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synthesis questions, please explain! 13. (10 pts.) Fill in the missing reagents or product in the...
Fill in the missing products or reagents (above blank arrows) for the following reaction schemes. No charged species should be drawn anywhere in this assignment. Acidic workup steps are assumed and are NOT explicitly included. Scheme 1: 10 pts EC- H2 KMnO4 Lindlar OH O ملتين NAOMe MeOH Scheme 2:12 pts 1) LDA H2O MgBr 2) O H2SO4 NaH Br LINHA mCPBA
13. (15) For each a For each of the following reactions, fill in the missing reagents from the list provided for Wormation of the product shown. Sequential steps, if necessary. should be numbered. Reagents can be used more than once. Reagent List: H2 C H2O2 = NaH PBT OCI NaBH. Pd/C NaOH BH2O HO HgCl2 Pd/Caco, Br2 HBr H2O (HOAC) (MCPBA) (pyridine) (Msch) por -Cl menos de plaqueta don -он i н он
(10 pts) Fill in the missing intermediates (two), final product, and reagents (two) in the llowing multistep synthesis. Br X OH -- NH 에 CH,Br 6) (5 pts) Write out the 3-step arrow pushing mechanism showing how cyclopentanol is dehydrated to make cyclopentene: он conc. H,SO + HO heat
Question 3 (20 points) – Fill in the missing reagent, reactant, or product V 1) CH,CVAICI, 2) KMnO4/H2SO4 3 SOCI, CI(3 eq) FeCl2 1) (CH2CH2),Culi 2) H,O/H3O+ Michael Acceptor PCC i. 1) KOC(CH):/HOC(CH): 2) mCPBA الد 3) CH,MgBr 4) H2O/HO* NH A 1) NH, TH,SO4 (cat.) 2) NADH 1) 2) 3)
13. Reactions: Fill in the missing products for each of the boxes in the following reaction sequences. (30) OH Na2Cr2O7 H2SO4 H2O PCC NaBH HOCH, PBr3 Br2, H20 NaH BrMg- 2. H2O* NaOEt 1. OsO4 2. NaHSO3
Fill in missing reagents 12. Fill in the missing reagents or products in the following scheme. (14 pts) Ma OH HCI NaOE! NaOEL
missing reagents, please explain 9. (20) For each of the following reactions, fill in the missing reagents for the formation of the product shown. Sequential steps. numbered. Reagent List: reagents from the list provided s necessary, should be HyC-Br Nah NaOH H,C- CH ( MCI) HBECH,OH Br-Br O=C=0 HOÀc) (LDA) 041 H2o depromat ΝΛΗ noad to Nattpostele Br Br-Brz H3C H-BK H4C1-NH2 H3C H,C CH, Br H2C+NCHE HEC CH2 LOA B
13.) Provide a synthesis for the target molecule shown. (18 pts)product. (6 pts) Bonus: (10 pts) Starting from Benzene and using reagents that we have discussed in class, design a synthesis for the Target molecule (TM) 13. Provide a synthesis for the target molecule shown. (18 pts) go alcohol aketone OH СОН M 얘 SM omgBr =sin 1-2 OH => KongBros Naz6.2010 H2SO4, H2O & H300 q Etmaira H20 어 #C=, 2° alcohol, aldehyde 20 TM o o #C77, Ketore...
give the missing reagents or products or reactants. also for letter C give me an arrow pushing mechanism with the name of the synthesis. please be serious with your answer кон но ΕΙΝΗ, H2SO4 SOCI CH,C12 Na NH.. Etон 1) Brz PBry Na Cro H2SO4 so 2) H.O and 2 x H202 ACOH NH HO NH H2SO4 HgSo. HO H2SO4 CH2CH2
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH . (E2) 1.BH 2. H2O NaOH, HÔ PCC HB/ROOR how many stereoisomers? how many stereoisomers? PCC Excess H2O H CH2C12 HB Nal SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 HO H2SO mCPBA NaOEt (E2) H2SO4 (cat) don't worry about this reaction OH OH KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH Рcc CH2C12 HI (SN1)