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Please help!!! Our experimental rate law is rate=k[H2O2][KI]
which shows they are both first order.
UsItion...
I need help with question number 5. 283 14.4 Equilibria in complex reactions (5) The experimental...
I need help with question number 5.
283 14.4 Equilibria in complex reactions (5) The experimental rate law for the reaction 2NO(g)+Br2(g)→2NOBI(g) Is u= kINO)2[Br2]. Show that this rate law is consistent with the mechanism NO(g) + Br2(g NOE3r2(g) + NO(g) kI NOBT2(g) k-1 2NOBrg) → Give an equation for the experimental rate constant k in terms of the elementary rate constants ki, k-i and k2. Briefly discuss, based on your derivation of the rate equation, which elementary processes are...
Question 5 and 6 Determine and report the rate law for the reaction of iodide and...
Question 5 and 6
Determine and report the rate law for the reaction of iodide and persul fate ions. Show all calculations and justifications. 2 3.Based on the rate law that you determined above, calculate the values and units of k for: a. the three initial rates experiments in Part A, b. the one initial rates experiment at a different temperature in Part B. 4Use your two experiments done at different temperatures to determine the activation energy Ea and the...
8. The rate law for the reaction H2O2 + 2H+212 + 2H2O is rate-k[H202][1]. The following...
8. The rate law for the reaction H2O2 + 2H+212 + 2H2O is rate-k[H202][1]. The following mechanism has been suggested. H2O2+1 - HOI + OH - slow OH + H H20 fast HỘI + H+ + + I2 + H2O fast Identify all intermediates included in this mechanism. A) H and I D) Honly B) H and HOI E) H20 and OH C) HOI and OH 9. Which of the following statements is false? A) A catalyst increases the rate...
The experimental rate law for the reaction 2H2(g) + 2 NO(g) → N2(g) +2 H2O(g) is...
The experimental rate law for the reaction 2H2(g) + 2 NO(g) → N2(g) +2 H2O(g) is d[N2) = kods[Hz][NO] Below is a proposed mechanism: H2(g) + NO(g) + NO(g) = N2O(g) + H2O(g) H2(g) + N2O(g) = N2(g) + H2O(g) ki k2 (a) Under what conditions does this mechanism give the observed rate law? Express kobs in terms of the rate constants for the individual steps of the mechanism. A second proposed mechanism is: NO(g) + NO(g) = N2O2(g) N2O2(g)...
6. The rate law for the following reaction is rate=k[NO2] (F2]: 2NO2(g) + F2(g) → 2NO2F(g)...
6. The rate law for the following reaction is rate=k[NO2] (F2]: 2NO2(g) + F2(g) → 2NO2F(g) The mechanism proposed for this reaction is as follows: (i) NO2(g) + F2(g) → NO2F(g) + F(g) (ii) NO2(g) + F(g) → NO2F(g) Which elementary step is the rate-determining step in this reaction? Explain your answer in 1-2 sentences.
2 NO (9) 1. (2 pts) Use the following experimental data to write a Rate Law...
2 NO (9) 1. (2 pts) Use the following experimental data to write a Rate Law for this reaction. Show your work and draw a box around your final answer. + Cl2() + 2 NOCG) [NO] (M) (C12) (M) Initial Rate (Mis) 0.50 1.14 1.00 0.50 4.56 1.00 1.00 9.12 0.50 2. (2 pts) Consider this two-step mechanism for a reaction: Step 1: 2 NO (9) + 2 H2 (9) ** N2 () + H2O2() SLOW Step 2: H2020) +...
— O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the...
— O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the formation of nitrosyl chloride proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Cl2(9) ► NOCI (9) km 2 NOCI (9) + NO(g) → 2 NOCI (9) kz Suppose also k«k. That is, the first slower than the second 0-0 Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical...
Please help me find the average k, determining the order with respect to H2O2 (B) and...
Please help me find the average k, determining the order with
respect to H2O2 (B) and H+ (y), and what is the complete rate law
by including the experimentally numerical value of k, a, b and
y.
The lodine Clock: Initial Rate Law Kinetics - 71 Calculations Below is a description and outline for the calculations you need to complete for this laboratory. Make sure to include all of your calculations. Use extra paper if you need to Initial Concentrations:...
To understand how elementary steps make up a mechanism and how the rate law for an...
To understand how elementary steps make up a mechanism and how the rate law for an elementary step can be determined. Very often, a reaction does not tell us the whole story. For instance, the reaction NO2(g)+CO(g)→NO(g)+CO2(g)NO2(g)+CO(g)→NO(g)+CO2(g) does not involve a collision between an NO2NO2 molecule and a COCO molecule. Based on experimental data at moderate temperatures, this reaction is thought to occur in the following two steps: NO2(g)+NO2(g)→NO3(g)+NO(g)NO2(g)+NO2(g)→NO3(g)+NO(g) NO3(g)+CO(g)→CO2(g)+NO2(g)NO3(g)+CO(g)→CO2(g)+NO2(g) Each individual step is called an elementary step. Together, these...
2 H2O2(aq) + 2 H2O(l) + O2(g) 5. Hydrogen peroxide decomposes according to the equation above. a. An aqueous solutio...
2 H2O2(aq) + 2 H2O(l) + O2(g) 5. Hydrogen peroxide decomposes according to the equation above. a. An aqueous solution of H2O, that is 6.00 percent H,O, by mass has a density of 1.03 g ml. Calculate each of the following. (i) The original number of moles of H2O, in a 125 ml sample of the 6.00 percent H2O2 solution (ii) The number of moles of O,(g) that are produced when all of the H2O2 in the 125 mL sample...
I need help with question number 5.
283 14.4 Equilibria in complex reactions (5) The experimental rate law for the reaction 2NO(g)+Br2(g)→2NOBI(g) Is u= kINO)2[Br2]. Show that this rate law is consistent with the mechanism NO(g) + Br2(g NOE3r2(g) + NO(g) kI NOBT2(g) k-1 2NOBrg) → Give an equation for the experimental rate constant k in terms of the elementary rate constants ki, k-i and k2. Briefly discuss, based on your derivation of the rate equation, which elementary processes are...
Question 5 and 6
Determine and report the rate law for the reaction of iodide and persul fate ions. Show all calculations and justifications. 2 3.Based on the rate law that you determined above, calculate the values and units of k for: a. the three initial rates experiments in Part A, b. the one initial rates experiment at a different temperature in Part B. 4Use your two experiments done at different temperatures to determine the activation energy Ea and the...
8. The rate law for the reaction H2O2 + 2H+212 + 2H2O is rate-k[H202][1]. The following mechanism has been suggested. H2O2+1 - HOI + OH - slow OH + H H20 fast HỘI + H+ + + I2 + H2O fast Identify all intermediates included in this mechanism. A) H and I D) Honly B) H and HOI E) H20 and OH C) HOI and OH 9. Which of the following statements is false? A) A catalyst increases the rate...
The experimental rate law for the reaction 2H2(g) + 2 NO(g) → N2(g) +2 H2O(g) is d[N2) = kods[Hz][NO] Below is a proposed mechanism: H2(g) + NO(g) + NO(g) = N2O(g) + H2O(g) H2(g) + N2O(g) = N2(g) + H2O(g) ki k2 (a) Under what conditions does this mechanism give the observed rate law? Express kobs in terms of the rate constants for the individual steps of the mechanism. A second proposed mechanism is: NO(g) + NO(g) = N2O2(g) N2O2(g)...
6. The rate law for the following reaction is rate=k[NO2] (F2]: 2NO2(g) + F2(g) → 2NO2F(g) The mechanism proposed for this reaction is as follows: (i) NO2(g) + F2(g) → NO2F(g) + F(g) (ii) NO2(g) + F(g) → NO2F(g) Which elementary step is the rate-determining step in this reaction? Explain your answer in 1-2 sentences.
2 NO (9) 1. (2 pts) Use the following experimental data to write a Rate Law for this reaction. Show your work and draw a box around your final answer. + Cl2() + 2 NOCG) [NO] (M) (C12) (M) Initial Rate (Mis) 0.50 1.14 1.00 0.50 4.56 1.00 1.00 9.12 0.50 2. (2 pts) Consider this two-step mechanism for a reaction: Step 1: 2 NO (9) + 2 H2 (9) ** N2 () + H2O2() SLOW Step 2: H2020) +...
— O KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism Suppose the formation of nitrosyl chloride proceeds by the following mechanism: step elementary reaction rate constant 1 NO(g) + Cl2(9) ► NOCI (9) km 2 NOCI (9) + NO(g) → 2 NOCI (9) kz Suppose also k«k. That is, the first slower than the second 0-0 Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical...
Please help me find the average k, determining the order with
respect to H2O2 (B) and H+ (y), and what is the complete rate law
by including the experimentally numerical value of k, a, b and
y.
The lodine Clock: Initial Rate Law Kinetics - 71 Calculations Below is a description and outline for the calculations you need to complete for this laboratory. Make sure to include all of your calculations. Use extra paper if you need to Initial Concentrations:...
2 H2O2(aq) + 2 H2O(l) + O2(g) 5. Hydrogen peroxide decomposes according to the equation above. a. An aqueous solution of H2O, that is 6.00 percent H,O, by mass has a density of 1.03 g ml. Calculate each of the following. (i) The original number of moles of H2O, in a 125 ml sample of the 6.00 percent H2O2 solution (ii) The number of moles of O,(g) that are produced when all of the H2O2 in the 125 mL sample...
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