 J
Calculation of change in thermal energy of the gas
By first law of thermodynamics: Q – W = ∆E
Q – 0 = ∆E
∆E = 709.36 J
Therefore the change in thermal energy of the gas is 709.36 J
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