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1. The reaction 6f propane with oxygen follows the reaction below: Equation1 ) Balance Equation 1 above i) is the above reaction endothermic or exothermic? Enstem i) Classify the reaction above as combination, single displacement, double displacement, decomposition or combustion. comba How much heat was produced in Equation 1 if it can heat 100 g of water from 32 °C? to 40 Is the energy in propane potential or kinetic energy? P。hhi vi) Given that 1 mole of propane produces 2220 kJ of energy, use your answer in iv) to calculate the grams of propane that produce the energy in iv. vi) For the elements C, H, and O determine the atomic number, proton number, electron number, mass number (for the most abundant isotope), number of neutrons, and electron configuration Atom | Atomic # p. # e. # Mass # 1 no # Electron arrangement vil) Between C and O which one has greater atomic size? Which one has greater ionization energy? Greater atomic size: Cach Greater ionization energyen ).Petermine the polarity of Cc, co, and O-H bonds. A. Determine the geometry of CO, H2O, and around the C atom in C3H8-
xi Which of reactants is oxidized? xi) If you burn 20.0 lbs how many Which of the reactants is reduced7 of propane, how many moles of Oz will it react with? xili) How many molecules of water will be produced? xiv) How many grams of CO, will be released? xv) How many liters of CO2 will be produced if the pressure is 1.5 atm and the temperature is 78.5°F? xv) If 36.0 g of CJHs is combined with 150. g of Oz, which reactant is the limiting reactant? i) If 36.0 g of C3Ha is combined with 150. g of 02, how many grams of water will be produced? ) If 36.0 g of CaHs is combined with 150. g of O2, and 12.5 g of water is isolated, what is the percent yield?
xix) One of the isotopes of carbon, C-14, decays of the product. emitting a 6-particle. Draw the nuclear symbol ml of o.121 M H2504 are neutralized by 17.1 mL of KOH solution according to the following reaction: a) Write the state symbols (s, I, g. or aq) for each compound in Equation1 b) 10.0 mL of 0.121 M H2S04 are neutralized by 17.1 mL of KOH solution according to Equation 1. Calculate the molarity of the KOH solution. c) Classify H25O4 and KOH in the Equation 1 as Arrhenius acid or base and/or as Bronsted-Lowry acid or base. H2504 Name H,S0, KOH, KSo, and H.O and classify each as ionic or covalent. lonic/Covalent d) Name KOH H2O e) Calculate the pH of a 0.121 M H SO4 solution. f) Calculate the (OH] of a 0.121 M H So, solution. g) Determine if a solution of H,50s and KHSO, is a buffer. Explain why or why not. Draw the structures of the following compounds. 3-bromo-2-methylpentane . li) 6-ethyl-2,5-difluoro-3-octyne
) 2,4,6-trinitrotoluene (TNT) v) trons-2-butene-1-thiol (skunk spray) ND Cyclohexylmethylamine v) vi) 3-hydroxyl-4-methylpentanal vi) 3-ethyl-2-hexanone ix) Propyl ethanoate (in pears) x) N-cyclopropylbutanamide 4. a) Write the products of the following reactions. Hydration of 3-chloro-2-methyl-1-pentene b) Dehydration of 2-methylcyclopentanol c) Oxidation of 2-methylcyclopentanol
5. The structure of glyceraldehyde shown below н,он a) Name two functional groups in glyceraldehyde b) Give the IUPAC name for slyceraldehyde. c) Draw the product of the oxidatnf dhyde at carbon-1. d) Draw the product of the oxidation of glyceraldehyde at carbon-2 e) Draw the product of the oxidation of glyceraldehyde at carbon-3 ) Classify the functional group at carbon-2 at primary, secondary, or tertiary 8) Give the reaction of the reduction of glyceraldehyde at carbon-1 6. Consider three structures below.
НН но C-C-N но он GH2 он SH он a) What class of compounds do they belong to? b) Label 5 functional groups present in the compounds above c) the product of the reaction of the three compounds if they react in the order provided d) What is the name of the functional group joining them together? What is the class of enzymes responsible for breaking this type of bond (in part d above) during digestion? e)
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