this is the transnational contribution to molecular partition function
3. (8 pts) Calculate the thermal wavelength and translational contribution to the molecular partition function for...
If thermal properties reveal a sample of F2 gas to have a one-molecule translational partition function qtrans of 2.29⋅10^26, and a second sample of a pure, unknown diatomic homonuclear gas is found to have a qtrans of 1.45⋅10^26 at the same temperature and volume, what is the second gas? trans of 2.29. 104, and a second sample of a pure, unknown diatomic homonuclear gas is found to have a trans of 1.45 . 102 at the same temperature and If...
1. Calculate (a) the thermal wave-length (in pm) and (b) the translational partition function of H atom in a cubic box of side 1.0 cm at 300 K. (c) Can a hydrogern molecule be considered as a classical system (as a diatomic molecule in whiclh hydrogen atoms behave classically) at this temperature? Explain why.
If thermal properties reveal a sample of N2 gas to have a one-molecule translational partition function qtrans of 1.45⋅10^26, and a second sample of a pure, unknown diatomic homonuclear gas is found to have a qtrans of 2.29⋅10^26 at the same temperature and volume, what is the second gas?
Calculate the value of the translational partition function of O2 at 300 K for a volume of 1 m3. Submit your answer multiplied by 10−32 (i.e. if you calculate 4.2e33, input 42).
Calculate the translational partition function of a helium atom (mHe = kg) at 297 K in a container of volume 0.6 m3 (use m3 in the expression and not dm3 or L). Express your answer in scientific notation with three significant figures (X.XXEXX).
-2 points Calculate the translational partition function at (a) 300 K and (b) 600 K of a molecule of molar mass 280 g mol'" in a container of volume 2.30 cm2. Ger at 300 K Qu at 600 K Note: this i s a measure of the vast number of accessible microstates of translation available to a molecule under these conditions.
Determine the volume of a container for which the translational partition function for atomic hydrogen is 1.0 states per atom at a temperature of 273 K. Comment on your answer.
a.) What does a partition function represent in statistical thermodynamics? A. The number of rotational symmetry elements of a molecule with more than 2 atoms. B. The number of thermally accessible energy levels at a given temperature. C. The number of molecules that partition themselves between the liquid and the gas phase of a substance b.) The constant volume heat capacity for a monoatomic gas is equal to: A. RT B. R C. 32 RT D. 3/2 R c.) The...
5) Calculate the total molecular partition function for 2 moles of Oz gas at 292.5 K and 24 atm. You can assume ideal behavior (V=nRT/P). For O2 the rotational constant is B = 1.45 cm and the vibrational frequency is 1580 cm. The ground state electronic level has a degeneracy of 3.
Problem 4. Calculate the vibrational partition function of CS, at 500 K given the wavelength 558 cm (symmetric stretch), 397 cm (bend; two modes), and 2097 cm (asymmetric stretch)