We have to draw the plot of ln(V) vs 1/T
where V = volume of N2 evolved ( in cm3) , T = Time (in min )
(A) As plot of ln(V) vs 1/T gives a straight line , so , order of reaction is 1st
(B) Now , from the plot , equation of line ,
y = -7.335x + 4.130
so, Slope = -7.335 = - K
where K = rate constant
Therefore , Rate constant = K = 7.335 min-1
12. Benezene diazonium chloride decomposes according to the following equation During the decomposition the nitrogen gas...
Nitrosyl chloride, NOCI, decomposes to form nitrogen monoxide gas and chlorine gas according to 2NOCI(g) = 2NO(g) + Cl2(g) Assuming that we start with no moles of NOCI(g) and no NO(g) or Cl2(g), derive an expression for K, in terms of the equilibrium value of the extent of reaction, Šeg, and the pressure p. Given that Ky = 2.00 x 10-4, calculate Šeg/no, when p = 0.080 bar. What is the new value of Šeg/no at equilibrium when p =...
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12) Ammonium nitrate decomposes explosively upon heating according to the following balanced equation: 2NH4NO3(s)→2N2(g)+O2(g)+4H2O(g) Calculate the total volume of gas (at 127 ∘C and 733 mmHg ) produced by the complete decomposition of 1.54 kg of ammonium nitrate.
Problems 1. According to the Ideal Gas Law, which of the following is/are correct for a gas cylinder of fixed volume filled with one mole of oxygen gas? Please explain each one. a. When the temperature of the cylinder changes from 15 °C to 30 °C, the pressure inside the cylinder doubles. b. When a second mole of oxygen is added to the cylinder, the ratio T/P remains constant. C. An identical cylinder filled with the same pressure of hydrogen...