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io003 10003) If caffeine hydrochloride, the salt of caffeine, is added to coffee, what will happen to the following caffeine equilibrium? Will it shift to the left, right, or not be affected at all? Why? What is this effect called? HC, H,,NO OH 5.3 x 10 11)(3) Could the caffeine/caffeine hydrochloride pair act as a buffer? Explain why or why not.

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As caffeine hydrochloride is added, the concentration of protonated caffeine increase and equilibrium shifts in such a way to cancel if effect. For this the reaction proceeds backwards. More caffeine will be produced. Hence the protonation of caffeine is depressed and this is called common ion effect.

A weak base and it's salt can act as a buffer. In this case if we add an acid then it will be neutralized by forming corresponding caffeine salt. If base is added, caffeine hydrochloride will react with it forming caffeine, which is weakly protonated/hydrolysed

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