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CHAPTER 10: CARBOXYLIC ACID 5. Show the preparation of butanoic...
Questions 12-20 are true and false! (12) Hydrolysis of nitriles is a method to synthesize carboxylic...
Questions 12-20 are true and false!
(12) Hydrolysis of nitriles is a method to synthesize carboxylic acid. (13) The order of reactivity of carboxylic acid derivatives is as follow: Acyl chloride > Acid anhydride > Ester > Amide. (14) SOCI2, PC13 and PCls are three types of special reagents to convert carboxylic acid to acyl chloride (15) Acyl chlorides are the most reactive common acyl derivatives, and can be used to synthesize anhydride, ester, and amide. (16) Acyl chloride is...
13. A solution of naphthalene, aniline, and benzoic acid in CH;Cl2 is treated with aqueous NaOH....
13. A solution of naphthalene, aniline, and benzoic acid in CH;Cl2 is treated with aqueous NaOH. What compound is extracted into the aqueous layer? NH2 он naphthalene benzoic acid aniline a. naphthalene b. aniline, as its sodium salt c. benzoic acid, as its sodium salt d. aniline and naphthalene 14. Which of the following Sy1 reactions did the Spartan program predict to have the lowest energy (AHrn, kcal/mol)? a. CH;CH;CH;CH;CI → CH;CHCH;CH, + Cr b. CH;CH;CHCICH3 CH;CH2CHCH, + Cr to...
Help me solve this question asap 3 (a) The reaction of 1-butanol, F. with several reagents...
Help me solve this question asap
3 (a) The reaction of 1-butanol, F. with several reagents is shown below Tindak balas 1-butonol.F.demgan beberapa reagen ditunjukkan di bawah conc H,SO HSO.prkat NiCH H,o Draw the structures of G. H and J ukis strukrur bagi G.H dan 3 marks] 3 markah] (ii) Suggest the reagent(s) needed to prepare F from methanal. Cadangkan reagen yang diperlukan bagi menyediakan F daripada metanal 2 marks] 2 markah Name the functional group in compound H Namakan...
please answer b) and question 3 b) An uknown ketone F reacted with CH,CH MgBr, followed...
please answer b) and question 3
b) An uknown ketone F reacted with CH,CH MgBr, followed by acidic hydrolysis to produce alcohol G, CHO. Reaction of F with sodium borohydride in methanol gives compound J, a chiral compound that undergoes dehydration with concentrated sulphuric acid to give 2-pentene as the major product. Write the reaction scheme involved and deduce the structure of F, Gand K Ketone F yang tidak diketahui bertindak balas dengan CH,CH MgBr, dikut dengan hidrolisis berasid menghasilkan...
Multiple Choice (5 points each, 30 points total). Circle the one BEST answer for each problem....
Multiple Choice (5 points each, 30 points total). Circle the one BEST answer for each problem. 1. Which of the following tertiary alcohols cannot be prepared using the reaction of an ester with excess (2 equivalents) Grignard reagent? . Which of the following esters undergoes hydrolysis in basic conditions (saponification) most readily? . Which compound will be essentially unreactive with excess 1-butanol in acid-catalyzed conditions (upon moderate heating if required)? . Which of the following is the best method for...
Complete questions 10-27 PART II: REACTIONS: Here is another different" question. Pretend you have been asked...
Complete questions 10-27
PART II: REACTIONS: Here is another different" question. Pretend you have been asked by me to put together a bunch of one-step reactions WITH starting materials (your choice), reagents and answers to help me with writing a final exam. For example: let's say I ask you to give an example of a free radical chlorination with a non-cyclic compound. Below would be your answer. As I am pretty sure you can figure out, there are millions of...
Grignard reagent THE GRIGNARD REAGENT-PREPARATION AND REACTION In this experiment, you will prepa...
i need help with the postlab questions please
Grignard reagent THE GRIGNARD REAGENT-PREPARATION AND REACTION In this experiment, you will prepare a Grignard reagent, phenyl magnesium bromide, from bromobenzene and magnesium metal. The Grignard reagent will then react with methyl benzoate to form triphenylmethanol. Introduction Grignard reagents, such as organomagnesium halides, were discovered in 1910 by French chemist Victor Grignard. The Grignard reaction is one of the most general methods for carbon- carbon bond formation in all of organic chemistry....
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an...
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an amine e. no reaction c. an aldehyde Which of the following combinations will react spontaneously? A. 12 + Cu2+ B. Pb2+ + Ag C. Zn2+ + Mg D. Sn2+ + Ni2+ The general formula for a cycloalkane can be represented by which of the following? a. C,H, C. CH b. C.H2n+2 d. C.H21-2 In a certain reaction AH =-136 kJ and E, = 96...
What is the theoretical yield (in grams) and percent yield of your triphenylmethanol product in this...
What is the theoretical yield (in grams) and percent yield of your
triphenylmethanol product in this experiment? (Weight of
triphenylmethanol: 0.060g)
BACKGROUND AND THEORY The Grignard reaction was one of the first organometallic reactions discovered and is still one of the most useful synthetically. By reacting an organohalide (usually a bromide) with magnesium in ethereal solvent, carbon becomes a nucleophile. Grignard reagents are the starting points for the syntheses of many alkanes, primary, secondary, and tertiary alcohols, alkenes, and carboxylic...
Questions 12-20 are true and false!
(12) Hydrolysis of nitriles is a method to synthesize carboxylic acid. (13) The order of reactivity of carboxylic acid derivatives is as follow: Acyl chloride > Acid anhydride > Ester > Amide. (14) SOCI2, PC13 and PCls are three types of special reagents to convert carboxylic acid to acyl chloride (15) Acyl chlorides are the most reactive common acyl derivatives, and can be used to synthesize anhydride, ester, and amide. (16) Acyl chloride is...
13. A solution of naphthalene, aniline, and benzoic acid in CH;Cl2 is treated with aqueous NaOH. What compound is extracted into the aqueous layer? NH2 он naphthalene benzoic acid aniline a. naphthalene b. aniline, as its sodium salt c. benzoic acid, as its sodium salt d. aniline and naphthalene 14. Which of the following Sy1 reactions did the Spartan program predict to have the lowest energy (AHrn, kcal/mol)? a. CH;CH;CH;CH;CI → CH;CHCH;CH, + Cr b. CH;CH;CHCICH3 CH;CH2CHCH, + Cr to...
Help me solve this question asap
3 (a) The reaction of 1-butanol, F. with several reagents is shown below Tindak balas 1-butonol.F.demgan beberapa reagen ditunjukkan di bawah conc H,SO HSO.prkat NiCH H,o Draw the structures of G. H and J ukis strukrur bagi G.H dan 3 marks] 3 markah] (ii) Suggest the reagent(s) needed to prepare F from methanal. Cadangkan reagen yang diperlukan bagi menyediakan F daripada metanal 2 marks] 2 markah Name the functional group in compound H Namakan...
please answer b) and question 3
b) An uknown ketone F reacted with CH,CH MgBr, followed by acidic hydrolysis to produce alcohol G, CHO. Reaction of F with sodium borohydride in methanol gives compound J, a chiral compound that undergoes dehydration with concentrated sulphuric acid to give 2-pentene as the major product. Write the reaction scheme involved and deduce the structure of F, Gand K Ketone F yang tidak diketahui bertindak balas dengan CH,CH MgBr, dikut dengan hidrolisis berasid menghasilkan...
Multiple Choice (5 points each, 30 points total). Circle the one BEST answer for each problem. 1. Which of the following tertiary alcohols cannot be prepared using the reaction of an ester with excess (2 equivalents) Grignard reagent? . Which of the following esters undergoes hydrolysis in basic conditions (saponification) most readily? . Which compound will be essentially unreactive with excess 1-butanol in acid-catalyzed conditions (upon moderate heating if required)? . Which of the following is the best method for...
Complete questions 10-27
PART II: REACTIONS: Here is another different" question. Pretend you have been asked by me to put together a bunch of one-step reactions WITH starting materials (your choice), reagents and answers to help me with writing a final exam. For example: let's say I ask you to give an example of a free radical chlorination with a non-cyclic compound. Below would be your answer. As I am pretty sure you can figure out, there are millions of...
i need help with the postlab questions please
Grignard reagent THE GRIGNARD REAGENT-PREPARATION AND REACTION In this experiment, you will prepare a Grignard reagent, phenyl magnesium bromide, from bromobenzene and magnesium metal. The Grignard reagent will then react with methyl benzoate to form triphenylmethanol. Introduction Grignard reagents, such as organomagnesium halides, were discovered in 1910 by French chemist Victor Grignard. The Grignard reaction is one of the most general methods for carbon- carbon bond formation in all of organic chemistry....
What results when a secondary alcohol is oxidized? a. a ketone d. an acid b. an amine e. no reaction c. an aldehyde Which of the following combinations will react spontaneously? A. 12 + Cu2+ B. Pb2+ + Ag C. Zn2+ + Mg D. Sn2+ + Ni2+ The general formula for a cycloalkane can be represented by which of the following? a. C,H, C. CH b. C.H2n+2 d. C.H21-2 In a certain reaction AH =-136 kJ and E, = 96...
What is the theoretical yield (in grams) and percent yield of your
triphenylmethanol product in this experiment? (Weight of
triphenylmethanol: 0.060g)
BACKGROUND AND THEORY The Grignard reaction was one of the first organometallic reactions discovered and is still one of the most useful synthetically. By reacting an organohalide (usually a bromide) with magnesium in ethereal solvent, carbon becomes a nucleophile. Grignard reagents are the starting points for the syntheses of many alkanes, primary, secondary, and tertiary alcohols, alkenes, and carboxylic...
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