It is possible to have a polyvinyl chloride (PVC) with the following molecular weight data and...
An alternating copolymer is known to have a number-average molecular weight of 250,000 g/mol and a number-average degree of polymerization of 3406. One of the alternating mers is polystyrene which has a molecular weight of 105_g/mol. Given that the molecular weight of polypropylene is 42 g/mol and that of polyvinyl chloride is 61.5 g/mol, Which of them is the other alternating mer?
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nber-average and weight-average molecular weight. Is it possible to have a polypropylene polymer with the following molecular weight data and a num degree of polymerization of 1134? Why or why not? Molecular Weight Range (g/mol) 8000-20000 W 0.02 0.05 20000-32000 0.08 0.15 32000-44000 0.17 0.21 44000-56000 0.29 0.28 56000-68000 0.23 0.18 68000-80000 0.16 0.10 80000-92000 0.05 0.03 The chemical formula for the polypropylene monomer is C3H6. The atomic weights of carbon...
8.a) A random poly(styrene-butadiene) copolymer has a weight-average molecular weight of 467,500 g/mol and a weight-average degree of polymerization of 5500. Calculate the fraction of styrene (C:Hg) and butadiene (C4H6) mers in this copolymer. Atomic weights: C-12, H-1 b) What weight % sulphur must be added to vulcanize polyisoprene (mer weight = 68) by crosslinking one half the possible sites. In this elastomer, each pair of mers has two possible crosslink sites. Assume three sulphur atoms are involved in each...
1. Which one of the following has the lowest Tg? H H нн нн м dooсн) H CH3 H H CI. (b) Polymethyl methacrylate (PMMA) (d) Polyvinyl chloride (a) Polypropylene (PP) (c) Polystyrene (PS) (PVC) Answer: 2. Which one of the following has the highest T? нн CH,CH н ni н CI (d) Polyvinyl (c) Polyethylene terephthalate (PET) (a) Polypropylene (PP) (b) Polystyrene (PS) chloride (PVC) Answer:
5) Rank the following polymers in terms of the listed properties from 1 (lowest value) to 5 (highest value). Explain the results. 19 -C-C- (Highly Cross- Liaked Structure) -C-C- -C-C- Polyethylene Epoxy Polyvinyl Chloride Polystyrene Chloride Tensile Strength Tensile Use Temperature Stiffness Polyethylene Epoxy Polyvinyl Chloride Polystyrene Polyvinylidene Chloride Useful information: Atomic mass: hydrogen: 1, carbon: 12, oxygen: 16, chlorine: 35.5, nitrogen: 14 Step Polymerization, Carother's Equations 1-p dt Xw=1+p R= _d (AA) = k [A-AJ (8-) S CA-AJ. CAAJ...
4 (20 Points) Calculate the number-average molecular weight and the weight average molecular weight of a polymer sample made of polystyrene with a repeat unit of (CH2- CH(CHs)) and composed of two types of chains. 60 percent of the chains have a degree of polymerization of 7,000 and the rest 50,000. Carbon has an atomic weight of 12 g/mol and hydrogen is 1 g/mol.
3 8.a) A random poly(styrene-butadiene) copolymer has a weight-average molecular weight of 467,500 g/mol and a weight-average degree of polymerization of 5500. Calculate the fraction of styrene (CsHg) and butadiene (C4H6) mers in this copolymer. Atomic weights: C-12, H-1 b) What weight % sulphur must be added to vulcanize polyisoprene (mer weight = 68) by crosslinking one half the possible sites. In this elastomer, each pair of mers has two possible crosslink sites. Assume three sulphur atoms are involved in...
(a) Any polymeric material will have a distribution of molecular weights, and therefore an average molecular weight is used to characters the material. Is it possible to have a polyethylene homopolymer with the following molecular weight distribution data and a weight average degree of polymerization of 2090? Why or why not? The polyethylene mer is shown below. (b) Based on the mer structure shown for poly(methyl methacrylate) (PMMA) and polyethylene (PE). Which has potential for greater crystallinity? Provide a brief...
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Problem 5 (10pts) The following table lists molecular weight data for a polyethylene material. Compute (a) the number-average molecular weight, and (b) the degree of polymerization. Molecular Weight Range (g/mol) 8,000-20,000 20,000-32,000 32,000-44,000 44,000-56,000 56,000-68,000 68,000-80,000 80,000-92,000
Problem 5 (10pts) The following table lists molecular weight data for a polyethylene material. Compute (a) the number-average molecular weight, and (b) the degree of polymerization. Molecular Weight Range (g/mol) 8,000-20,000 20,000-32,000 32,000-44,000 44,000-56,000 56,000-68,000 68,000-80,000 80,000-92,000
1. A sample of polystyrene has a number average molecular weight of 30,000 daltons. What is the number average degree of polymerization (n)? The mer structure is shown below, amu are C-12, H-1; 1 dalton 6.023x103 grams