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(13). if we look to the Rxn: S2O8 (aq)3 1 (aq) 2SO4 (aq) + I3 (aq)...
Find the values m , n and the over all order of reaction? (13). if we look to the Rxn: 2- 2- S2Os(aq)3 I (aq) 2SO4 (aq) I3 (aq) 2-m Rate k [S2Os1" [I 1" We can write the rate of reaction as: Experimental Data for this Reaction are: Initial Conc.,M Initial rate Expt. S20s2 S2Os0.038 [S2Os212=0.076 S2O0.060 -1 Ms [I] [I] 0.060 [I 12=0.060 Ri 1.4 x10 1 R2-2.8 x10 2 R3 4.4x10 [I ]3=0.120 3 Find the values...
S2O8^-2(aq)+3I^-(aq)--2SO4^-2(aq)+I3^-(aq) S2O8^-2. I^- rate 0.018M. 0.018M. 2.6*10^-6 0.018M. 0.036M. 5.3*10^-6 0.072M. 0.036M. 2.12*10^-5 a. write the rate law for this reaction including the reaction order for each reactant b. calculate the value of k c. calculate the Rate of the concentration when [S2O8^-2]= 0.2500M and [I]= 0.120M
37. The data below were determined for the reaction shown below. The rate law for this reaction 12 Marks must be: s2or" + 31-(aq)-25042-+13- Initial Rate 1.4 × 10-5 M/s 2.8 × 10-5 MS 1.4 x 10-5M/s 0.060 0.060 0.030 0.038 0.076 0.076 2 a. Rate kIS 0s I] b. Rate kIS20s IUT *d. Rate = k[S2082-11
I have a reaction that has three elementary steps: 3I- +S2O82- ---> I3- + 2 SO42- (this is the RLS) I3 + 2 S2O32- ---> 3 I- + S4O62- starch + I3- ---> starch - I3- complex. (color change to indicate rxn is over) In multiple trials I change the concentrations to see its effect on the rate of the rxn. But the reagents I'm using in this rxn are: (1) starch, Na2S2O3 , KI, KNO3 , and (2) (NH4)2S2O8...
The oxidation of bromide ion by persulfate is given by the equation: S2O82–(aq) + 3Br–(aq) 2SO4–(aq) + Br3–(aq) What is the rate law for this reaction based on the following experimental data? 1. The oxidation of bromide ion by persulfate is given by the equation: S2082-(aq) + 3Br (aq) + 2504 (aq) + Br3 (aq) What is the rate law for this reaction based on the following experimental data? Expt # (S2082-) (Br"] Initial rate mol/L mol/L mol/(L-sec) 1...
The following reaction was studied experimentally at 25 °C. S2O82(aq) + 21'(ag) = 12(aq) + 2SO4 (aq) The reaction was found to be first order with respect to I and first order with respect to S208". A reaction was performed with [1] = 0.080 M and [S208²-] = 0.040 M. The initial rate of formation of 12 was found to be 1.25 x 10-M St. Provide an expression for the rate law for this reaction and determine the initial rate...
Consider the reaction of peroxydisulfate ion (S2O8^2-)(Aq) with iodide ion (I-) in aqueous solution: (S2O8^2-)(Aq)+(3I-)(Aq)---->2SO4^2-+(I3-)(Aq).At a particular temperature the rate of disappearance of S2O8^2 varies with reactant concentrations in the following manner:Experiment S2O8^2- I- Initial Rate1 0.018 0.036 2.6x10^-62 0.027 0.036 3.9x10^-63 0.036 0.054 7.8x10^-64 0.050 0.072 1.4x10^-51) Determine the rate law for the reaction.Apparently the rate law is Rate=[S2O8^2-][I-]How did they come up with this?2)How is the rate of disappearance ofS2O8^2- related to the rate of disappearance of [I-]...
Rate Laws (Section)Consider the reaction of peroxydisulfate ion (S2O8 2-) with iodide ion (I - ) in aqueous solution:S2O82 - (aq) + 3 I - (aq)→2 SO42 - (aq) + I3- (aq)At a particular temperature the initial rate of disappearance of S2O8 2 - varies with reactant concentrations in the following manner:Experiment[S2O82‑] (M)[I_] (M)Initial Rate (M/S)10.0180.0362.6 × 10-620.0270.0363.9 × 10-630.0360.0547.8 × 10-640.0500.0721.4 × 10-5(a) Determine the rate law for the reaction and state the units of the rate constant. (b)...
Preliminary: Key Chemical Equations Reaction 2 Fe3 (a)3 I(a)2 Fe(aq) + I3'(aq) I3(ag) 2 S2032(aq) 3 1a)S4O(0) Reaction 2: + + Prelab Questions 1. List and define any new terms relevant to this experiment 2. Write the general formula for the rate law for Reaction 1 (given above) 3. Write the general formula for calculating average rate bases on the disappearance of thiosulfate (S2O,2) in Reaction 2 (given above) 4. Write the equation used for calculating a concentration after dilution...
The reaction of peroxydisulfate ion (S2O82-) with iodide ion (I -) is given below. S2O82-(aq) + 3 I - 2SO24-(aq) +I3- The following data are collected at a certain temperature. Experiment [S2O82- ](M) [I- ](M) Initial Rate (M/s) 1 0.080 0.034 2.2 X 10-4 2 0.080 0.017 1.1 X 10-4 3 0.16 0.017 2.2 X 10-4 Determine the rate law. ____________________ Calculate the rate constant. ______________ /(M·s) The reaction of peroxydisulfate ion (S2O8^2-) with iodide ion (I -) is given...