Draw the product for each of these three mutli-step reactions A. 1. Propanol + KMnO4...
Draw the product for each of these three mutli-step reactions
A. 1. Propanol + KMnO4 2. Reaction with Methyl Amine 3. Reduction with LiAlH4
Final Product formed:
B. 1. Butyl amine treated with excess CH3I followed by
reaction with Ag2O and Heat.
Final Product formed:
C. 1. propanal treated with NaCN 2.
Treatment of the alkoxide formed with CH3I.
3. Hydrolysis of the nitrile to form an acid
Final Product formed:
Homework Answers
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Draw the product for each of these three mutli-step
reactions
A. 1. Propanol + KMnO4...
Question 4: Starting with 2-methyl-1-propanol, draw the organic product formed when treated with the following reagents:...
Question 4: Starting with 2-methyl-1-propanol, draw the organic product formed when treated with the following reagents: OH 2-methyl-1-propanol a) H.SO,, heat HCI c) 1) TsCl, py PBr 2) NaSH
4. Draw the expected major product that results from each of the following SN2 reactions S. Na os , nor — WC'Nano,...
4. Draw the expected major product that results from each of the following SN2 reactions S. Na os , nor — WC'Nano, — Br + NaNz + NaCN CI. e) [ .. f) HY O + NaCN +NaNg H 5. Explain why treatment of 1-propanol with NaBr fails to give 1-bromopropane, but treatment of 1- propanol with HBr does give 1-bromopropane. NaBr Br HBT ~ Br 6. Propose a mechanism for the following reaction excess H-Br
Which one of the following series of reactions does not produce a primary amine? O 1)...
Which one of the following series of reactions does not produce a primary amine? O 1) LiAlH4 (excess) 1) Fe, HCI, H2O 1) LiAIH4 (excess) A) PhCN B) PhNO2 C) PhNHCCH? 2) H20 2) NaOH, H2O 2) H20 O H2, Raney-Ni NaOH, H20, heat D) PhCHENH E) PENHÖCH Which of the following amines cannot be made by reduction of a nitrile? PhCH2NH2 EtNH2 (CH3)2CHCH2NH2 Me3CCH2NH2 A B C D Ph2CHNH2 E
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic...
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenyl ketone) and benzaldehyde + KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (f) acetanilide and LiAlH4 in diethyl ether, followed by addition of water.
9. Predict the product(s) for the following reaction. excess HBr heat B. 1-propanol+ bromoethane E. none...
9. Predict the product(s) for the following reaction. excess HBr heat B. 1-propanol+ bromoethane E. none of these C. 1-propanol+ ethanol A. ethanol+ 1-bromopropane 10. What is the IUPAC name for the following compound? 0 A. 3-ethyl-2-methyloxirane D. I-ethyl-2-methyloxypentane B. 2-ethyl-3-methyloxirane E. none of these C.2 -ethyl-1-methyloxypentane 11. Predict the product for the following reaction. (E)-2-pentene+ mCPBA A. I D. IV 12. Predict the product for the following reaction + enantiomer A. I D. IV 13. Predict the product(s) for...
1) Draw the acetal produced when ethanol adds to ethanal. 2) Draw the major organic product formed when...
1) Draw the acetal produced when ethanol adds to ethanal. 2) Draw the major organic product formed when 2-butanone undergoes a reaction with NaBH4. 3) Predict the organic product formed when heptan-3-one undergoes reaction with LiAlH4. 4) Reduction of 1-phenylpropan-1-one using NH2NH2 and HO-, heat: Draw the structure of the product formed when 1-phenylpropan-1-one is heated with NH2NH2 under basic conditions.
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyri...
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyridine Ig 1) NaH; 2) CH3CH2Br b NaH e PBr3 h 1) TSCI, pyridine; 2) NaSH c HBr f TsCl, pyridine 3. Draw the organic product formed when l-methylcyclohexanol is treaded with each reagent. In some cases, no reaction occurs. a KH c HBr Te NaHCO3 b Nacid HCI f 1) KH; 2) CH3CH2Br Draw two different routes to each of...
Help me please as soon as possible i need the solutions for those questions s, show structures of reac the products for both reactions. a) What is/are the product(s) of the treatment of 3-methyl-1-but...
Help me please
as soon as possible
i need the solutions for those questions
s, show structures of reac the products for both reactions. a) What is/are the product(s) of the treatment of 3-methyl-1-butene with aqueous acidic What is/are the product(s) of the treatment of 2-methyl-2-butene with aqueous basic KMnO4? b) 36) (3 pts each) Predict the products (name and structure) from reaction of 3-hexyne with the following reagents: a) H2, Lindlar catalyst b) Li in NH3 c) HgSO4, H2SO4...
For each of the following reactions supply the missing starting material(s) or final organic product(s) in...
For each of the following reactions supply the missing starting
material(s) or final organic product(s) in the bobxes provided.
HO Ph 1) LiAlH4 2) H20 Me Me Mel Br2 H30 1) PBr3, Br2 2) H20 OH excess NaOH 1) excess Br2 2) H30 Reaction Name:
3x. A. Write out the structure of the product of the following reaction. 1.) CH3O Na...
3x. A. Write out the structure of the product of the following reaction. 1.) CH3O Na CH2OH 2.) HCI B. Write out the complete mechanism for the above reaction. C. What will be the product of the reaction if the product formed in step A Is treated with aqueous hydroxide followed by acid and heat? D. What structural feature is required for these reactions to go to completion?
Question 4: Starting with 2-methyl-1-propanol, draw the organic product formed when treated with the following reagents: OH 2-methyl-1-propanol a) H.SO,, heat HCI c) 1) TsCl, py PBr 2) NaSH
4. Draw the expected major product that results from each of the following SN2 reactions S. Na os , nor — WC'Nano, — Br + NaNz + NaCN CI. e) [ .. f) HY O + NaCN +NaNg H 5. Explain why treatment of 1-propanol with NaBr fails to give 1-bromopropane, but treatment of 1- propanol with HBr does give 1-bromopropane. NaBr Br HBT ~ Br 6. Propose a mechanism for the following reaction excess H-Br
Which one of the following series of reactions does not produce a primary amine? O 1) LiAlH4 (excess) 1) Fe, HCI, H2O 1) LiAIH4 (excess) A) PhCN B) PhNO2 C) PhNHCCH? 2) H20 2) NaOH, H2O 2) H20 O H2, Raney-Ni NaOH, H20, heat D) PhCHENH E) PENHÖCH Which of the following amines cannot be made by reduction of a nitrile? PhCH2NH2 EtNH2 (CH3)2CHCH2NH2 Me3CCH2NH2 A B C D Ph2CHNH2 E
2. Identify the principal organic product of each of the following reactions: (30 pts) (a) acetic anhydride and 2-pentanol (b) 4-methyl-3-penten-2-one and ammonia in water solution (c) acetophenone (methyl phenyl ketone) and benzaldehyde + KOH in ethanol solvent (d) methyl butanoate and LDA (lithium diisopropylamide) in THF solution, then ethyl iodide (e) butylamine and excess 1-iodobutane (f) acetanilide and LiAlH4 in diethyl ether, followed by addition of water.
9. Predict the product(s) for the following reaction. excess HBr heat B. 1-propanol+ bromoethane E. none of these C. 1-propanol+ ethanol A. ethanol+ 1-bromopropane 10. What is the IUPAC name for the following compound? 0 A. 3-ethyl-2-methyloxirane D. I-ethyl-2-methyloxypentane B. 2-ethyl-3-methyloxirane E. none of these C.2 -ethyl-1-methyloxypentane 11. Predict the product for the following reaction. (E)-2-pentene+ mCPBA A. I D. IV 12. Predict the product for the following reaction + enantiomer A. I D. IV 13. Predict the product(s) for...
Hc VCH Draw the organic product formed when CH3CH2CH2OH is treated with each reagent. a H2S04 (180°C) d SOC12, pyridine Ig 1) NaH; 2) CH3CH2Br b NaH e PBr3 h 1) TSCI, pyridine; 2) NaSH c HBr f TsCl, pyridine 3. Draw the organic product formed when l-methylcyclohexanol is treaded with each reagent. In some cases, no reaction occurs. a KH c HBr Te NaHCO3 b Nacid HCI f 1) KH; 2) CH3CH2Br Draw two different routes to each of...
Help me please
as soon as possible
i need the solutions for those questions
s, show structures of reac the products for both reactions. a) What is/are the product(s) of the treatment of 3-methyl-1-butene with aqueous acidic What is/are the product(s) of the treatment of 2-methyl-2-butene with aqueous basic KMnO4? b) 36) (3 pts each) Predict the products (name and structure) from reaction of 3-hexyne with the following reagents: a) H2, Lindlar catalyst b) Li in NH3 c) HgSO4, H2SO4...
For each of the following reactions supply the missing starting
material(s) or final organic product(s) in the bobxes provided.
HO Ph 1) LiAlH4 2) H20 Me Me Mel Br2 H30 1) PBr3, Br2 2) H20 OH excess NaOH 1) excess Br2 2) H30 Reaction Name:
3x. A. Write out the structure of the product of the following reaction. 1.) CH3O Na CH2OH 2.) HCI B. Write out the complete mechanism for the above reaction. C. What will be the product of the reaction if the product formed in step A Is treated with aqueous hydroxide followed by acid and heat? D. What structural feature is required for these reactions to go to completion?
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