Molecule1= R-4-propylnonan-5-ol 1.Draw your Molecule 1 with a properly drawn stereocenter. 2.Predict the major organic product(s)...
Molecule1= R-4-propylnonan-5-ol
1.Draw your Molecule 1 with a properly drawn stereocenter.
2.Predict the major organic product(s) (including stereochemistry where appropriate) for reaction of Molecule 1 with the following reagents.
a) Phosphorous tribromide. There is one product and it is called Molecule 2a.
b) TsCl and pyridine. Show all pie bonds. There is one product and it is called Molecule 2b.
c) Thionyl chloride and pyridine. There is one product and it is called Molecule 2c.
d) Draw a full Lewis Structure of sulfuric acid ( Reaction of Molecule 1 with sulfuric acid and heat creates 3 products (one major, one minor, and one very minor). Label your products as follows: call your major product Molecule 2dMJ and your first minor product Molecule 2dMN. Call your most minor product (the one formed in the least amount) Molecule 2dMMN
Homework Answers
The structure of the product of R-4-propyl nonane 1-ol was labled as 1.
The compound 1 reacts with PBr3 and the corresponding bromo product with inversion of stereochemistry will form.
The compound 1 react with Tosyl chloride in presence of pyridine and the tosyl protected alcohol without change in stereochemistry will be the product
The compound 1 with thionylchloride will give the corresponding chloro compound with inversion of stereochemistry.
The elimination product of alcohol with sulfuricacid gives 3 types of olefins. The carbocation formed by elimination of water molecule can be stabilised by migration(wagner meerwein rearrangement),which will give most hyperconjugated structures of olefin as major. The possible olefin structures was drawn and labled as you mentioned.
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Molecule1= R-4-propylnonan-5-ol
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For the following SN2 reaction, draw the major organic product
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involving products that result
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