Question

A mixture of two monatomic ideal gases consists of Na molecules of gas A and Na molecules of gas B in a container of volume V at temperature T. (a) Obtain an expression for natural log of the number of the accessible microstates for each species (ie, ln S, and In Ω), (b) Show that the entropy of the mixture system is 4. EA and Ea are the total energies for the two molecular species, m, and m , the atomic mass of each kind. (c) Prove that fundamental relation for a two component systems, Tds- dE+ PdV-H,AN-dN, where p, and p, are chemical potentials for the two species, respectively, prove that the as k. (d) From the generalized e Derive os an expression d( dT = T-1 ). (25 points) for the heat capacity under constant volume (i.e., C,-

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312 NA 2 NA , NA mu lan 3% h NB2 Ks (NA

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