![[14.38] Consider the reaction of peroxydisulfate ion (S208) with io- dide ion (I) in aqueous solution: S20s (ag) +3I(ag)2 SO4 (ag) +I3 (aq) At a particular temperature the initial rate of disappearance of S2082 varies with reactant concentrations in the following manner Experiment [S208 ] (M UI M Initial Rate (M/s) 2 3 4 0.018 0.027 0.036 0.050 0.036 2.6 x 106 0.036 3.9 x 106 0.054 7.8 x 106 0.072 E4 105 (a) Determine the rate law for the reaction and state the units of the rate constant. (b) What is the average value of the rate constant for the disappearance of S208 based on the four sets of data? (c) How is the rate of disappearance of S20 related to the rate of disappearance of T? (d) What is the rate of disappearance of Γ when [S2082-] 0.025 M and 0.050 M?](http://img.homeworklib.com/questions/fb05e7c0-7bd8-11eb-9a75-b7eb0f7f7a9d.png?x-oss-process=image/resize,w_560)
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[14.38] Consider the reaction of peroxydisulfate ion (S208) with io- dide ion (I) in aqueous solution:...
Consider the reaction of peroxydisulfate ion (S20;-) with iodide ion (I) in aqueous solution: S2O3- (aq)...
Consider the reaction of peroxydisulfate ion (S20;-) with iodide ion (I) in aqueous solution: S2O3- (aq) + 31- (aq) +250- (aq) +15 (aq). At a particular temperature the rate of disappearance of S20% varies with reactant concentrations in the following manner: 1 Experiment S20%- (M) I- (M) Initial Rate (M/s) 0.018 0.036 2.6 x 10-6 0.027 0.036 3.9 x 10-6 0.036 0.054 7.8 x 10-6 N 3 4 0.050 0.072 1.4 x 10-5 Part D What is the rate of...
Rate Laws (Section)Consider the reaction of peroxydisulfate ion (S2O8 2-) with iodide ion (I - )...
Rate Laws (Section)Consider the reaction of peroxydisulfate ion (S2O8 2-) with iodide ion (I - ) in aqueous solution:S2O82 - (aq) + 3 I - (aq)→2 SO42 - (aq) + I3- (aq)At a particular temperature the initial rate of disappearance of S2O8 2 - varies with reactant concentrations in the following manner:Experiment[S2O82‑] (M)[I_] (M)Initial Rate (M/S)10.0180.0362.6 × 10-620.0270.0363.9 × 10-630.0360.0547.8 × 10-640.0500.0721.4 × 10-5(a) Determine the rate law for the reaction and state the units of the rate constant. (b)...
Rate of Disappearance/Rate Constant
Consider the reaction of peroxydisulfate ion (S2O8^2-)(Aq) with iodide ion (I-) in aqueous solution: (S2O8^2-)(Aq)+(3I-)(Aq)---->2SO4^2-+(I3-)(Aq).At a particular temperature the rate of disappearance of S2O8^2 varies with reactant concentrations in the following manner:Experiment S2O8^2- I- Initial Rate1 0.018 0.036 2.6x10^-62 0.027 0.036 3.9x10^-63 0.036 0.054 7.8x10^-64 0.050 0.072 1.4x10^-51) Determine the rate law for the reaction.Apparently the rate law is Rate=[S2O8^2-][I-]How did they come up with this?2)How is the rate of disappearance ofS2O8^2- related to the rate of disappearance of [I-]...
The peroxydisulfate ion (S2082") reacts with the iodide ion in aqueous solution via the reaction: S2082-...
The peroxydisulfate ion (S2082") reacts with the iodide ion in aqueous solution via the reaction: S2082- (aq) + 31 → 25042- (aq) + 13- (aq) An aqueous solution containing 0.050 M of S2082-ion and 0.072 M of l' is prepared, and the progress of the reaction followed by measuring [I“). The data obtained is given in the table below. Time (s) [1-) (M) 0.000 0.072 400.0 0.067 800.0 0.046 1200.0 0.037 16000 0.029 What is the concentration (M) of S,062-...
The peroxydisulfate ion (S2O82-) reacts with the iodide ion in aqueous solution via the reaction: S2O82-...
The peroxydisulfate ion (S2O82-) reacts with the iodide ion in aqueous solution via the reaction: S2O82- (aq) + 3I- → 2SO42- + I3- (aq) An aqueous solution containing 0.050 M of S2O82-ion and 0.072 M of I-is prepared, and the progress of the reaction followed by measuring [I-].The data obtained is given the table below. Time (s) 0.000 400.0 800.0 1200.0 1600.0 [I-] (M) 0.072 0.057 0.046 0.037 0.029 The concentration of S2O82- remaining at 800 s is ________ M....
The following data was obtained: a. Determine the rate law. B. Calculate the rate constant Experiment...
The following data was obtained: a. Determine the rate law. B. Calculate the rate constant Experiment S2082-(M)|l-(M) Initial Rate (M/s) 0.018 0.036 2.6x10-6 0.027 0.036 3.9x10-6 0.036 0.054 7.8x10-6 4 0.050 0.072 1.4x10-5
The peroxydisulfate ion (S2082) reacts with the iodide ion in aqueous solution via the reaction: 52082 (aq)+31-2S042- (aq)+ 13 (aq) An aqueous solution containing 0.050 M of S2082 ion and 0.072 M...
The peroxydisulfate ion (S2082) reacts with the iodide ion in aqueous solution via the reaction: 52082 (aq)+31-2S042- (aq)+ 13 (aq) An aqueous solution containing 0.050 M of S2082 ion and 0.072 M of I- is prepared, and the progress of the reaction followed by measuring [I-]. The data obtained is given in the table below. Time (s) 0 400 800 1200 1600 IlM 0.072 0.057 0.046 0.037 0.029 Between 800 and 1200 s the average rate of decomposition of 12...
q 4 Be sure to answer all parts. The reaction of peroxydisulfate ion (S20s with iodide...
q 4
Be sure to answer all parts. The reaction of peroxydisulfate ion (S20s with iodide ion (I) is S20s(aq) + 31(aq) - » 2sO4(aq) + I3 (aq) From the following data collected at a certain temperature, determine the rate law and calculate the rate constant. Experiment[S20sj(M IM Initial Rate [M/s] 0.0300 0.0300 0.0600 0.0440 0.0220 0.0220 8.40 × 10-4 4.20 × 10-4 8.40 x 104 (a) Which of the following equations represents the rate law for this reaction? A....
5. The reaction of peroxydisulfate ion (S2O82−) with iodide ion (I−) is S2O82−(aq) + 3I−(aq) →...
5. The reaction of peroxydisulfate ion (S2O82−) with iodide ion (I−) is S2O82−(aq) + 3I−(aq) → 2SO42−(aq) + I3−(aq) From the following data collected at a certain temperature, determine the rate law and calculate the rate constant. Experiment [S2O82−](M) . [I−](M) . Initial Rate [M/s] 1 0.0300 0.0840 8.80 × 10−4 2 0.0300 0.0420 4.40 × 10−4 3 0.0600 0.0420 8.80 × 10−4 (a) Which of the following equations represents the rate law for this reaction? What is the...
The reaction of peroxydisulfate ion (S2O82-) with iodide ion (I -) is given below. S2O82-(aq) +...
The reaction of peroxydisulfate ion
(S2O82-) with iodide ion (I
-) is given below.
S2O82-(aq) + 3 I
-
2SO24-(aq)
+I3-
The following data are collected at a certain temperature.
Experiment
[S2O82- ](M)
[I- ](M)
Initial Rate (M/s)
1
0.080
0.034
2.2 X 10-4
2
0.080
0.017
1.1 X 10-4
3
0.16
0.017
2.2 X 10-4
Determine the rate law.
____________________
Calculate the rate constant.
______________ /(M·s)
The reaction of peroxydisulfate ion (S2O8^2-) with iodide ion (I -) is given...
Consider the reaction of peroxydisulfate ion (S20;-) with iodide ion (I) in aqueous solution: S2O3- (aq) + 31- (aq) +250- (aq) +15 (aq). At a particular temperature the rate of disappearance of S20% varies with reactant concentrations in the following manner: 1 Experiment S20%- (M) I- (M) Initial Rate (M/s) 0.018 0.036 2.6 x 10-6 0.027 0.036 3.9 x 10-6 0.036 0.054 7.8 x 10-6 N 3 4 0.050 0.072 1.4 x 10-5 Part D What is the rate of...
The peroxydisulfate ion (S2082") reacts with the iodide ion in aqueous solution via the reaction: S2082- (aq) + 31 → 25042- (aq) + 13- (aq) An aqueous solution containing 0.050 M of S2082-ion and 0.072 M of l' is prepared, and the progress of the reaction followed by measuring [I“). The data obtained is given in the table below. Time (s) [1-) (M) 0.000 0.072 400.0 0.067 800.0 0.046 1200.0 0.037 16000 0.029 What is the concentration (M) of S,062-...
The following data was obtained: a. Determine the rate law. B. Calculate the rate constant Experiment S2082-(M)|l-(M) Initial Rate (M/s) 0.018 0.036 2.6x10-6 0.027 0.036 3.9x10-6 0.036 0.054 7.8x10-6 4 0.050 0.072 1.4x10-5
The peroxydisulfate ion (S2082) reacts with the iodide ion in aqueous solution via the reaction: 52082 (aq)+31-2S042- (aq)+ 13 (aq) An aqueous solution containing 0.050 M of S2082 ion and 0.072 M of I- is prepared, and the progress of the reaction followed by measuring [I-]. The data obtained is given in the table below. Time (s) 0 400 800 1200 1600 IlM 0.072 0.057 0.046 0.037 0.029 Between 800 and 1200 s the average rate of decomposition of 12...
q 4
Be sure to answer all parts. The reaction of peroxydisulfate ion (S20s with iodide ion (I) is S20s(aq) + 31(aq) - » 2sO4(aq) + I3 (aq) From the following data collected at a certain temperature, determine the rate law and calculate the rate constant. Experiment[S20sj(M IM Initial Rate [M/s] 0.0300 0.0300 0.0600 0.0440 0.0220 0.0220 8.40 × 10-4 4.20 × 10-4 8.40 x 104 (a) Which of the following equations represents the rate law for this reaction? A....
The reaction of peroxydisulfate ion
(S2O82-) with iodide ion (I
-) is given below.
S2O82-(aq) + 3 I
-
2SO24-(aq)
+I3-
The following data are collected at a certain temperature.
Experiment
[S2O82- ](M)
[I- ](M)
Initial Rate (M/s)
1
0.080
0.034
2.2 X 10-4
2
0.080
0.017
1.1 X 10-4
3
0.16
0.017
2.2 X 10-4
Determine the rate law.
____________________
Calculate the rate constant.
______________ /(M·s)
The reaction of peroxydisulfate ion (S2O8^2-) with iodide ion (I -) is given...
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