Sugar stereochemistry. The linear chain form of
mannose is shown below (on the left side). Draw the Hayworth
structure of the cyclic anomer of fructose (named on the right
side).
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Sugar stereochemistry. The linear chain form of mannose is shown below (on the left side). Draw...
5 a) identify the anomeric carbon in the below molecule
b) identify the thpe of ring pyranose or furanose
c) identify if it is a or b
6 a) identify the anomeric carbon in the below molecule
b) identify the thpe of ring pyranose or furanose
c) identify if it is a or b
7 The structure of 6-carbon ketose sugar is shown. Draw the
common cyclic structure of this structure (both a and b form)
8 Identify the relationship...
Draw the sugar below in its open-chain form: Use the wedge/hash bond tools to indicate stereochemistry. Do not draw the open-chain form as a Fischer projection.
Ribose is an important pentose sugar in the structure of nucleic acids. The linear structure for D-ribose is shown below. Use the methods we discussed in class (also in Timberlake) to convert the linear form below into the corresponding. Haworth structure for the beta anomer of D-ribose. Is the cyclic structure an acetal or a hemiacetal?
1. Below is a monosaccharide in its cyclic (ring) form. OH он Linear form OH a) Is the monosaccharide the a-or the B-anomer? b) Label each carbon with its carbon number. c) Draw the linear form of this monosaccharide with the correct chirality in the box at right. 2. a) Draw the linear form of D-ribose: b) Ribose can form a pyranose ring. Draw an electron arrow on your linear ribose drawing above, indicating which nucleophile attacks which electrophile to...
5. Below, draw a ketoheptose of your choosing in its linear form, and then in the corresponding cyclic form. Linear Cyclic 6. The end of a polysaccharide that has an anomeric carbon that is not bound to another saccharide is called the reducing end; the anomeric carbon can still open and close and also act as a reducing agent. How many reducing ends does a small amylopectin molecule with 100 branches have? Refer to the structure given in our notes...
Draw a beta-hemiacetal form of the sugar shown below, numbering all the carbons and circling the location of the original aldehyde oxygen:
1) a. Please draw the structure of the intermediate in the process shown below. CH2OH CH2OH Кон о он КОН OH OH OH OH OH The process shown above is called: c. Please mark an anomeric carbon and designate the orientation of the hydroxyl group. d. Indicate the carbon that determines the D or L configuration in the glucopyranose above by number or with an X. e. Is this a reducing sugar? f. Can it react with another carbohydrate to...
3) Draw the products of each reaction shown below. Circle which side of the equilibrium (left or right) is favored based on your knowledge of Kos. and boo * 9. roho 4) The phenols shown below have approximate pka values of 4, 7, 9, 10, and 11. Which pk, value belongs to which phenol?
4. For each monomer shown below, draw a segment of the polymer chain that would form as the product of addition polymerization. Draw a segment that contains at least 3 monomers. DCI CH3 CH3
3. The questions below refer to the cyclic peptide shown below. HO H. -ΝΗ HN OH HN -NH ot SH Me a. This peptide is made from how many amino acids? (single number on the line) b. How many potential diastereomers are possible for this molecule? (single number) c. Starting at the glycine residue, draw the linear, Fmoc-protected form of the peptide shown above. Make sure you are drawing the correct stereochemistry! Do not use any abbreviations. Draw out the...