3. Which cyclohexane molecule would you consider to be
the most stable?
a.2
b. 1
c. 4
d. 3
4. The molecules below are:
a. meso compounds
b. structural isomers
c. dual comformers
d. diastereomers
most stable conformation of cyclohexane is the chair form shown in figure 1. The C-C-C bonds are very close to 109.5o, so it is almost free of angle strain. It is also a fully staggered conformation and so is free of torsional strain.
3. Which cyclohexane molecule would you consider to be the most stable? a.2 b. 1 c....
9. C (Z-2-hexene d. They are all of equal stability. Choose the most stable alkene among the following a 1-hexene b. (E)-2-hexene 10. What is the relation between an enantiomer's configuration and its specific rotation? (a) Rcompounds usually are dextrorotatory with few exceptions (b) R compounds always are dextrorotatory. (c) There is no relation. (d) R compounds always are levorotatory 11. How many chiral centers are there in tartaric acid, and how many different stereoisomers exist for this acid? он...
Which of the following structures is most stable? 2) How many stereoisomers does the molecule below have? (СН), С+ снен снаси сна OH CH₃ br. a) 3 6) 4 c) 6 d) 8 e 9 3) Which of the following molecules below are chiral? 0) to A Boh A MOH HOS DBr e) 1, 2 and 3 a) Only 1 b) 1 and 3 c) 2 and 3 d) 1 and 3 What is the relationship between the following two...
Which cyclohexane molecule would you consider to be the most stable? Н H -H Н Н Н -Н 1 2 3 Н Н 4 Н Н — Н 2 4 3 1
1. Which of the following molecules has the lowest strain energy? a. Cyclobutane b. Cyclohexane c. Cycloheptane d. Cyclopropane 2. Which of the following arranges the groups in order of decreasing priority according to the sequence rules? a. CH3 > CH2CH3 > CH2OH > CO2H c. CH2OH > CO2H > CH2CH3 > CH3 b. CH3 > CH2CH3 > CO2H >CH2OH d. CO2H > CH2OH > CH2CH3 > CH3 3. Which of the following structures represent a meso compound? a. b....
3. Identify the relationship between the pairs of molecules shown below as either: the same molecule, diastereomers, enantiomers, or epimers. (3 points each) CH2OH СНОн он но -н H-OH он OH он OH OH OH H2OH CH2OH 4. Draw the Line Angle formula for the products of the following reactions. (4 points each) Cu+2 -Cu2O(s) + + но -н CH2OH Ht, heat OH HO heat
7. What is the relationship between these two compounds? CHO CH OH H HH HE A. The compounds are identical. B. The compounds are enantiomers. C. The compounds are diastereomers. D. The compounds are structural isomers. нонс OHC 8 What is the relationship between these two compounds? соон COOH H- ci CH A. The compounds are identical. B. The compounds are enantiomers. C. The compounds are diastereomers. D. The compounds are structural isomers. CH CH3 CH,OH CH, OH 9. What...
H 9. For each molecule: 1) Identify all possible enantiomers and distinguish those that are enantiomers, diastereomers and meso compounds. II) Assign the absolute configuration of chiral carbons in each molecule OCH3 HO+Br HS+CN H2N-CH3 HOSH Он HO+CH3 н OCH3 Сн, ососна Br +D HOCH HC-BrHN+Br CH 8. For the following compounds, assign the absolute configuration for those with chiral carbons and identify those that are NOT enantiomers HO C-C-OHY -CCIN 13CH3 HAN CH3 CH3 осі H-CH3 H2N+CH H O+COOH...
HELP tatMtiele Cheice 2.0peints.each Which of the fellowing structures is mest stable? How many stereaisomers does the molecule below have? 2) CH)HCtCH CHCH CH3 CH2 br OH e) 9 d) 8 c) 6 b)4 al 3 Which of the follewing molecules below are chiral? 3) HO Ho e) 1, 2 and 3 a) Only 1 d) 1 and 3 b) 1 and 3 c) 2 and 3 What is the relationship between the following two compounds? 4 сн, H- H...
5.50 For each molecule in Problem 5.49, identify all chiral centers that exist. Which of those molecule 5.51 Draw each of the following molecules in a zigzag conformation. (a) CH,он (b) CH3 (c) (d) CN Но HO=O -H но- -OH -H H -OH OH ОН Н- -Cl OH Н- но но -H - CH3 но- CH2OH H но- CO2H CH,он CH2CI WOT I
QUESTION 7 Identify the relationship between the two molecules below. сно он н он н -сно H-OH HOH сн,он A. Diastereomers B. Constitutional isomers C. Enantiomers D. Same molecule E. Same molecule & meso