Question

2. (6 points) The rearrangement of cyclopropane (C3Hs) to propene (C34) is a first-order reaction, with a rate constant (k) 6.7x 104 s1 at 773 K 0.25 mol of C3H6 is placed in a 5 L container. (i) What is the concentration (M) of C3Hs after 30 minutes? (ii) How long does it take for the C3H6 concentration to drop to 0.010 M? (iii ) How long does it take for 25 % of the C3H6 to react? 3. (8 points) A three-step mechanism has been suggested for the reaction of OCI with H20 as given below: ki HOCI(aq) + OH(aq) (fast) k-1 k2 k.2 k3 Step 2: HOClag)Ta) HOIag) Cl(aq) (slow) Step 3: Hola) + OH(aq) → H2O() + OI(aq) (fast) (a) Which species is an intermediate? (b) What is the molecularity of the rate-determining step? (c) Write an equation for the overall reaction. (d) What is the likely rate law for the overall reaction? Note: The concentrations of intermediates should not appear in the rate law for the overall reaction) 4. (6 points) (a) The reaction that takes place in a Breathalyzer for determining the alcohol leve in a persons bloodstream is given below. 2 K2Cr20 +8 H2S04+ 3 C2H602 Cr2(SO4)s+ 2 K2S04+ 11 H20 If the rate of formation of Cra(S0)s is 2.04 mol min lat a particular moment, what is: (i) the rate of formation of C2H6O in mol s1? (i) the rate of disappearance of H2SO4 in mol min-l ? (ii) the rate of formation of H20 in mol h?
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Answer #1

Approach: 1) Write integrated rate law for a 1st order reaction

2) Identify all the variables

3) Calculate unknown quantities from the equation

Rata lau AnTA [AT → cone entra tion of A after time t K--> Rabe eons tcnt t 30 mins 1800 S0 concent丫ation of C3H6 after 30 min-O-01:0)3 (in:) = 0.0375(H) ,· An (010375) м (о.os)-- (6.7 x1o-4 X t S 429.4s il be vequised

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