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11. a) Provide the two substituenproductsforthe followingSNI reaction: (6…) OH b) Show the mechanism for the...
5:43 PM Thu Oct 31 29% Chem2542 Assignment-6.doc 1. Provide the structure of diene and dienophile...
5:43 PM Thu Oct 31 29% Chem2542 Assignment-6.doc 1. Provide the structure of diene and dienophile required for the synthesis of the following compound via Diels-Alder reaction. Ph сно сно 2. The following a,b-unsaturated ketone can react with nucleophilic reagents to yield 1,2-addition as well as 1,4-addition (conjugate addition) products depending on the nucleophilic reagent. Provide the structure of the major primary 1,2-addition or 1,4 addition product formed in each reaction 1. CH,MgCI 2. HC 1. LIAIH 2. HC 1....
draw curved arrows Draw curved arrows to complete the Diels-Alder mechanism for the two reactants shown....
draw curved arrows
Draw curved arrows to complete the Diels-Alder mechanism for the two reactants shown. Then draw the product of the reaction in the box to the right. Do not show stereochemistry.
Provide a mechanism to explain the formation of the two products shown following reaction. Show all...
Provide a mechanism to explain the formation of the two products
shown following reaction. Show all key intermediates and indicate
electron flow using arrows.
a. OH H2O, Ht, heat CH3 H3C CH3 CH3
9. Give the curved arrow mechanism for each reaction. H2SO4 b. H,o OH c. H20 H2SO...
9. Give the curved arrow mechanism for each reaction. H2SO4 b. H,o OH c. H20 H2SO d. OH H2o 10. For the following reaction, H,so, H,O он a. Give the curved arrow mechanism for the reaction, showing formation of both products b. Identify the major product and explain why it is favored. c. Draw the energy diagram for the formation of the major product. 11. Give the major organic product for the following reactions. If a racemic mixture is expected,...
these are confusing me. help please? Homework #6 Due Monday November 18th, 2019 Problem I: Diels-Alder...
these are confusing me. help please?
Homework #6 Due Monday November 18th, 2019 Problem I: Diels-Alder Reaction Below is shown the Diels Alder reaction. Predict the sign of H and the sign of S. Then indicate when the reaction would work. C + = Problem II: Enolate formation We look at the reaction below which is the formation of an enolate. Base, + O Reaction Coordinate Which product is the kinetic product? Which product is the thermodynamic product? The reaction...
tion 5 continued) c. Anthracene is known to act as the diene in Diels-Alder read as...
tion 5 continued) c. Anthracene is known to act as the diene in Diels-Alder read as maleic anhydride as shown below. Draw the str reaction and draw a reasonable mechanism illustrating its comma explanation for the observed regioselectivity. he diene in Diels-Alder reactions with dienophiles such s shown below. Draw the structure of the major product of this nechanism illustrating its formation. Give a brief [4 marks) Propose a detailed mechanism for the following two transformations. Use curved arrows to...
6. (12 points total) Mechanism: Provide a detailed mechanism for the following reaction. Use curved arrows...
6. (12 points total) Mechanism: Provide a detailed mechanism for the following reaction. Use curved arrows to show the movement of electrons. (Hint: Begin by drawing the resonance structure for the reagent over the arrow) from med arrows total) Mecha H2C=N=N O-H OCH3 NEN (gas) 7. (18 points total) Mechanism: Provide a detailed, stepwise mechanism for the following reaction. Use curved arrows to show the movement of electrons. O Me Me
show how toluene can be transferred to product A OH C O A Provide the reaction...
show how toluene can be transferred to product A OH C O A Provide the reaction conditions & the structure of the correct products of the following: „OH -CO2 o 1) LDA 2) CH ₃ Br Propose a mechanism that shows the following transformation 09 11 1ether 11 2) H₃0 از قلم ~ Mg Br + öt 0
ASAP 6.(8) a. The 1,2 addition product of the reaction is shown. Draw the 1,4 addition...
ASAP
6.(8) a. The 1,2 addition product of the reaction is shown. Draw the 1,4 addition product. HBr 1,2 1,4 b. Which is more stable? Circle one: the 1,2 product, the 1.4 product. c. Which product is favored at low temperatures? Circle one: the 1.2 product, the 14 product d. "The proximity effect is used to account for the formation of which product? Circle one: the 1,2 product, the 1.4 product. 7. (5) The pesticide chlordane, sold starting in 1948,...
3) (D) Which one of the following molecular orbitals will have the highest energy? 4) Choose...
3) (D) Which one of the following molecular orbitals will have the highest energy? 4) Choose how many "occupied MOS" can occur for the conjugated t-system of B-carotene and LED compounds? NH beta-carotene (a) 22 and 6 5) The diene LED material (b) 11 and 6 (c) 22 and 12 (d) 11 and 12 is not suitable for Diels-Alder [4+2) cycloaddition? 6) Which one of bicyclic isomers is appropriate for both Diels-Alder and 1,2-/1.4-additions? 7) Both 1.2- and 1,4-additions of...
5:43 PM Thu Oct 31 29% Chem2542 Assignment-6.doc 1. Provide the structure of diene and dienophile required for the synthesis of the following compound via Diels-Alder reaction. Ph сно сно 2. The following a,b-unsaturated ketone can react with nucleophilic reagents to yield 1,2-addition as well as 1,4-addition (conjugate addition) products depending on the nucleophilic reagent. Provide the structure of the major primary 1,2-addition or 1,4 addition product formed in each reaction 1. CH,MgCI 2. HC 1. LIAIH 2. HC 1....
draw curved arrows
Draw curved arrows to complete the Diels-Alder mechanism for the two reactants shown. Then draw the product of the reaction in the box to the right. Do not show stereochemistry.
Provide a mechanism to explain the formation of the two products
shown following reaction. Show all key intermediates and indicate
electron flow using arrows.
a. OH H2O, Ht, heat CH3 H3C CH3 CH3
9. Give the curved arrow mechanism for each reaction. H2SO4 b. H,o OH c. H20 H2SO d. OH H2o 10. For the following reaction, H,so, H,O он a. Give the curved arrow mechanism for the reaction, showing formation of both products b. Identify the major product and explain why it is favored. c. Draw the energy diagram for the formation of the major product. 11. Give the major organic product for the following reactions. If a racemic mixture is expected,...
these are confusing me. help please?
Homework #6 Due Monday November 18th, 2019 Problem I: Diels-Alder Reaction Below is shown the Diels Alder reaction. Predict the sign of H and the sign of S. Then indicate when the reaction would work. C + = Problem II: Enolate formation We look at the reaction below which is the formation of an enolate. Base, + O Reaction Coordinate Which product is the kinetic product? Which product is the thermodynamic product? The reaction...
tion 5 continued) c. Anthracene is known to act as the diene in Diels-Alder read as maleic anhydride as shown below. Draw the str reaction and draw a reasonable mechanism illustrating its comma explanation for the observed regioselectivity. he diene in Diels-Alder reactions with dienophiles such s shown below. Draw the structure of the major product of this nechanism illustrating its formation. Give a brief [4 marks) Propose a detailed mechanism for the following two transformations. Use curved arrows to...
6. (12 points total) Mechanism: Provide a detailed mechanism for the following reaction. Use curved arrows to show the movement of electrons. (Hint: Begin by drawing the resonance structure for the reagent over the arrow) from med arrows total) Mecha H2C=N=N O-H OCH3 NEN (gas) 7. (18 points total) Mechanism: Provide a detailed, stepwise mechanism for the following reaction. Use curved arrows to show the movement of electrons. O Me Me
show how toluene can be transferred to product A OH C O A Provide the reaction conditions & the structure of the correct products of the following: „OH -CO2 o 1) LDA 2) CH ₃ Br Propose a mechanism that shows the following transformation 09 11 1ether 11 2) H₃0 از قلم ~ Mg Br + öt 0
ASAP
6.(8) a. The 1,2 addition product of the reaction is shown. Draw the 1,4 addition product. HBr 1,2 1,4 b. Which is more stable? Circle one: the 1,2 product, the 1.4 product. c. Which product is favored at low temperatures? Circle one: the 1.2 product, the 14 product d. "The proximity effect is used to account for the formation of which product? Circle one: the 1,2 product, the 1.4 product. 7. (5) The pesticide chlordane, sold starting in 1948,...
3) (D) Which one of the following molecular orbitals will have the highest energy? 4) Choose how many "occupied MOS" can occur for the conjugated t-system of B-carotene and LED compounds? NH beta-carotene (a) 22 and 6 5) The diene LED material (b) 11 and 6 (c) 22 and 12 (d) 11 and 12 is not suitable for Diels-Alder [4+2) cycloaddition? 6) Which one of bicyclic isomers is appropriate for both Diels-Alder and 1,2-/1.4-additions? 7) Both 1.2- and 1,4-additions of...
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