Question

Draw a structural formula for the major organic product(s) of the reaction shown below. H2N 1. CH3l (excess) 2. Ag20, H20, heat • You do not have to consider stereochemistry. . Do not draw inorganic by-products. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. Coor -O0O-F CH3CH3 H2 CH3 ChemDoodle Previous Next

Answer 1

OH CH₂I Ha -16 -lo HANK Ag₂0H20 Texcess) Heat Ho HC Elemination of Ha leads to: 1X Elm,modom of нь и 4 : 1 Elemination of te ur : t Noc, (I) and (II) is some So two structures are (I) (1 (II) (Minos) (less ex and Le rore steric) sterie) 2 (I) (TV) (Major (5 Hyper conjugative (6 Hyperconjugative hydrogen, so den hydrogen, so more aucestituted alkenes qulostituted arkenes Best due to internal alkene, structure (II) has more steric crowding thon (I) or (I). So (I) or (I) is major prot.

HA Ag2O, H2O H2N ND , V CH3 I (excess) " Heat HC X 2 Elemination of Ha leads to compound : Elemination of Ho u u u : Ellmination of He u « « : Now basically (I) and (II) in some. so two structures are (I) (1) (II) nd C5 Hyper conjugative Hydrogen) 1 (runon Que to 6 hyperconjugative hydrogen this alkene more stabile) (Major)

HA Ag2O, H2O H2N ND , V CH3 I (excess) " Heat HC X 2 Elemination of Ha leads to compound : Elemination of Ho u u u : Ellmination of He u « « : Now basically (I) and (II) in some. so two structures are (I) (1) (II) nd C5 Hyper conjugative Hydrogen) 1 (runon Que to 6 hyperconjugative hydrogen this alkene more stabile) (Major)

Please ignore the previous one. Compound I or II is major compound