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draw out structures or reagents Draw out either the structures or the reagents A-Q needed to...
(10 pts total) Give the structures for compounds/reagents A through K in the following road- map. 6-methylhept-1-yne SOCIO c. (CH3),Culi (1) B (1) CH,MgBr in ether (2) H30+ Na2Cr2O, H2SO4 (CH3)2CH(CH)3MgBr (2) H307 (1) K (2) H,0* KCN HCN (1) J (2) H307 H30 U
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
(10 pts total) Give the structures for compounds/reagents A through K in the following road- map. 6-methylhept-1-yne SOCI LG (CH),Culi (1) CH (1) B (2) H20+ (CH3)-CH(CH3)3MgBr (1) CH,MgBr in ether (2) H30* Na2Cr202 H2SO4 9 - (1) K (2) H30* KCN HCN (1)] OH (2) H30+ H₃O+ 4 Y OH
(10 pts total) Give the structures for compounds/reagents A through K in the following road- map. 6-methylhept-1-yne SOCI2 E (CH3),Culi (1) B (2) H0+ CH),CH(CH)3 MgBr – (1) CH,MgBr in ether (2) H30* Na2Cr2O7 H2SO4 C (1) K (2) H30+ KCN HEN (1) J 4 (2) H30+ H₂O OH &
2. Write out the required reagents/reaction conditions or Lewis structures for the productis) produced for 18 of the following 21 reactions. Answer only (18), otherwise only the first (18) will be graded (72 pts/4 pts each) NOTE: C(=O) represents C=0 a. CH3CH2OH → CH3-C(=O)-H b. CH3-C(=O)-CI CH3-C(=O)-CH3 C. CH3-CEC-H CH3CH2-C(=O)-H d. CH3-C(EO)-H H-CEN e. CH3-C(=O)-H (CH3)2-CH-OH f. CH3-C(=O)-CH3 + (CH3)2NH / H30 9. CH3-C(=O)-CH3 + CH3OH (2 equiv) / H30* → h. C6H5-CH3 C6H5-CO2H I. CH3-Mg-CI CH3-CO2H 1 CH3-CO2H CH3CH2-OH...
(10 pts total) Give the structures for compounds/reagents A through K in the following road- map 6-methylhept-1-yne SOCI G (CH3),Culi (1) CH,MgBr in ether (2) H30* (1) B (CH3)CH(CH), MgBr — (2) H30 Na Cr20 H2SO4 KCN HCN (1) K (2) H307 (1) J (2) H30+ OH H0+ H тон
1. NaOCH; 2. CH3CH2Br 3. H2O* heat Love OCH3 ОСН3 o OCH3 Which reaction sequence would accomplish this transformation? Joego LDA H30* heat H H2Cr2O7 monog morangayan H30*/CH3CH2OH NaOCH2CH3/heat LDA (CH3)2CHMOBrNaOH, heat NaOH heat [(CH3)2CH]>Culi
NaOH сн. then heat NaOH yer then heat NaOH (CH3),Culi then heat 1. NaOCH Снзон OCH 2. dil. HCI 1. LDA 1. LIATHA 2. Br 2.H30* 1. NaOCH lich, 2.phor 1. NaOCH, OCH, 2. Ph Br 2. CI 3. H30+, heat 1. LDA 1. LDA o 2. 0 CI 3. H3O+ H 3. H3O+
2. Predict the product. CH,CHINH Or . 1. excess CH 1 2. Ag,0,H,O heat 5. Match the reagents to the corresponding reaction. G. H20 H. xs CH3CH2NH2 A. SOCI2, pyridine B. Ethanol, pyridine C. 1) xs LAH 2) H20 D. 1) xs CH,CHMgBr 2) H30 E. 1) NaOH 2) H30* F. 1) DIBAH 2) H20 1. 1) LiAl(OR)2) H20 J. (CH2CH2) Culi K. xs NH3 L. 1) NaOH 2) CHÚCHỊCHÚCOCI M. Butanol, H
Answer A-K please. (10 pts total) Give the structures for compounds/reagents A through K in the following road- map. 6-methylhept-1-yne D— SOCI, SOCI2 her G (CH3)2Culi (1) CH,MgBr in ether (2) H30+ CHICH), M&B (1) BOC (CH3)2CH(CH3 MgBr - (1) B (2) H30+ Na2Cr2O7 H2SO4 1,80m (1) K (2) H30+ (K KCN HCN (1) J OH (2) H30+. HO_ OH |