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Molecules in excited electronic states can return to the ground electronic state by emitting a photon...

Molecules in excited electronic states can return to the ground electronic state by emitting a photon through the processes of fluorescence and phosphorescence. Which of these processes is faster?

fluorescence

phosphorescence

they occur at the same rate

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Answer #1

Fluorescence is the faster process in comparison with phosphorescence.

In Fluorescence process the excited molecule will directly return to the ground state without changing its spin. But in phosphorescence there is an additional process called Inter System crossing (ISC), where the spin of the molecule changes to singlet to triplet and then it revert back to singlet.

Due to the intersystemcrossing the overall time that is required for phosphorescence is more. Hence it a delayed process.

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