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Fill in the blank boxes. H-Br 1 equiv Kinetic conditions OMe + heat Meo H* catalyst...
-NH2 PCC, CH2Cl2 NaBH CN OH 8 Br 1. 3 equiv. 12 4 equiv. NaOH 1....
-NH2 PCC, CH2Cl2 NaBH CN OH 8 Br 1. 3 equiv. 12 4 equiv. NaOH 1. LiAlH4 2. H2O 2. H30* 9 10 2 equiv. (CH3)2NH 1. LiAIH 2. H20 11 12 H2O 1. CH,MgCI 2. H30 13 14
*b. CN O TSCI, pyridine oh Teci, pyridine -OH cd* H2, Lindlar catalyst CA H3C-CEC-CH3 1...
*b. CN O TSCI, pyridine oh Teci, pyridine -OH cd* H2, Lindlar catalyst CA H3C-CEC-CH3 1 equiv HI * och Teade + HOCH order + HOC 2 products NaH *. HOCHCHBr *g.LA BH3 + OH POCl3, pyridine Ocach 2 -CEC-H 1. BH3 2. H2O2, OH
Give the major organic product(s) of the following reaction. CH2CH2CH2Br (1 mole) Name CH3OH heat OH...
Give the major organic product(s) of the following reaction. CH2CH2CH2Br (1 mole) Name CH3OH heat OH Me Meo Y ome OMe Meo OMe OH 0 0 0 HO There is no reaction under these conditions or the correct product is not listed here. Give the major organic product of the following reaction. NaOme CH3CH Br | NaOH, H2O H30+ CH2OH heat heat heat HOX OH - Co₂H 0 0 Meo ОMe ОН Meo ОMe но тон Оснон There is no...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as appropriate. Do not forget to include stereochemistry as appropriate unless specified otherwise. 2. Hgo :0: :o 1. Na* CN 2. H30* /heat gnore stereochemistry c) :Br: :OH d) 1 Equiv H3C CI: e) Ph h) heat (Aldol reaction)
2) Fill in each of the following boxes with the structure of the major reaction product(s)...
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. (28 points total). a) Pd(PPhale NaOH b) + Pd(OA) (CH CHN CN 1. NaBH 2. H2O HH OH но -н H- OH HH OH CH,OH HNO, но NH,OH trace of acid 1. CHI (excess 2. Ag,0 H2O, heat CI 1 CRUS POY Grubbs catalyst) Page 2 of 5
Fill in the reaction's reagents/ products 1) KOH H, H2O سینه Heat 2) Ph-CH2-Br 1) 2x...
Fill in the reaction's reagents/ products
1) KOH H, H2O سینه Heat 2) Ph-CH2-Br 1) 2x MgBr اللہ H 2) H20 PhCuli H Heat
OH 1. NaOCHZ 2. H20 CO2H acid catalyst hint: - BuOH 1 2 NaOH, H2O heat...
OH 1. NaOCHZ 2. H20 CO2H acid catalyst hint: - BuOH 1 2 NaOH, H2O heat 1. (CH3)2CuLi, ether 2. H30* H 3 1. NaOCH3 u 1. H307 2. heat 2. Br Br 5 6
Fill the missing reagents/products in each box 1) KOH H, H20 vilion Heat 2) Ph-CH2-Br 1)...
Fill the missing reagents/products in each box
1) KOH H, H20 vilion Heat 2) Ph-CH2-Br 1) 2x MgBr rich 2) H20 H* Ph2Culi ou H Heat
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20...
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20 refux 9- NH2 CH -C-Cl 10. 2.HaO кон. rMso 12- CH3 CH Ch 13- NH2 14- -78C 15- OH LiAIH 4 16- socl2 2 pyridine P2Os NH2 18- 1. NaHCO.. H2O 2. OH Br 19. 2, H30 20- 1. BH4 2. H3O 21- 22- 2. PBr 3.2 equiv. CH,CH CH&NH 23- 1. Mg Br 3. NaHCO Cl 24- 2 LAH 25-
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't need to...
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't need to necessarily fill all the boxes, but if you don't use them all, fill from the top down. Unused boxes can be left empty. Br CH3CH2CH2Li 1. BH3-THF; 2. NaOH, H2O2, H2o Hg2+, H2O, H+ KCN, HCN H20, H+ CH3OH, H+ NaOH, H2O 1. (Sia 2BH; 2. NaOH, H2O2, H2O PhLi HOCH2CH2OH, H+ Nothing Needed PCC PhMgBr CH3CH2NH2, H+ H2Cr04 KCN NaBH4, MeOH (CH3CH2CH2)2Culi CH3CH2MgBr...
-NH2 PCC, CH2Cl2 NaBH CN OH 8 Br 1. 3 equiv. 12 4 equiv. NaOH 1. LiAlH4 2. H2O 2. H30* 9 10 2 equiv. (CH3)2NH 1. LiAIH 2. H20 11 12 H2O 1. CH,MgCI 2. H30 13 14
*b. CN O TSCI, pyridine oh Teci, pyridine -OH cd* H2, Lindlar catalyst CA H3C-CEC-CH3 1 equiv HI * och Teade + HOCH order + HOC 2 products NaH *. HOCHCHBr *g.LA BH3 + OH POCl3, pyridine Ocach 2 -CEC-H 1. BH3 2. H2O2, OH
Give the major organic product(s) of the following reaction. CH2CH2CH2Br (1 mole) Name CH3OH heat OH Me Meo Y ome OMe Meo OMe OH 0 0 0 HO There is no reaction under these conditions or the correct product is not listed here. Give the major organic product of the following reaction. NaOme CH3CH Br | NaOH, H2O H30+ CH2OH heat heat heat HOX OH - Co₂H 0 0 Meo ОMe ОН Meo ОMe но тон Оснон There is no...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as appropriate. Do not forget to include stereochemistry as appropriate unless specified otherwise. 2. Hgo :0: :o 1. Na* CN 2. H30* /heat gnore stereochemistry c) :Br: :OH d) 1 Equiv H3C CI: e) Ph h) heat (Aldol reaction)
2) Fill in each of the following boxes with the structure of the major reaction product(s) from each of the following reactions. (28 points total). a) Pd(PPhale NaOH b) + Pd(OA) (CH CHN CN 1. NaBH 2. H2O HH OH но -н H- OH HH OH CH,OH HNO, но NH,OH trace of acid 1. CHI (excess 2. Ag,0 H2O, heat CI 1 CRUS POY Grubbs catalyst) Page 2 of 5
Fill in the reaction's reagents/ products
1) KOH H, H2O سینه Heat 2) Ph-CH2-Br 1) 2x MgBr اللہ H 2) H20 PhCuli H Heat
OH 1. NaOCHZ 2. H20 CO2H acid catalyst hint: - BuOH 1 2 NaOH, H2O heat 1. (CH3)2CuLi, ether 2. H30* H 3 1. NaOCH3 u 1. H307 2. heat 2. Br Br 5 6
Fill the missing reagents/products in each box
1) KOH H, H20 vilion Heat 2) Ph-CH2-Br 1) 2x MgBr rich 2) H20 H* Ph2Culi ou H Heat
1. PCC CI 3. Cl2 H,0, heat 7- け 3. на, но 8- CH-CH HBr H20 refux 9- NH2 CH -C-Cl 10. 2.HaO кон. rMso 12- CH3 CH Ch 13- NH2 14- -78C 15- OH LiAIH 4 16- socl2 2 pyridine P2Os NH2 18- 1. NaHCO.. H2O 2. OH Br 19. 2, H30 20- 1. BH4 2. H3O 21- 22- 2. PBr 3.2 equiv. CH,CH CH&NH 23- 1. Mg Br 3. NaHCO Cl 24- 2 LAH 25-
Slide appropriate reactants into the boxes to conduct the following synthetic transformation. You don't need to necessarily fill all the boxes, but if you don't use them all, fill from the top down. Unused boxes can be left empty. Br CH3CH2CH2Li 1. BH3-THF; 2. NaOH, H2O2, H2o Hg2+, H2O, H+ KCN, HCN H20, H+ CH3OH, H+ NaOH, H2O 1. (Sia 2BH; 2. NaOH, H2O2, H2O PhLi HOCH2CH2OH, H+ Nothing Needed PCC PhMgBr CH3CH2NH2, H+ H2Cr04 KCN NaBH4, MeOH (CH3CH2CH2)2Culi CH3CH2MgBr...
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