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2. Write in all the product(s) of these reactions. Label products as "major" or "minor" if...
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate...
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: i 1. NaBH, MOH 2. H, H2O 3. conc. H2SO4, heat 1. LiAlH4, THE 2. H, H2O 3. MSCI, Pyr, 0 °C 1. SOCI, EIN -D 2. LAIH, ether 1. Li, hexane 2. i . THE 3. acidic work-up Jone's reagent ОН OH 1. PBT 2. NaCN, THE PH conc. H2SO4 NaCl 0°C conc. HBO OH heat
DRAW the products of the following chemical reactions. Label major and minor products if applicable. Include,...
DRAW the products of the following chemical reactions.
Label major and minor products if applicable. Include, where
necessary, the correct structures showing proper stereochemistry
and orientation using wedges and dashes. If no reaction occurs
write “NA” or “no reaction”.
o anon DMSO, (COC), - CHOH Et;N, CH2Cl2, --60°C CHE 211: Organic Chemistry 2 Spring 2020 | Nazr20/ H2SC -CH2OH : SOCI pyridine Mg Br - - - ether 2. H20
(4 pts each) Write all possible products of the following reactions. (2 pts each) Write reasoning for the possible products (mechanism with arrows) (1 pt each) Write approximate atio (major, minor, v...
(4 pts each) Write all possible products of the following reactions. (2 pts each) Write reasoning for the possible products (mechanism with arrows) (1 pt each) Write approximate atio (major, minor, very minor, etc are okay) 4. СНз H3C CH3CH20H њено" Br CH3 њење Br Name: Page 4 of 9
(4 pts each) Write all possible products of the following reactions. (2 pts each) Write reasoning for the possible products (mechanism with arrows) (1 pt each) Write approximate atio (major,...
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate...
1. Give the major product of the following reactions, write N.R.
if no reaction happens. Indicate the stereochemistry if
necessary:
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: CHCl3 KOC(CH3)3, (CH3)3COH 1. conc. HBr, heat 2. KOBU, HOBU ✓ 1. NaoMe, MeOH 2. BrCN 1. 1 eq. BH3, THE 2. H2O2, NaOH, H20 3. Hg(OAc)2, MeOH 4. NaBH4, NaOH, H20
Question : Predict the major and minor products for the following reactions: NASH -CH3 + 1...
Question : Predict the major and minor products for the following reactions: NASH -CH3 + 1 H30 HC b) NaOEt Question 6: Predict the major and minor products for the following reactions: NaOEt OTS - Tosylate (OTS) With on CHM 2210 CH3 NaOH H₂C O=O=O Question 7: Draw the plausible mechanism for each of the following transformations: CHE BECH HO HBr CH CH CH3 H₂C- conc. H,SO heat HC Insuu H Question 8 Which is the better retrosynthesis for the...
2. Predict the structure of the major organic product(s) of following sequence of reactions. Be sure...
2. Predict the structure of the major organic product(s) of following sequence of reactions. Be sure to indicate any relevant stereochemistry. If no reaction is expected, please write N.R. Please place your answers in the box provided. (4 points) mCPBA 1) EtMgBr ether 2) H30*
3. Draw the major and minor products for each of the following reactions. Label major or minor if more than one pro...
3. Draw the major and minor products for each of the following reactions. Label major or minor if more than one product. (14 pts) Br DBU 1. TsCl, pyridine CH3CH2OH 2. methoxide ion HO 1. BH, 2.1,0. OH d. HC CHỊCH5OH
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write...
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write N.R. if no reaction occurs. Identify the type of substrate (1º, 2º, 3º, allylic, benzylic, aryl, vinyl) and give the type of mechanism by which each product is formed (Syl, Sy2, E, B). Assume the reaction is at room temperature if no temperature or heat symbol (A) is indicated. You may work in peer groups; if so, turn in just one copy with the...
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write...
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write N.R. if no reaction occurs. Identify the type of substrate (1º, 2º, 3º, allylic, benzylic, aryl, vinyl) and give the type of mechanism by which each product is formed (Syl. Sy 2, E.B). Assume the reaction is at room temperature if no temperature or heat symbol (A) is indicated. You may work in peer groups; if so, turn in just one copy with the...
1.Predict all the products for the following reaction. Which is the major product? Why? + conc....
1.Predict all the products for the following reaction. Which is the major product? Why? + conc. H2SO4 heat OH 2. Give an alcohol that you could use to synthesis each of the following alkenes? din 3.Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН ОН conc H2SO4 conc H2SO4 heat heat
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: i 1. NaBH, MOH 2. H, H2O 3. conc. H2SO4, heat 1. LiAlH4, THE 2. H, H2O 3. MSCI, Pyr, 0 °C 1. SOCI, EIN -D 2. LAIH, ether 1. Li, hexane 2. i . THE 3. acidic work-up Jone's reagent ОН OH 1. PBT 2. NaCN, THE PH conc. H2SO4 NaCl 0°C conc. HBO OH heat
DRAW the products of the following chemical reactions.
Label major and minor products if applicable. Include, where
necessary, the correct structures showing proper stereochemistry
and orientation using wedges and dashes. If no reaction occurs
write “NA” or “no reaction”.
o anon DMSO, (COC), - CHOH Et;N, CH2Cl2, --60°C CHE 211: Organic Chemistry 2 Spring 2020 | Nazr20/ H2SC -CH2OH : SOCI pyridine Mg Br - - - ether 2. H20
(4 pts each) Write all possible products of the following reactions. (2 pts each) Write reasoning for the possible products (mechanism with arrows) (1 pt each) Write approximate atio (major, minor, very minor, etc are okay) 4. СНз H3C CH3CH20H њено" Br CH3 њење Br Name: Page 4 of 9
(4 pts each) Write all possible products of the following reactions. (2 pts each) Write reasoning for the possible products (mechanism with arrows) (1 pt each) Write approximate atio (major,...
1. Give the major product of the following reactions, write N.R.
if no reaction happens. Indicate the stereochemistry if
necessary:
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: CHCl3 KOC(CH3)3, (CH3)3COH 1. conc. HBr, heat 2. KOBU, HOBU ✓ 1. NaoMe, MeOH 2. BrCN 1. 1 eq. BH3, THE 2. H2O2, NaOH, H20 3. Hg(OAc)2, MeOH 4. NaBH4, NaOH, H20
Question : Predict the major and minor products for the following reactions: NASH -CH3 + 1 H30 HC b) NaOEt Question 6: Predict the major and minor products for the following reactions: NaOEt OTS - Tosylate (OTS) With on CHM 2210 CH3 NaOH H₂C O=O=O Question 7: Draw the plausible mechanism for each of the following transformations: CHE BECH HO HBr CH CH CH3 H₂C- conc. H,SO heat HC Insuu H Question 8 Which is the better retrosynthesis for the...
2. Predict the structure of the major organic product(s) of following sequence of reactions. Be sure to indicate any relevant stereochemistry. If no reaction is expected, please write N.R. Please place your answers in the box provided. (4 points) mCPBA 1) EtMgBr ether 2) H30*
3. Draw the major and minor products for each of the following reactions. Label major or minor if more than one product. (14 pts) Br DBU 1. TsCl, pyridine CH3CH2OH 2. methoxide ion HO 1. BH, 2.1,0. OH d. HC CHỊCH5OH
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write N.R. if no reaction occurs. Identify the type of substrate (1º, 2º, 3º, allylic, benzylic, aryl, vinyl) and give the type of mechanism by which each product is formed (Syl, Sy2, E, B). Assume the reaction is at room temperature if no temperature or heat symbol (A) is indicated. You may work in peer groups; if so, turn in just one copy with the...
For each of the following reactions, predict the major product(s), showing proper stereochemistry where appropriate. Write N.R. if no reaction occurs. Identify the type of substrate (1º, 2º, 3º, allylic, benzylic, aryl, vinyl) and give the type of mechanism by which each product is formed (Syl. Sy 2, E.B). Assume the reaction is at room temperature if no temperature or heat symbol (A) is indicated. You may work in peer groups; if so, turn in just one copy with the...
1.Predict all the products for the following reaction. Which is the major product? Why? + conc. H2SO4 heat OH 2. Give an alcohol that you could use to synthesis each of the following alkenes? din 3.Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН ОН conc H2SO4 conc H2SO4 heat heat
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