Question

Rank the following compounds in order of increasing rate of the reaction with KI in acetone...

Rank the following compounds in order of increasing rate of the reaction with KI in acetone

a) (CH3)3CCl

b) (CH3)2CHCl

c) (CH3)2CHBr

d) (CH3)2CHCH2Cl

e) CH3(CH2)3CH2Br

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Answer #1

order of increasing rate of reaction:

a < b < c < d < e

highest rate: e

Reaction of alkyl halide with KI in acetone follows SN2 mechanism. primary alkyl halides are more reactive in SN2 reactions.

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