Consider a metal atom surrounded by a cube-shaped arrangement of eight ligand atoms (Oh symmetry). (1)...
Consider a metal atom surrounded by a cube-shaped arrangement of eight ligand atoms (Oh symmetry). (1) Derive the reducible representation for the 8 σ-bonds. (2) Systematically (step-by-step) reduce this representation to its irreducible representations – showing all of your calculations! (3) Which (s, p or d) metal orbitals have the same symmetry as these irreducible representations? (4) Why do we not observe this coordination arrangement?
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Consider a metal atom surrounded by a cube-shaped arrangement of
eight ligand atoms (Oh symmetry). (1)...
Could you show how to do (d) step by step, please? AO = Atomic orbital MO = Molecular orbital (L)GO= (Ligand) Group orb...
Could you show how to do (d) step by step, please?
AO = Atomic orbital
MO = Molecular orbital
(L)GO= (Ligand) Group orbital
2. TaHs has a square pyramidal geometry and a Cev symmetry. (a) Assign x, y, z coordinates on the atoms: - Z axis on central Ta atom is the principal rotation axis (z axes on other atoms are colinear) - X, y axes on central Ta atom match Ta-H bonds (x, y axes on other atoms are...
i can't solve this question of coordination chemistry, could someone hlep me please Exercise 1: 1. What kind(s) o...
i
can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
Could you show how to do (d) step by step, please?
AO = Atomic orbital
MO = Molecular orbital
(L)GO= (Ligand) Group orbital
2. TaHs has a square pyramidal geometry and a Cev symmetry. (a) Assign x, y, z coordinates on the atoms: - Z axis on central Ta atom is the principal rotation axis (z axes on other atoms are colinear) - X, y axes on central Ta atom match Ta-H bonds (x, y axes on other atoms are...
i
can't solve this question of coordination chemistry, could someone
hlep me please
Exercise 1: 1. What kind(s) of interaction between the ligand and the metal ion is(are) considered in the crystal field approach? 2. Give and justify the degeneracy lifting for a tetrahedral complex. Would it be the same for an octahedral complex? 3. Let us consider hexaaquacopper(II) ion. Justify the elongation of two opposite Cu-O bonds (along z for example) compared to the other four Cu-O bonds using...
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