Question

Provide the major organic product(s) of the reaction shown below. HNO3, H2SO4 H3C CH3 Draw the molecule on the canvas by choosing buttons from t

Answer 1

The mixture of Concentrated HNO3 and Concentrated Hasoy generates the NOZP and this is the electrophilic species. Hasoy + Ho-Noz Asoy + H2J – NO2 H2U-NU2 & thothor H2O + H2sog Hoftisuun. overall 2#2504 + HNO3 = 2Hs0y"+#30f 1024 0 +9 effect Reffect O-Teffect Netiz - CH3 group has ag effect wherean &.ch3 grouphan -I as well as-Reffect so at first it may be assume that the Nitration product wat ie the incorporation of-Noz group will be at the one tho position this actually does not happena - () е хеесt tv — сHз амор Би- happen. we have to consider the stability of the corresponding & Complex ... The stability of the complex gives a straight forward Conclusion for the incorporation of a Nuz group of the meta position with respect to c113 group.

NUZ NO2 Now, from the isolation of the resonating HBC ,, Structure fury theo.complexe NH Joimed » maatjac with respeet to 7 is more stable - of Nuz group is more stable - To L Comp are to that of the 6 Complex formed by the out the attack with respect to-cits group) of nur group. NOR UN02H C4 Car of Canonical farmiston) Iess mator So the product will be sc-040 20 0 Tong is loc.com, NO2