Specific Rotation = Observed Rotation / (conc,g/ml) (length of
sample tube, decimeters)
From this formula we can find optical rotation of pure compound
+44 = Observed Rotation / 1 x 1
Observed Rotation = + 44
Observed optical rotation = Percentage of pure optical compound x specific rotation of the compound.
Observed optical rotation = (66-34) x 44 / 100 = -14.08 Degrees
The negative sign is for telling -camphour is presents as major enantiomer which rotates the lights counter clock wise.
explain please (*)-Camphor has a specific rotation of +44 degree. If you have a mixture of...
(+)-camphor has a specific rotation of +44. if you have a mixture of 34% (+)-camphor and 66% (-)-camphor, what will be the observed rotation of this mixture? Assume 1 g dissolved in 1 mL; the sample cell is 1 dm long
5.41 Predict the value for the specific rotation of the following compound. Explain your answer. -OH НО. 5.42 The specific rotation of (S)-2-butanol is +13.5. If 1.00 g of its enantiomer is dissolved in 10.0 mL of ethanol and placed in a sample cell with a length of 1.00 dm, what observed rotation do you expect? 5.43 The specific rotation of l-alanine in water (at 25°C) is +2.8. A chemist prepared a mixture of l- alanine and its enantiomer, and...
5.42 The specific rotation of (S)-2-butanol is +13.5. If 1.00 g of its enantiomer is dissolved in 10.0 mL of ethanol and placed in a sample cell with a length of 1.00 dm, what observed rotation do you expect?
Confused on how to get answer to problem. Please help 10. Camphor is a naturally occurring aromatic compound used as an embalming fluid, for medicinal purposes, and in religious ceremonies. The naturally occurring (+) isomer has a specific rotation of +44 If a sample with a mixture of camphor and its enantiomer is analyzed for its optical activity what would the observed specific rotation be if the ratio of enantiomers was 55% ) and 45% (-)? a. 0° 557,- 45%-...
please solve and probide step by step 15. Calculate the observed rotation expected in the following situation: a standard 2.00-dm cell is used and ten grams of a 9:1 mixture of enantiomers is dissolved in 100 mL of solvent. The major enantiomer has a specific rotation of +200°.(4 pts)
A) If the observed rotation for the product mixture obtained from running the reaction in toluene is 18.7, what is the specific rotation of the S enantiomer? B) Based on your answer in part (a), predict what the observed rotation would be for a solution containing 0.250 g of this S-enantiomer dissolved in 10.0 mL of ethanol and placed in a sample cell with a length of 10.0 cm.
A 0.110 M solution of an enantiomerically pure chiral compound D has an observed rotation of +0.24° in a 1-dm sample container. The molar mass of the compound is 144.0 g/mol. (a) What is the specific rotation of D? (b) What is the observed rotation if this solution is mixed with an equal volume of a solution that is 0.110 M in L, the enantiomer of D? Number deg mL Number g dm deg (c) What is the observed rotation...
1) (S)(-) mandelic acid has a specific rotation of -158.0 degrees, If the rotation you observed in your polarimeter in a 2.5 dm cell was -150.1, what is the concentration of the solution in g ml1?
A 0.120 M solution of an enantiomerically pure chiral compound D has an observed rotation of + 0.26 degree in a 1-dm sample container. The molar mass of the compound is 153.0 g/mol. What is the specific rotation of D? What is the observed rotation if this solut is mixed with an equal volume of a solution t is 0.120 M in L, the enantiomer of D? What is the observed rotation if the solution of D is diluted with...
1.Calculate the specific rotation, [α], if the observed rotation is -24°, the concentration is 31 g/100 mL, and the cell length is 5 cm. Answer in :° mL/g/dm 2. The height of three peaks; A, B, and C obtained in a gas chromatogram are 27.7 mm, 19.2 mm and 41.0 mm. The width of the peaks, at half height, are 4.9 mm, 4.7 mm and 4.6 mm, respectively. Calculate the percentage composition of C in the sample. Answer in :...